{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,2]],"date-time":"2026-10-02T06:26:32Z","timestamp":1790922392975,"version":"4.1.0"},"reference-count":59,"publisher":"Wiley","issue":"18","license":[{"start":{"date-parts":[[2021,1,28]],"date-time":"2021-01-28T00:00:00Z","timestamp":1611792000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100004281","name":"Narodowe Centrum Nauki","doi-asserted-by":"publisher","award":["OPUS DEC-2017\/27\/B\/ST5\/02329"],"award-info":[{"award-number":["OPUS DEC-2017\/27\/B\/ST5\/02329"]}],"id":[{"id":"10.13039\/501100004281","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100004281","name":"Narodowe Centrum Nauki","doi-asserted-by":"publisher","award":["PRELUDIUM DEC-2015\/17\/N\/ST5\/03657"],"award-info":[{"award-number":["PRELUDIUM DEC-2015\/17\/N\/ST5\/03657"]}],"id":[{"id":"10.13039\/501100004281","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Chemistry A European J"],"published-print":{"date-parts":[[2021,3,26]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Simple RZnOR\u2019 alkoxides are among the first known organozinc compounds, and widespread interest in their multifaced chemistry has been driven by their fundamental significance and potential applications including various catalytic reactions. Nevertheless, their chemistry in solution and in the solid state remains both relatively poorly understood and a subject of constant debate. Herein, the synthesis and structural characterization of long\u2010sought structural forms, a roof\u2010like trimer [(\n                    <jats:italic>t<\/jats:italic>\n                    BuZn)\n                    <jats:sub>3<\/jats:sub>\n                    (\u03bc\u2010OC(H)Ph\n                    <jats:sub>2<\/jats:sub>\n                    )\n                    <jats:sub>2<\/jats:sub>\n                    (\u03bc\n                    <jats:sub>3<\/jats:sub>\n                    \u2010OC(H)Ph\n                    <jats:sub>2<\/jats:sub>\n                    )] and a ladder\u2010type tetramer [(PhZn)\n                    <jats:sub>4<\/jats:sub>\n                    (\u03bc\u2010OC(H)Ph\n                    <jats:sub>2<\/jats:sub>\n                    )\n                    <jats:sub>2<\/jats:sub>\n                    (\u03bc\n                    <jats:sub>3<\/jats:sub>\n                    \u2010OC(H)Ph\n                    <jats:sub>2<\/jats:sub>\n                    )\n                    <jats:sub>2<\/jats:sub>\n                    ], incorporating diphenylmethanolate as a model alkoxide ligand, are reported. Both novel aggregates are robust in the solid state and resistant towards mechanical force. By using\n                    <jats:sup>1<\/jats:sup>\n                    H\u2005NMR and diffusion\u2010order spectroscopy, it is demonstrated that new RZnOR\u2019 alkoxides are kinetically labile in solution and readily undergo ligand scrambling, such as in the case of Schlenk equilibrium. The elucidated key structural issues, which have remained undiscovered for decades, significantly advance the chemistry of RZnOR\u2019 alkoxides and should support the rational design of zinc alkoxide\u2010based applications.\n                  <\/jats:p>","DOI":"10.1002\/chem.202004222","type":"journal-article","created":{"date-parts":[[2020,11,13]],"date-time":"2020-11-13T05:59:14Z","timestamp":1605247154000},"page":"5666-5674","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":21,"title":["Unravelling Structural Mysteries of Simple Organozinc Alkoxides"],"prefix":"10.1002","volume":"27","author":[{"given":"\u0141ukasz","family":"M\u0105kolski","sequence":"first","affiliation":[{"name":"Faculty of Chemistry Warsaw University of Technology  Noakowskiego 3 00-664 Warsaw Poland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7787-7084","authenticated-orcid":false,"given":"Vadim","family":"Szejko","sequence":"additional","affiliation":[{"name":"Faculty of Chemistry Warsaw University of Technology  Noakowskiego 3 00-664 Warsaw