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Upon methylation or protonation, the emission maxima are significantly bathochromically shifted compared to the neutral compounds, although the absorption maxima remain almost unchanged. As a result, the cationic compounds show very large apparent Stokes shifts of up to 7200\u2005cm\n                    <jats:sup>\u22121<\/jats:sup>\n                    . The\n                    <jats:italic>N<\/jats:italic>\n                    \u2010methylpyridinium compounds have a single reduction at ca. \u22121.5\u2005V vs. Fc\/Fc\n                    <jats:sup>+<\/jats:sup>\n                    in MeCN. While the reduction process was reversible for the 2,7\u2010disubstituted compound, it was irreversible for the mono\u2010substituted one. Experimental findings are complemented by DFT and TD\u2010DFT calculations. Furthermore, the\n                    <jats:italic>N<\/jats:italic>\n                    \u2010methylpyridinium compounds show strong interactions with calf thymus (ct)\u2010DNA, presumably by intercalation, which paves the way for further applications of these multi\u2010functional compounds as potential DNA\u2010bioactive agents.\n                  <\/jats:p>","DOI":"10.1002\/chem.202004748","type":"journal-article","created":{"date-parts":[[2020,11,24]],"date-time":"2020-11-24T22:54:21Z","timestamp":1606258461000},"page":"2837-2853","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":36,"title":["2\u2010 and 2,7\u2010Substituted\n                    <i>para<\/i>\n                    \u2010\n                    <i>N<\/i>\n                    \u2010Methylpyridinium Pyrenes: Syntheses, Molecular and Electronic Structures, Photophysical, Electrochemical, and Spectroelectrochemical Properties and Binding to Double\u2010Stranded (ds) 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