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In this paper, complexation of the phosphanoxy\u2010substituted phosphaalkenes with gold are investigated, and the catalytic activity of the mono\u2010 and bis(chlorogold) complexes are subsequently evaluated. Reaction of the P=C\u2212O\u2212P compound with (tht)AuCl (tht=tetrahydrothiophene) showed dominant coordination on the sp<jats:sup>3<\/jats:sup> phosphorus, and complete coordination on the sp<jats:sup>2<\/jats:sup> phosphorus required removal of tetrahydrothiophene. Atoms In Molecules (AIM) analysis based on the X\u2010ray structure of the mono(chlorogold) complex indicated a pseudo coordinating interaction between the gold center and the P=C unit. The bis(chlorogold) complexes displayed conformational isomerism, and catalyzed the cycloisomerization\/alkoxycyclization of 1,6\u2010enyne and for hydration of terminal alkyne without activation treatment. Even the mono(chlorogold) complexes catalyzed the alkoxycyclization reactions without a silver co\u2010catalyst, indicating that the alcohols were effective in activating the AuCl unit.<\/jats:p>","DOI":"10.1002\/chem.202004281","type":"journal-article","created":{"date-parts":[[2020,10,20]],"date-time":"2020-10-20T08:53:33Z","timestamp":1603184013000},"page":"2469-2475","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":12,"title":["Gold(I) Complexation of Phosphanoxy\u2010Substituted Phosphaalkenes for Activation\u2010Free LAuCl Catalysis"],"prefix":"10.1002","volume":"27","author":[{"given":"Miki","family":"Kato","sequence":"first","affiliation":[{"name":"Department of Applied Chemistry School of Materials and Chemical Technology Tokyo Institute of Technology  2-12-1-H113 Ookayama, Meguro-ku Tokyo 1528552 Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yasuhiro","family":"Ueta","sequence":"additional","affiliation":[{"name":"Department of Applied Chemistry School of Materials and Chemical Technology Tokyo Institute of Technology  2-12-1-H113 Ookayama, Meguro-ku Tokyo 1528552 Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5737-8499","authenticated-orcid":false,"given":"Shigekazu","family":"Ito","sequence":"additional","affiliation":[{"name":"Department of Applied Chemistry School of Materials and Chemical Technology Tokyo Institute of Technology  2-12-1-H113 Ookayama, Meguro-ku Tokyo 1528552 Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2020,12,23]]},"reference":[{"key":"e_1_2_7_1_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr100133q"},{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja00483a041"},{"key":"e_1_2_7_3_1","unstructured":"\u00a0"},{"key":"e_1_2_7_4_2","volume-title":"Phosphorus: The Carbon Copy","author":"Dillon K. 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