Poland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0313-4066","authenticated-orcid":false,"given":"Karolina","family":"Zelga","sequence":"additional","affiliation":[{"name":"Faculty of Chemistry Warsaw University of Technology  Noakowskiego 3 00-664 Warsaw Poland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7390-7346","authenticated-orcid":false,"given":"Adam","family":"Tulewicz","sequence":"additional","affiliation":[{"name":"Institute of Physical Chemistry Polish Academy of Science  Kasprzaka 44\/52 01-224 Warsaw Poland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8891-0380","authenticated-orcid":false,"given":"Piotr","family":"Bernatowicz","sequence":"additional","affiliation":[{"name":"Institute of Physical Chemistry Polish Academy of Science  Kasprzaka 44\/52 01-224 Warsaw Poland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4392-0267","authenticated-orcid":false,"given":"Iwona","family":"Justyniak","sequence":"additional","affiliation":[{"name":"Institute of Physical Chemistry Polish Academy of Science  Kasprzaka 44\/52 01-224 Warsaw Poland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3407-0395","authenticated-orcid":false,"given":"Janusz","family":"Lewi\u0144ski","sequence":"additional","affiliation":[{"name":"Faculty of Chemistry Warsaw University of Technology  Noakowskiego 3 00-664 Warsaw Poland"},{"name":"Institute of Physical Chemistry Polish Academy of Science  Kasprzaka 44\/52 01-224 Warsaw Poland"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2021,1,28]]},"reference":[{"key":"e_1_2_7_1_1","doi-asserted-by":"publisher","DOI":"10.1038\/1821211b0"},{"key":"e_1_2_7_2_1","volume-title":"The Chemistry of Metal Alkoxides","author":"Turova N. Y.","year":"2002"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1002\/jlac.18490710205"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1039\/jr9650001870"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1039\/j29660000799"},{"key":"e_1_2_7_6_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja01022a011"},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja036020t"},{"key":"e_1_2_7_8_1","doi-asserted-by":"publisher","DOI":"10.1021\/ic062438r"},{"key":"e_1_2_7_9_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200601001"},{"key":"e_1_2_7_9_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200601001"},{"key":"e_1_2_7_10_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201004504"},{"key":"e_1_2_7_10_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201004504"},{"key":"e_1_2_7_11_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201402875"},{"key":"e_1_2_7_12_1","first-page":"194","author":"Shearer H. M. M.","year":"1966","journal-title":"Chem. Commun."},{"key":"e_1_2_7_13_1","doi-asserted-by":"publisher","DOI":"10.1246\/bcsj.39.1828"},{"key":"e_1_2_7_14_1","doi-asserted-by":"publisher","DOI":"10.1107\/S056774088000790X"},{"key":"e_1_2_7_15_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja00009a024"},{"key":"e_1_2_7_16_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja010837"},{"key":"e_1_2_7_17_1","doi-asserted-by":"publisher","DOI":"10.1021\/cm0493997"},{"key":"e_1_2_7_18_1","doi-asserted-by":"publisher","DOI":"10.1039\/b405362a"},{"key":"e_1_2_7_19_1","doi-asserted-by":"publisher","DOI":"10.1021\/om060867r"},{"key":"e_1_2_7_20_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jorganchem.2007.10.043"},{"key":"e_1_2_7_21_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja00193a040"},{"key":"e_1_2_7_22_1","doi-asserted-by":"publisher","DOI":"10.1039\/C8MH00106E"},{"key":"e_1_2_7_23_1","doi-asserted-by":"publisher","DOI":"10.1038\/378767a0"},{"key":"e_1_2_7_24_1","doi-asserted-by":"publisher","DOI":"10.1021\/ar5003208"},{"key":"e_1_2_7_25_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201403851"},{"key":"e_1_2_7_26_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200503068"},{"key":"e_1_2_7_26_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200503068"},{"key":"e_1_2_7_27_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja804071h"},{"key":"e_1_2_7_28_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