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In contrast, reactions using an organotin sulfide cluster with another core structure, [(R<jats:sup><jats:italic>N<\/jats:italic><\/jats:sup>Sn)<jats:sub>3<\/jats:sub>S<jats:sub>4<\/jats:sub>Cl] (<jats:bold>A<\/jats:bold>), leads to formation of small molecular fragments, [(R<jats:sup><jats:italic>pyr<\/jats:italic><\/jats:sup>Cl<jats:sub>2<\/jats:sub>Sn)<jats:sub>2<\/jats:sub>S] (<jats:bold>1<\/jats:bold>), (pyren\u20101\u2010ylmethylene)hydrazine (<jats:bold>2<\/jats:bold>), and 1,2\u2010bis(pyren\u20101\u2010ylmethylene)hydrazine (<jats:bold>3<\/jats:bold>). Besides synthesis and structures of the new compounds, we report the influence of the inorganic core on the optical properties of the dye, which was analyzed exemplarily for compound\u2005<jats:bold>5\u2009a<\/jats:bold> via absorption and fluorescence spectroscopy. This cluster was also used for exploring the potential of such non\u2010volatile clusters for deposition on a metal surface under vacuum conditions.<\/jats:p>","DOI":"10.1002\/chem.202003889","type":"journal-article","created":{"date-parts":[[2020,9,16]],"date-time":"2020-09-16T18:16:47Z","timestamp":1600280207000},"page":"2734-2741","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":4,"title":["Pyrene\u2010Terminated Tin Sulfide Clusters: Optical Properties and Deposition on a Metal Surface"],"prefix":"10.1002","volume":"27","author":[{"given":"Eugenie","family":"Geringer","sequence":"first","affiliation":[{"name":"Fachbereich Chemie und Wissenschaftliches Zentrum f\u00fcr, Materialwissenschaften (WZMW) Philipps-Universit\u00e4t Marburg  Hans-Meerwein-Str. 4 35043 Marburg Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Marina","family":"Gerhard","sequence":"additional","affiliation":[{"name":"Fachbereich Physik and Wissenschaftliches Zentrum f\u00fcr, Materialwissenschaften (WZMW) Philipps-Universit\u00e4t Marburg  Renthof 5 35032 Marburg Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"M.","family":"Koch","sequence":"additional","affiliation":[{"name":"Fachbereich Physik and Wissenschaftliches Zentrum f\u00fcr, Materialwissenschaften (WZMW) Philipps-Universit\u00e4t Marburg  Renthof 5 35032 Marburg Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Claudio K.","family":"Krug","sequence":"additional","affiliation":[{"name":"Fachbereich Chemie und Wissenschaftliches Zentrum f\u00fcr, Materialwissenschaften (WZMW) Philipps-Universit\u00e4t Marburg  Hans-Meerwein-Str. 4 35043 Marburg Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"J. 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