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One of the complexes was found to be active in both the Leuckart\u2013Wallach (NH<jats:sub>4<\/jats:sub>CO<jats:sub>2<\/jats:sub>H) type reaction as well as in the hydrogenative (H<jats:sub>2<\/jats:sub>\/NH<jats:sub>4<\/jats:sub>AcO) reductive amination. The protocol with ammonium formate does not require an inert atmosphere, dry solvents, as well as additives and in contrast to previous reports takes place in hexafluoroisopropanol (HFIP) instead of methanol. Applying NH<jats:sub>4<\/jats:sub>CO<jats:sub>2<\/jats:sub>D or D<jats:sub>2<\/jats:sub> resulted in a high degree of deuterium incorporation into the primary amine \u03b1\u2010position.<\/jats:p>","DOI":"10.1002\/chem.202005508","type":"journal-article","created":{"date-parts":[[2021,1,28]],"date-time":"2021-01-28T20:49:52Z","timestamp":1611866992000},"page":"5919-5922","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":16,"title":["Air Stable Iridium Catalysts for Direct Reductive Amination of Ketones"],"prefix":"10.1002","volume":"27","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-8622-0455","authenticated-orcid":false,"given":"Iuliia","family":"Polishchuk","sequence":"first","affiliation":[{"name":"Institute of Organic Chemistry RWTH Aachen University  Landoltweg 1 Aachen Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Jan","family":"Sklyaruk","sequence":"additional","affiliation":[{"name":"Institute of Organic Chemistry RWTH Aachen University  Landoltweg 1 Aachen Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2985-6876","authenticated-orcid":false,"given":"Yury","family":"Lebedev","sequence":"additional","affiliation":[{"name":"KAUST Catalysis Center King Abdullah University of Science and Technology  Thuwal Saudi Arabia"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4580-5227","authenticated-orcid":false,"given":"Magnus","family":"Rueping","sequence":"additional","affiliation":[{"name":"Institute of Organic Chemistry RWTH Aachen University  Landoltweg 1 Aachen Germany"},{"name":"KAUST Catalysis Center King Abdullah University of Science and Technology  Thuwal Saudi Arabia"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2021,3,3]]},"reference":[{"key":"e_1_2_2_1_1","unstructured":"\u00a0"},{"key":"e_1_2_2_2_2","doi-asserted-by":"crossref","unstructured":"P. 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