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The convergent synthesis involves the construction of the C1\u2013C11 tetrahydropyran segment via catalytic asymmetric allylation and Prins cyclization, and the formation of the C12\u2013C21 phosphonate segment via catalytic asymmetric cyclocondensation reaction and Johnson\u2013Claisen rearrangement. The synthesis of 15\u2010\n                    <jats:italic>epi<\/jats:italic>\n                    \u2010exiguolide is also described.\n                  <\/jats:p>","DOI":"10.1002\/chem.202001773","type":"journal-article","created":{"date-parts":[[2020,5,19]],"date-time":"2020-05-19T17:53:22Z","timestamp":1589910802000},"page":"12862-12867","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":17,"title":["Catalytic Asymmetric Total Synthesis of Exiguolide"],"prefix":"10.1002","volume":"26","author":[{"given":"Kengo","family":"Oka","sequence":"first","affiliation":[{"name":"Graduate School of Biomedical Sciences Nagasaki University  Bunkyo-machi Nagasaki 852-8521 Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shunsuke","family":"Fuchi","sequence":"additional","affiliation":[{"name":"Graduate School of Biomedical Sciences Nagasaki University  Bunkyo-machi Nagasaki 852-8521 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