{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,10,13]],"date-time":"2025-10-13T20:03:19Z","timestamp":1760385799520,"version":"build-2065373602"},"reference-count":45,"publisher":"Wiley","issue":"4","license":[{"start":{"date-parts":[[2020,11,18]],"date-time":"2020-11-18T00:00:00Z","timestamp":1605657600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/100007397","name":"Univerzita Karlova v Praze","doi-asserted-by":"publisher","award":["UNCE\/SCI\/014"],"award-info":[{"award-number":["UNCE\/SCI\/014"]}],"id":[{"id":"10.13039\/100007397","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100007543","name":"Grantov\u00e1 Agentura, Univerzita Karlova","doi-asserted-by":"publisher","award":["920119"],"award-info":[{"award-number":["920119"]}],"id":[{"id":"10.13039\/100007543","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Chemistry A European J"],"published-print":{"date-parts":[[2021,1,18]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>(Ferrocenylmethyl)phosphane (<jats:bold>1<\/jats:bold>) oxidation with hydrogen peroxide, elemental sulfur and grey selenium produced (ferrocenylmethyl)phosphane oxide <jats:bold>1O<\/jats:bold>, sulfide <jats:bold>1S<\/jats:bold> and selenide <jats:bold>1Se<\/jats:bold>, respectively, as the first <jats:italic>isolable<\/jats:italic> primary phosphane chalcogenides lacking steric protection. At elevated temperatures, compound\u2005<jats:bold>1O<\/jats:bold> disproportionated into <jats:bold>1<\/jats:bold> and (ferrocenylmethyl)phosphinic acid. In reactions with [(\u03b7<jats:sup>6<\/jats:sup>\u2010mes)RuCl<jats:sub>2<\/jats:sub>]<jats:sub>2<\/jats:sub>, <jats:bold>1O<\/jats:bold> underwent tautomerization into a phosphane complex [(\u03b7<jats:sup>6<\/jats:sup>\u2010mes)RuCl<jats:sub>2<\/jats:sub>{FcCH<jats:sub>2<\/jats:sub>PH(OH)\u2010<jats:italic>\u03baP<\/jats:italic>}], whereas <jats:bold>1S<\/jats:bold> and <jats:bold>1Se<\/jats:bold> lost their P\u2010bound chalcogen atoms, giving rise to the phosphane complex [(\u03b7<jats:sup>6<\/jats:sup>\u2010mes)RuCl<jats:sub>2<\/jats:sub>(FcCH<jats:sub>2<\/jats:sub>PH<jats:sub>2<\/jats:sub>\u2010<jats:italic>\u03baP<\/jats:italic>)] (Fc=ferrocenyl, mes=mesitylene). No tautomerization was observed in the reaction of <jats:bold>1O<\/jats:bold> with B(C<jats:sub>6<\/jats:sub>F<jats:sub>5<\/jats:sub>)<jats:sub>3<\/jats:sub>, which instead produced a Lewis pair FcCH<jats:sub>2<\/jats:sub>P(O)H<jats:sub>2<\/jats:sub>\u2010B(C<jats:sub>6<\/jats:sub>F<jats:sub>5<\/jats:sub>)<jats:sub>3<\/jats:sub>. Phosphane oxide <jats:bold>1O<\/jats:bold> added to C=O bonds of aldehydes and ketones and even to cumulenes PhNCE (E=O and S). However, both PH hydrogens were only employed in the reactions with aldehydes and cyanates.<\/jats:p>","DOI":"10.1002\/chem.202003702","type":"journal-article","created":{"date-parts":[[2020,9,2]],"date-time":"2020-09-02T15:18:51Z","timestamp":1599059931000},"page":"1282-1285","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":12,"title":["A Stable Primary Phosphane Oxide and Its Heavier Congeners"],"prefix":"10.1002","volume":"27","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-1910-7516","authenticated-orcid":false,"given":"Filip","family":"Hork\u00fd","sequence":"first","affiliation":[{"name":"Department of Inorganic Chemistry Faculty of Science Charles University  Hlavova 2030 128 40 Prague Czech Republic"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9612-9831","authenticated-orcid":false,"given":"Ivana","family":"C\u00edsa\u0159ov\u00e1","sequence":"additional","affiliation":[{"name":"Department of Inorganic Chemistry Faculty of Science Charles University  Hlavova 2030 128 40 Prague Czech Republic"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5966-0578","authenticated-orcid":false,"given":"Petr","family":"\u0160t\u011bpni\u010dka","sequence":"additional","affiliation":[{"name":"Department of Inorganic Chemistry Faculty of Science Charles University  Hlavova 2030 128 40 Prague Czech Republic"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2020,11,18]]},"reference":[{"key":"e_1_2_2_1_1","unstructured":"\u00a0"},{"key":"e_1_2_2_2_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2005.03.007"},{"key":"e_1_2_2_3_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2015.03.002"},{"key":"e_1_2_2_4_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0040-4039(00)88307-0"},{"key":"e_1_2_2_5_1","unstructured":"\u00a0"},{"key":"e_1_2_2_6_2","first-page":"95","volume-title":"A Guide to Organophosphorus Chemistry","author":"Quin L. 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