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Zinc compounds have been showcased as catalysts for carbon dioxide hydrosilylation and hydroboration. The extent of carbon dioxide reduction can depend on various factors, including electrophilicity at the zinc center and the denticity of the ancillary ligands. In a few cases, the addition of Lewis acids to zinc hydride catalysts markedly influences carbon dioxide reduction. These factors have been investigated by exploring elementary reactions of carbon dioxide hydrosilylation and hydroboration by using cationic zinc hydrides bearing tetradentate tris[2\u2010(dimethylamino)ethyl]amine and tridentate\n                    <jats:italic>N<\/jats:italic>\n                    ,\n                    <jats:italic>N<\/jats:italic>\n                    ,\n                    <jats:italic>N<\/jats:italic>\n                    \u2032,\n                    <jats:italic>N<\/jats:italic>\n                    \u2032\u2032,\n                    <jats:italic>N<\/jats:italic>\n                    \u2032\u2032\u2010pentamethyldiethylenetriamine in the presence of triphenylborane and tris(pentafluorophenyl)borane.\n                  <\/jats:p>","DOI":"10.1002\/chem.202005392","type":"journal-article","created":{"date-parts":[[2021,1,18]],"date-time":"2021-01-18T09:12:35Z","timestamp":1610961155000},"page":"7391-7401","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":37,"title":["Cationic Zinc Hydride Catalyzed Carbon Dioxide Reduction to Formate: Deciphering Elementary Reactions, Isolation of Intermediates, and Computational Investigations"],"prefix":"10.1002","volume":"27","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-9830-2888","authenticated-orcid":false,"given":"Raju","family":"Chambenahalli","sequence":"first","affiliation":[{"name":"School of Chemistry Indian Institute of Science Education and Research, Thiruvananthapuram  Vithura, Thiruvananthapuram 695551 India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"R. 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