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C\u2212N axial chiral iodine reagents are rarely investigated in the hypervalent iodine arena. The potential of the novel chiral iodoarenes as organocatalysts for stereoselective oxidative transformations is assessed using the well explored, but challenging stereoselective \u03b1\u2010oxytosylation of ketones. All investigated reagents catalyse the stereoselective oxidation of propiophenone to the corresponding chiral \u03b1\u2010oxytosylated products with good stereochemical control. Using the optimised reaction conditions a wide range of products was obtained in generally good to excellent yields and with good enantioselectivities.<\/jats:p>","DOI":"10.1002\/chem.202005253","type":"journal-article","created":{"date-parts":[[2021,1,15]],"date-time":"2021-01-15T01:17:31Z","timestamp":1610673451000},"page":"4317-4321","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":23,"title":["C\u2212N Axial Chiral Hypervalent Iodine Reagents: Catalytic Stereoselective \u03b1\u2010Oxytosylation of Ketones"],"prefix":"10.1002","volume":"27","author":[{"given":"Haifa","family":"Alharbi","sequence":"first","affiliation":[{"name":"School of Chemistry Cardiff University  Main Building, Park Place Cardiff CF10 3AT UK"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mohamed","family":"Elsherbini","sequence":"additional","affiliation":[{"name":"School of Chemistry Cardiff University  Main Building, Park Place Cardiff CF10 3AT UK"},{"name":"current address: Department of Chemistry University of Huddersfield  Queensgate Huddersfield HD1 3DH UK"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jihan","family":"Qurban","sequence":"additional","affiliation":[{"name":"School of Chemistry Cardiff University  Main Building, Park Place Cardiff CF10 3AT UK"},{"name":"current address: Department of Chemistry Faculty of Applied Science Umm Al-Qura University  Makkah Saudi Arabia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8990-0667","authenticated-orcid":false,"given":"Thomas","family":"Wirth","sequence":"additional","affiliation":[{"name":"School of Chemistry Cardiff University  Main Building, Park Place Cardiff CF10 3AT UK"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2021,2,8]]},"reference":[{"key":"e_1_2_2_1_1","unstructured":"\u00a0"},{"key":"e_1_2_2_2_2","doi-asserted-by":"publisher","DOI":"10.1002\/tcr.20104"},{"key":"e_1_2_2_3_2","doi-asserted-by":"publisher","DOI":"10.1039\/b821747e"},{"key":"e_1_2_2_4_2","volume-title":"Hypervalent Iodine Chemistry: Preparation, Structure, and Synthetic Applications of Polyvalent Iodine Compounds","author":"Zhdankin V. 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