201406245"},{"key":"e_1_2_7_29_1","doi-asserted-by":"publisher","DOI":"10.1039\/C7CC05818G"},{"key":"e_1_2_7_30_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41557-020-0421-8"},{"key":"e_1_2_7_31_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.202003260"},{"key":"e_1_2_7_32_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.200400085"},{"key":"e_1_2_7_33_1","doi-asserted-by":"publisher","DOI":"10.1039\/jm9940401249"},{"key":"e_1_2_7_34_1","doi-asserted-by":"publisher","DOI":"10.1039\/b306163a"},{"key":"e_1_2_7_35_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr000411y"},{"key":"e_1_2_7_36_1","doi-asserted-by":"publisher","DOI":"10.1002\/ejic.200300265"},{"key":"e_1_2_7_37_1","doi-asserted-by":"publisher","DOI":"10.1073\/pnas.0308178101"},{"key":"e_1_2_7_38_1","doi-asserted-by":"publisher","DOI":"10.1021\/ic048332i"},{"key":"e_1_2_7_39_1","doi-asserted-by":"publisher","DOI":"10.1002\/asia.201000317"},{"key":"e_1_2_7_40_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.mencom.2017.07.006"},{"key":"e_1_2_7_41_1","doi-asserted-by":"publisher","DOI":"10.1002\/1099-0682(200012)2000:12<2517::AID-EJIC2517>3.0.CO;2-V"},{"key":"e_1_2_7_42_1","doi-asserted-by":"publisher","DOI":"10.1002\/ejic.200390006"},{"key":"e_1_2_7_43_1","doi-asserted-by":"publisher","DOI":"10.1002\/1521-3773(20020402)41:7<1226::AID-ANIE1226>3.0.CO;2-N"},{"key":"e_1_2_7_43_2","doi-asserted-by":"publisher","DOI":"10.1002\/1521-3757(20020402)114:7<1274::AID-ANGE1274>3.0.CO;2-5"},{"key":"e_1_2_7_44_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.199605191"},{"key":"e_1_2_7_44_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.19961080508"},{"key":"e_1_2_7_45_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201105127"},{"key":"e_1_2_7_45_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201105127"},{"key":"e_1_2_7_46_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja00195a027"},{"key":"e_1_2_7_47_1","doi-asserted-by":"publisher","DOI":"10.1039\/cs9912000167"},{"key":"e_1_2_7_48_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0DT03026K"},{"key":"e_1_2_7_49_1","unstructured":"Deposition numbers 2026992 (for13) 2026994 (for24lad) 2026993 (for24cub) 2026995 (for3) and 2026996 (for4)contain the supplementary crystallographic data for this paper. These data are provided free of charge by the joint Cambridge Crystallographic Data Centre and Fachinformationszentrum Karlsruhe Access Structures servicewww.ccdc.cam.ac.uk\/structures.."},{"key":"e_1_2_7_50_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja067229k"},{"key":"e_1_2_7_51_1","unstructured":"CrysAlisPro Data Collection and Processing Software for Agilent X-ray Diffractometers ver. 1.171.35.21b Agilent Technologies 2012."},{"key":"e_1_2_7_52_1","doi-asserted-by":"publisher","DOI":"10.1107\/S0108767307043930"},{"key":"e_1_2_7_53_1","doi-asserted-by":"publisher","DOI":"10.1107\/S2053273314022207"}],"container-title":["Chemistry \u2013 A European Journal"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/chem.202004222","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/chem.202004222","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/chem.202004222","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,12]],"date-time":"2025-10-12T17:47:07Z","timestamp":1760291227000},"score":1,"resource":{"primary":{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/10.1002\/chem.202004222"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2021,1,28]]},"references-count":59,"journal-issue":{"issue":"18","published-print":{"date-parts":[[2021,3,26]]}},"alternative-id":["10.1002\/chem.202004222"],"URL":"https:\/\/doi.org\/10.1002\/chem.202004222","archive":["Portico"],"relation":{},"ISSN":["0947-6539","1521-3765"],"issn-type":[{"value":"0947-6539","type":"print"},{"value":"1521-3765","type":"electronic"}],"subject":[],"published":{"date-parts":[[2021,1,28]]},"assertion":[{"value":"2020-09-16","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2021-01-28","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}]}}