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The metalated species were characterized in situ by NMR spectroscopy and in two cases isolated as crystalline solids. Single\u2010crystal XRD studies revealed the presence of salt\u2010like structures with strongly interacting ions. Synthetic applications of K[(R<jats:sub>2<\/jats:sub>N)<jats:sub>2<\/jats:sub>P(BH<jats:sub>3<\/jats:sub>)] were studied in reactions with a 1,2\u2010dichlorodisilane and CS<jats:sub>2<\/jats:sub>, which afforded either mono\u2010 or difunctional phosphine boranes with a rare combination of electronegative amino and electropositive functional disilanyl groups on phosphorus, or a phosphinodithioformate. Spectroscopic studies gave a first hint that removal of the borane fragment may be feasible.<\/jats:p>","DOI":"10.1002\/chem.202002296","type":"journal-article","created":{"date-parts":[[2020,6,22]],"date-time":"2020-06-22T07:44:12Z","timestamp":1592811852000},"page":"15190-15199","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":5,"title":["Isolable Diaminophosphide Boranes"],"prefix":"10.1002","volume":"26","author":[{"given":"Markus","family":"Blum","sequence":"first","affiliation":[{"name":"Institute of Inorganic Chemistry University of Stuttgart  Pfaffenwaldring 55 70550 Stuttgart Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Tobias","family":"Dunaj","sequence":"additional","affiliation":[{"name":"Institute of Inorganic Chemistry University of Stuttgart  Pfaffenwaldring 55 70550 Stuttgart Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Julius A.","family":"Kn\u00f6ller","sequence":"additional","affiliation":[{"name":"Institute of Inorganic Chemistry University of Stuttgart  Pfaffenwaldring 55 70550 Stuttgart Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Christoph M.","family":"Feil","sequence":"additional","affiliation":[{"name":"Institute of Inorganic Chemistry University of Stuttgart  Pfaffenwaldring 55 70550 Stuttgart Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1677-0109","authenticated-orcid":false,"given":"Martin","family":"Nieger","sequence":"additional","affiliation":[{"name":"Department of Chemistry University of Helsinki  P.O Box 55 00014 University of Helsinki Finland"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9196-0466","authenticated-orcid":false,"given":"Dietrich","family":"Gudat","sequence":"additional","affiliation":[{"name":"Institute of Inorganic Chemistry University of Stuttgart  Pfaffenwaldring 55 70550 Stuttgart Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2020,10,19]]},"reference":[{"key":"e_1_2_7_1_1","unstructured":"See:"},{"key":"e_1_2_7_2_2","first-page":"329","volume-title":"Science of Synthesis Vol.\u200531.42 update 2013\/2","author":"Stankevi\u010d M.","year":"2013"},{"key":"e_1_2_7_3_2","first-page":"71","volume-title":"Science of Synthesis Vol.\u200542.4","author":"Hey-Hawkins E.","year":"2008"},{"key":"e_1_2_7_4_2","first-page":"155","volume-title":"Science of Synthesis Vol.\u200542.6","author":"Gudat D.","year":"2008"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.200802307"},{"key":"e_1_2_7_6_1","unstructured":"\u00a0"},{"key":"e_1_2_7_7_2","doi-asserted-by":"publisher","DOI":"10.1002\/cber.19590920518"},{"key":"e_1_2_7_8_2","doi-asserted-by":"publisher","DOI":"10.1002\/zaac.19592990108"},{"key":"e_1_2_7_9_2","doi-asserted-by":"publisher","DOI":"10.1515\/znb-1959-0515"},{"key":"e_1_2_7_10_1","doi-asserted-by":"publisher","DOI":"10.1002\/cber.19540870621"},{"key":"e_1_2_7_11_1","unstructured":"\u00a0"},{"key":"e_1_2_7_12_2","doi-asserted-by":"publisher","DOI":"10.1002\/zaac.19764220203"},{"key":"e_1_2_7_13_2","doi-asserted-by":"publisher","DOI":"10.1002\/zaac.19916060111"},{"key":"e_1_2_7_14_1","unstructured":"Formation of a mixture of mono and dilithiated aminophosphides (R2N)nPLi3\u2212n(R=Me Et;n=1 2) is claimed in a patent but no characterization data are reported and pure products do not seem to have been isolated:L.Maier(Monsanto) DE 1244180 1967."},{"key":"e_1_2_7_15_1","unstructured":"\u00a0"},{"key":"e_1_2_7_16_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0022-328X(98)00744-X"},{"key":"e_1_2_7_17_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0022-328X(99)00031-5"},{"key":"e_1_2_7_18_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201600850"},{"key":"e_1_2_7_19_1","unstructured":"\u00a0"},{"key":"e_1_2_7_20_2","doi-asserted-by":"publisher","DOI":"10.1016\/0040-4039(96)01296-8"},{"key":"e_1_2_7_21_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0957-4166(97)00052-9"},{"key":"e_1_2_7_22_1","doi-asserted-by":"publisher","DOI":"10.1039\/C7DT04110A"},{"key":"e_1_2_7_23_1","doi-asserted-by":"publisher","DOI":"10.1002\/ejic.201201471"},{"key":"e_1_2_7_24_1","doi-asserted-by":"publisher","DOI":"10.1002\/cber.19630960520"},{"key":"e_1_2_7_25_1","unstructured":"\u00a0"},{"key":"e_1_2_7_26_2","doi-asserted-by":"publisher","DOI":"10.1002\/1521-3773(20000901)39:17<3084::AID-ANIE3084>3.0.CO;2-R"},{"key":"e_1_2_7_26_3","doi-asserted-by":"publisher","DOI":"10.1002\/1521-3757(20000901)112:17<3211::AID-ANGE3211>3.0.CO;2-A"},{"key":"e_1_2_7_27_2","doi-asserted-by":"publisher","DOI":"10.1021\/ar100041j"},{"key":"e_1_2_7_28_2","doi-asserted-by":"publisher","DOI":"10.1039\/C6DT00085A"},{"key":"e_1_2_7_29_1","unstructured":"M. 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