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The reaction with zinc(II) acetate hydrate led to the related MOF <jats:bold>Zn(3,3\u2019\u2010L)<\/jats:bold>. The compound is isostructural with its mono(amino) analogue Zn(BPZNH<jats:sub>2<\/jats:sub>) and with <jats:bold>Zn(3,5\u2010L)<\/jats:bold>, its isomeric parent built with 3,5\u2010diamino\u20104,4\u2019\u2010bipyrazole. The textural analysis has unveiled its micro\u2010\/mesoporous nature, with a BET area of 463\u2005m<jats:sup>2<\/jats:sup>\u2009g<jats:sup>\u22121<\/jats:sup>. Its CO<jats:sub>2<\/jats:sub> adsorption capacity (17.4\u2005wt.\u2009% CO<jats:sub>2<\/jats:sub> at <jats:italic>p<\/jats:italic><jats:sub>CO2<\/jats:sub> = 1\u2005bar and <jats:italic>T<\/jats:italic> = 298\u2005K) and isosteric heat of adsorption (<jats:italic>Q<\/jats:italic><jats:sub>st<\/jats:sub> = 24.8\u2005kJ\u2009mol<jats:sup>\u22121<\/jats:sup>) are comparable to that of <jats:bold>Zn(3,5\u2010L)<\/jats:bold>. Both <jats:bold>Zn(3,3\u2019\u2010L)<\/jats:bold> and <jats:bold>Zn(3,5\u2010L)<\/jats:bold> have been tested as heterogeneous catalysts in the reaction of CO<jats:sub>2<\/jats:sub> with the epoxides epichlorohydrin and epibromohydrin to give the corresponding cyclic carbonates at <jats:italic>T<\/jats:italic> = 393\u2005K and <jats:italic>p<\/jats:italic><jats:sub>CO2<\/jats:sub> = 5\u2005bar under solvent\u2010 and co\u2010catalyst\u2010free conditions. In general, the conversions recorded are higher than those found for Zn(BPZNH<jats:sub>2<\/jats:sub>), proving that the insertion of an extra amino tag in the pores is beneficial for the epoxidation catalysis. The best catalytic match has been observed for the <jats:bold>Zn(3,5\u2010L)<\/jats:bold>\/epichlorohydrin couple, with 64\u2009% conversion and a TOF of 5.3\u2005mmol(carbonate)\u2009(mmol<jats:sub>Zn<\/jats:sub>)<jats:sup>\u22121<\/jats:sup>\u2009h<jats:sup>\u22121<\/jats:sup>. To gain better insights on the MOF\u2010epoxide interaction, the crystal structure of the [epibromohydrin@<jats:bold>Zn(3,3\u2019\u2010L)<\/jats:bold>] adduct has been solved, confirming the existence of Br\u22c5\u22c5\u22c5(H)\u2212N non\u2010bonding interactions. To our knowledge, this study represents the first structural determination of a [epibromohydrin@MOF] adduct.<\/jats:p>","DOI":"10.1002\/chem.202005216","type":"journal-article","created":{"date-parts":[[2020,12,28]],"date-time":"2020-12-28T11:20:06Z","timestamp":1609154406000},"page":"4746-4754","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":23,"title":["Carbon Dioxide Capture and Utilization with Isomeric Forms of Bis(amino)\u2010Tagged Zinc Bipyrazolate Metal\u2013Organic Frameworks"],"prefix":"10.1002","volume":"27","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-2467-6342","authenticated-orcid":false,"given":"Giorgio","family":"Mercuri","sequence":"first","affiliation":[{"name":"Istituto di Chimica dei Composti Organometallici (ICCOM-CNR)  Via Madonna del Piano 10 50019 Sesto Fiorentino Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6167-3792","authenticated-orcid":false,"given":"Marco","family":"Moroni","sequence":"additional","affiliation":[{"name":"Dipartimento di Scienza e Alta Tecnologia Universit\u00e0 dell'Insubria  Via Valleggio 11 22100 Como Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kostiantyn V.","family":"Domasevitch","sequence":"additional","affiliation":[{"name":"Taras Shevchenko National University of Kyiv  Volodymyrska Str. 64\/13 01601 Kyiv Ukraine"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0958-6103","authenticated-orcid":false,"given":"Corrado","family":"Di Nicola","sequence":"additional","affiliation":[{"name":"Scuola di Scienze e Tecnologie Universit\u00e0 di Camerino  Via S. 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Agostino 1 62032 Camerino Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0315-3286","authenticated-orcid":false,"given":"Giuliano","family":"Giambastiani","sequence":"additional","affiliation":[{"name":"Istituto di Chimica dei Composti Organometallici (ICCOM-CNR)  Via Madonna del Piano 10 50019 Sesto Fiorentino Italy"},{"name":"Institute of Chemistry and Processes for Energy, Environment and Health (ICPEES) UMR 7515 CNRS-University of Strasbourg (UdS)  25, rue Becquerel 67087 Strasbourg Cedex 02 France"},{"name":"Alexander Butlerov Institute of Chemistry Kazan Federal University  420008 Kazan Russian