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In the present work, we employ standard quantum chemistry methods to characterize formation of previously unrecognized sulfur <jats:italic>tetra<\/jats:italic>hydride (<jats:italic>C<\/jats:italic><jats:sub>4<jats:italic>v<\/jats:italic><\/jats:sub>\u2010symmetric SH<jats:sub>4<\/jats:sub>) from hydrogen sulfide (H<jats:sub>2<\/jats:sub>S) and molecular hydrogen (H<jats:sub>2<\/jats:sub>) on the ground state potential energy surface. The unusual intramolecular interactions of SH<jats:sub>4<\/jats:sub> defy Lewis\u2010like bonding conceptions, exhibiting the dominance of resonance\u2010type donor\u2010acceptor delocalizations well beyond those of SF<jats:sub>4<\/jats:sub> (<jats:italic>C<\/jats:italic><jats:sub>2<jats:italic>v<\/jats:italic><\/jats:sub> sawhorse geometry) and other known tetrahalides. The distressed character of SH<jats:sub>4<\/jats:sub> bonding also leads to exotic intermolecular structural motifs in clusters of pure (SH<jats:sub>4<\/jats:sub>)<jats:sub><jats:italic>n<\/jats:italic><\/jats:sub> and mixed (SH<jats:sub>4<\/jats:sub>\u22c5\u22c5\u22c5H<jats:sub>2<\/jats:sub>S)<jats:sub><jats:italic>n<\/jats:italic><\/jats:sub> composition. We evaluate structural, spectroscopic, and electronic properties for various 2D\/3D coordination patterns and discuss how (SH<jats:sub>4<\/jats:sub>\u22c5\u22c5\u22c5H<jats:sub>2<\/jats:sub>S)<jats:sub><jats:italic>n<\/jats:italic><\/jats:sub>\u2010type building blocks may relate to recent experimental studies of superconductivity in high\u2010pressure materials of \u201cSH<jats:sub>3<\/jats:sub>\u201d stoichiometry.<\/jats:p>","DOI":"10.1002\/chem.202005420","type":"journal-article","created":{"date-parts":[[2021,2,10]],"date-time":"2021-02-10T11:12:48Z","timestamp":1612955568000},"page":"6748-6759","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["Sulfur Tetrahydride and Allied Superhydride Clusters: When\u2009Resonance Takes Precedence"],"prefix":"10.1002","volume":"27","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-9580-054X","authenticated-orcid":false,"given":"Frank","family":"Weinhold","sequence":"first","affiliation":[{"name":"Theoretical Chemistry Institute and Department of Chemistry University of Wisconsin-Madison  Madison WI 53706 USA"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2021,3,16]]},"reference":[{"key":"e_1_2_5_1_1","first-page":"405","volume":"12","author":"Mendelejev D.","year":"1869","journal-title":"Zeitschrift f. 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