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Mesoporous carbons with wide, accessible pores were prepared by pyrolysis of a resorcinol\u2010formaldehyde resin using a PEO\u2010b\u2010PS block copolymer as a sacrificial templating agent and the nitrogen and sulfur doping were accomplished in a second thermal treatment employing 1,10\u2010phenanthroline and dibenzothiophene as nitrogen and sulfur precursors, respectively. The synthetic strategy allowed to obtain carbon materials with very high surface area and mesopore volume without any further physicochemical post treatment. Voltammetric rotating ring\u2010disk measurements in combination with potentiostatic and galvanostatic bulk electrolysis measurements in 0.5\u2009<jats:sc>m<\/jats:sc> H<jats:sub>2<\/jats:sub>SO<jats:sub>4<\/jats:sub> demonstrated a pronounced effect of heteroatom doping and mesopores volume on the catalytic activity and selectivity for H<jats:sub>2<\/jats:sub>O<jats:sub>2<\/jats:sub>. N\u2010RFC electrode was employed as electrode material in a 45\u2005h electrolysis showing a constant H<jats:sub>2<\/jats:sub>O<jats:sub>2<\/jats:sub> production of 298\u2005mmol\u2009g<jats:sup>\u22121<\/jats:sup>\u2009h<jats:sup>\u22121<\/jats:sup> (millimoles of H<jats:sub>2<\/jats:sub>O<jats:sub>2<\/jats:sub> divided by mass of catalyst and electrolysis time), with a faradic efficiency (FE) up to 61\u2009% and without any clear evidence of degradation. The undoped carbon RFC showed a lower production rate (218\u2005mmol\u2009g<jats:sup>\u22121<\/jats:sup>\u2009h<jats:sup>\u22121<\/jats:sup>) but a higher FE of 76\u2009%, while the performances drastically dropped when S\u2010RFC (production rate 11\u2005mmol\u2009g<jats:sup>\u22121<\/jats:sup>\u2009h<jats:sup>\u22121<\/jats:sup> and FE=39\u2009%) was used.<\/jats:p>","DOI":"10.1002\/chem.202003355","type":"journal-article","created":{"date-parts":[[2020,9,21]],"date-time":"2020-09-21T15:26:13Z","timestamp":1600701973000},"page":"1002-1014","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":34,"title":["PEO\u2010b\u2010PS Block Copolymer Templated Mesoporous Carbons: A Comparative Study of Nitrogen and Sulfur Doping in the Oxygen Reduction Reaction to Hydrogen Peroxide"],"prefix":"10.1002","volume":"27","author":[{"given":"Valentina","family":"Perazzolo","sequence":"first","affiliation":[{"name":"Department of Chemical Sciences University of Padua  Via Marzolo 1 35131 Padova Italy"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Giorgia","family":"Daniel","sequence":"additional","affiliation":[{"name":"Department of Chemical Sciences University of Padua  Via Marzolo 1 35131 Padova Italy"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Riccardo","family":"Brandiele","sequence":"additional","affiliation":[{"name":"Department of Chemical Sciences University of Padua  Via Marzolo 1 35131 Padova Italy"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Luca","family":"Picelli","sequence":"additional","affiliation":[{"name":"Department of Chemical Sciences University of Padua  Via Marzolo 1 35131 Padova Italy"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Gian Andrea","family":"Rizzi","sequence":"additional","affiliation":[{"name":"Department of Chemical Sciences University of Padua  Via Marzolo 1 35131 Padova Italy"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0966-1983","authenticated-orcid":false,"given":"Abdirisak Ahmed","family":"Isse","sequence":"additional","affiliation":[{"name":"Department of Chemical Sciences University of Padua  Via Marzolo 1 35131 Padova Italy"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8764-1219","authenticated-orcid":false,"given":"Christian","family":"Durante","sequence":"additional","affiliation":[{"name":"Department of Chemical Sciences University of Padua  Via Marzolo 1 35131 Padova Italy"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2020,12,3]]},"reference":[{"key":"e_1_2_7_1_1","doi-asserted-by":"publisher","DOI":"10.1002\/cssc.201600895"},{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.rser.2019.04.082"},{"key":"e_1_2_7_3_1","first-page":"31","volume-title":"Pulp Pap. 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