Federation"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0335-5707","authenticated-orcid":false,"given":"Simona","family":"Galli","sequence":"additional","affiliation":[{"name":"Dipartimento di Scienza e Alta Tecnologia Universit\u00e0 dell'Insubria  Via Valleggio 11 22100 Como Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1283-2803","authenticated-orcid":false,"given":"Andrea","family":"Rossin","sequence":"additional","affiliation":[{"name":"Istituto di Chimica dei Composti Organometallici (ICCOM-CNR)  Via Madonna del Piano 10 50019 Sesto Fiorentino Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2021,2,15]]},"reference":[{"key":"e_1_2_7_1_1","unstructured":"\u00a0"},{"key":"e_1_2_7_2_2","doi-asserted-by":"publisher","DOI":"10.1039\/C4EE01647E"},{"key":"e_1_2_7_3_2","doi-asserted-by":"publisher","DOI":"10.1039\/c2ee03403d"},{"key":"e_1_2_7_4_2","doi-asserted-by":"publisher","DOI":"10.1039\/B912904A"},{"key":"e_1_2_7_5_1","unstructured":"\u00a0"},{"key":"e_1_2_7_6_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr4002758"},{"key":"e_1_2_7_7_2","doi-asserted-by":"publisher","DOI":"10.1039\/c2ee02774g"},{"key":"e_1_2_7_8_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr068357u"},{"key":"e_1_2_7_9_1","unstructured":"\u00a0"},{"key":"e_1_2_7_10_2","doi-asserted-by":"publisher","DOI":"10.1002\/cssc.201700748"},{"key":"e_1_2_7_11_2","doi-asserted-by":"publisher","DOI":"10.1002\/smll.201602711"},{"key":"e_1_2_7_12_2","volume-title":"Metal\u2013Organic Framework Materials","author":"MacGillivray L. 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Bond lengths and angles for the rigid body describing epibromohydrin: C\u2212C and C\u2212O of the epoxide ring 1.44\u2005\u00c5; exocyclic C\u2212C 1.50\u2005\u00c5; C\u2212Br 1.94\u2005\u00c5; C\u2212H 0.95\u2005\u00c5; epoxide ring internal bond angles 60\u00b0; exocyclic O-C-H and O-C-C angles 116\u00b0; angles around the sp3exocyclic carbon 109.5\u00b0."},{"key":"e_1_2_7_31_1","doi-asserted-by":"publisher","DOI":"10.1107\/S0021889891010804"},{"key":"e_1_2_7_32_1","unstructured":"\u00a0"},{"key":"e_1_2_7_33_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5b10266"},{"key":"e_1_2_7_34_2","first-page":"49","volume-title":"Studies in Surface Science and Catalysis, Vol.\u2005160","author":"Rouquerol J.","year":"2007"},{"key":"e_1_2_7_35_1","unstructured":"\u00a0"},{"key":"e_1_2_7_36_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.6b07644"},{"key":"e_1_2_7_37_2","doi-asserted-by":"publisher","DOI":"10.1039\/c4cc01588f"},{"key":"e_1_2_7_38_1","doi-asserted-by":"publisher","DOI":"10.1007\/s10450-011-9382-y"},{"key":"e_1_2_7_39_1","volume-title":"Infrared and Raman Spectra of Inorganic and Coordination Compounds","author":"Nakamoto K.","year":"2009"},{"key":"e_1_2_7_40_1","doi-asserted-by":"publisher","DOI":"10.1021\/cg500498k"},{"key":"e_1_2_7_41_1","doi-asserted-by":"publisher","DOI":"10.1039\/C6CC03026B"},{"key":"e_1_2_7_42_1","unstructured":"\u00a0"},{"key":"e_1_2_7_43_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5b07925"},{"key":"e_1_2_7_44_2","doi-asserted-by":"publisher","DOI":"10.1039\/c2jm33269h"},{"key":"e_1_2_7_45_1","unstructured":"\u00a0"},{"key":"e_1_2_7_46_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.cgd.7b00471"},{"key":"e_1_2_7_47_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic3001416"},{"key":"e_1_2_7_48_1","unstructured":"\u00a0"},{"key":"e_1_2_7_49_2","doi-asserted-by":"publisher","DOI":"10.1039\/C9CC09664G"},{"key":"e_1_2_7_50_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.cgd.0c00258"},{"key":"e_1_2_7_51_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.9b03051"},{"key":"e_1_2_7_52_2","doi-asserted-by":"publisher","DOI":"10.1021\/acssuschemeng.6b02972"},{"key":"e_1_2_7_53_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.7b01286"},{"key":"e_1_2_7_54_2","doi-asserted-by":"publisher","DOI":"10.1039\/C7CC08315G"},{"key":"e_1_2_7_55_2","doi-asserted-by":"publisher","DOI":"10.1039\/C7CC08298C"},{"key":"e_1_2_7_56_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemmater.7b03183"},{"key":"e_1_2_7_57_2","doi-asserted-by":"publisher","DOI":"10.1039\/C6CC08773F"},{"key":"e_1_2_7_58_2","doi-asserted-by":"publisher","DOI":"10.1002\/smll.201503741"},{"key":"e_1_2_7_59_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.6b01569"},{"key":"e_1_2_7_60_2","first-page":"4373","author":"Sanjay K.","year":"2016","journal-title":"Eur. 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