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This has ultimately been motivated by a desire to find TM\u2010mediated alternatives to the current industrial routes used to transform P<jats:sub>4<\/jats:sub> into myriad useful P\u2010containing products, which are typically indirect, wasteful, and highly hazardous. Such a TM\u2010mediated process can be divided into two steps: activation of P<jats:sub>4<\/jats:sub> to generate a polyphosphorus complex TM\u2010P<jats:sub><jats:italic>n<\/jats:italic><\/jats:sub>, and subsequent functionalization of this complex to release the desired phosphorus\u2010containing product. The former step has by now become well established, allowing the isolation of many different TM\u2010P<jats:sub><jats:italic>n<\/jats:italic><\/jats:sub> products. In contrast, productive functionalization of these complexes has proven extremely challenging and has been achieved only in a relative handful of cases. In this review we provide a comprehensive summary of successful TM\u2010P<jats:sub><jats:italic>n<\/jats:italic><\/jats:sub> functionalization reactions, where TM\u2010P<jats:sub><jats:italic>n<\/jats:italic><\/jats:sub> must be accessible by reaction of a TM precursor with P<jats:sub>4<\/jats:sub>. We hope that this will provide a useful resource for continuing efforts that are working towards this highly challenging goal of modern synthetic chemistry.<\/jats:p>","DOI":"10.1002\/chem.202001854","type":"journal-article","created":{"date-parts":[[2020,7,21]],"date-time":"2020-07-21T16:10:53Z","timestamp":1595347853000},"page":"1886-1902","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":114,"title":["Transition\u2010Metal\u2010Mediated Functionalization of White Phosphorus"],"prefix":"10.1002","volume":"27","author":[{"given":"Christian M.","family":"Hoidn","sequence":"first","affiliation":[{"name":"University of Regensburg Institute of Inorganic Chemistry  93040 Regensburg Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7826-9833","authenticated-orcid":false,"given":"Daniel J.","family":"Scott","sequence":"additional","affiliation":[{"name":"University of Regensburg Institute of Inorganic Chemistry  93040 Regensburg Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4066-6483","authenticated-orcid":false,"given":"Robert","family":"Wolf","sequence":"additional","affiliation":[{"name":"University of Regensburg Institute of Inorganic Chemistry  93040 Regensburg Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2020,11,18]]},"reference":[{"key":"e_1_2_6_1_1","first-page":"846","volume-title":"Anorganische Chemie, Band 1 Grundlagen und Hauptgruppenelemente","author":"Holleman A. 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