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Zr\u2010abtc demonstrated advantages in both substrate conversion and product selectivity for epoxidation of electron\u2010deficient C=C bonds in \u03b1,\u03b2\u2010unsaturated ketones. The significant predominance of 1,2\u2010epoxide in carvone epoxidation, coupled with high sulfone selectivity in thioether oxidation, points to a nucleophilic oxidation mechanism over Zr\u2010abtc. The superior catalytic performance in the epoxidation of unsaturated ketones correlates with a larger amount of weak basic sites in Zr\u2010abtc. Electrophilic activation of H<jats:sub>2<\/jats:sub>O<jats:sub>2<\/jats:sub> can also be realized, as evidenced by the high activity of Zr\u2010abtc in epoxidation of the electron\u2010rich C=C bond in caryophyllene. XRD and FTIR studies confirmed the retention of the Zr\u2010abtc structure after the catalysis. The low activity of MIP\u2010200 in H<jats:sub>2<\/jats:sub>O<jats:sub>2<\/jats:sub>\u2010based oxidations is most likely related to its specific hydrophilicity, which disfavors adsorption of organic substrates and H<jats:sub>2<\/jats:sub>O<jats:sub>2<\/jats:sub>.<\/jats:p>","DOI":"10.1002\/chem.202005152","type":"journal-article","created":{"date-parts":[[2021,2,9]],"date-time":"2021-02-09T09:33:41Z","timestamp":1612863221000},"page":"6985-6992","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":28,"title":["Catalytic Performance of Zr\u2010Based Metal\u2013Organic Frameworks Zr\u2010abtc and MIP\u2010200 in Selective Oxidations with H<sub>2<\/sub>O<sub>2<\/sub>"],"prefix":"10.1002","volume":"27","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-7810-8220","authenticated-orcid":false,"given":"Nataliya V.","family":"Maksimchuk","sequence":"first","affiliation":[{"name":"Boreskov Institute of Catalysis  pr. 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Lavrentieva 5 Novosibirsk 630090 Russia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6555-095X","authenticated-orcid":false,"given":"Vasiliy Yu.","family":"Evtushok","sequence":"additional","affiliation":[{"name":"Boreskov Institute of Catalysis  pr. Lavrentieva 5 Novosibirsk 630090 Russia"},{"name":"Department of Natural Sciences Novosibirsk State University  Pirgova str. 2 Novosibirsk 630090 Russia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kirill P.","family":"Larionov","sequence":"additional","affiliation":[{"name":"Boreskov Institute of Catalysis  pr. Lavrentieva 5 Novosibirsk 630090 Russia"},{"name":"Department of Natural Sciences Novosibirsk State University  Pirgova str. 2 Novosibirsk 630090 Russia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8366-9698","authenticated-orcid":false,"given":"Tatiana S.","family":"Glazneva","sequence":"additional","affiliation":[{"name":"Boreskov Institute of Catalysis  pr. Lavrentieva 5 Novosibirsk 630090 Russia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3640-8190","authenticated-orcid":false,"given":"Jong\u2010San","family":"Chang","sequence":"additional","affiliation":[{"name":"Research Center for Nanocatalysts Korea Research Institute of Chemical Technology  P.O. 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