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Although the diphosphanylchalcogane has been obtained for tellurium, all other chalcogens give diphosphane monochalcogenides. The latter transform via chalcogen\u2010transfer rearrangement to the corresponding diphosphanylchalcoganes upon heating. The kinetics of this rearrangement has been followed with NMR spectroscopy supported by DFT calculations. Intermediates during rearrangement point to a disproportionation\/synproportionation mechanism for the S and Se derivatives. Cyclic voltammetry together with DFT studies indicate ferrocene\u2010centred oxidation for most of the compounds presented.\n                  <\/jats:p>","DOI":"10.1002\/chem.202002481","type":"journal-article","created":{"date-parts":[[2020,7,17]],"date-time":"2020-07-17T13:41:19Z","timestamp":1594993279000},"page":"641-648","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":16,"title":["Chalcogen\u2010Transfer Rearrangement: Exploring Inter\u2010 versus Intramolecular P\u2212P Bond Activation"],"prefix":"10.1002","volume":"27","author":[{"given":"Roman","family":"Franz","sequence":"first","affiliation":[{"name":"Institute for Chemistry and CINSaT University of Kassel  Heinrich Plett-Strasse 40 34132 Kassel Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sina","family":"Nasemann","sequence":"additional","affiliation":[{"name":"Institute for Chemistry and CINSaT University of Kassel  Heinrich Plett-Strasse 40 34132 Kassel Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Clemens","family":"Bruhn","sequence":"additional","affiliation":[{"name":"Institute for Chemistry and CINSaT University of Kassel  Heinrich Plett-Strasse 40 34132 Kassel Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4787-9804","authenticated-orcid":false,"given":"Zsolt","family":"Kelemen","sequence":"additional","affiliation":[{"name":"Department of Inorganic and Analytical Chemistry Budapest University of Technology and Economics and MTA-BME, Computation Driven Chemistry Research Group  Szent Gell\u00e9rt t\u00e9r 4 1111 Budapest Hungary"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0551-3633","authenticated-orcid":false,"given":"Rudolf","family":"Pietschnig","sequence":"additional","affiliation":[{"name":"Institute for Chemistry and CINSaT University of Kassel  Heinrich Plett-Strasse 40 34132 Kassel Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2020,11,9]]},"reference":[{"key":"e_1_2_6_1_1","unstructured":"\u00a0"},{"key":"e_1_2_6_2_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr00029a008"},{"key":"e_1_2_6_3_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja981015o"},{"key":"e_1_2_6_4_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr050044w"},{"key":"e_1_2_6_5_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200800572"},{"key":"e_1_2_6_5_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200800572"},{"key":"e_1_2_6_6_1","doi-asserted-by":"publisher","DOI":"10.1021\/ic9614879"},{"key":"e_1_2_6_7_1","doi-asserted-by":"publisher","DOI":"10.1016\/0022-1902(62)80180-8"},{"key":"e_1_2_6_8_1","doi-asserted-by":"publisher","DOI":"10.1002\/hlca.19620450709"},{"key":"e_1_2_6_9_1","doi-asserted-by":"publisher","DOI":"10.1002\/zaac.19693710506"},{"key":"e_1_2_6_10_1","doi-asserted-by":"publisher","DOI":"10.1021\/ic401002b"},{"key":"e_1_2_6_11_1","doi-asserted-by":"publisher","DOI":"10.1039\/C3CC49456J"},{"key":"e_1_2_6_12_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.5b02723"},{"key":"e_1_2_6_13_1","first-page":"478","volume":"47","author":"Foss V. 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