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Nine of the complexes were investigated by low\u2010temperature X\u2010ray diffraction. In addition, all compounds were investigated by infrared spectroscopy (IR), differential thermal analysis (DTA), elemental analysis (EA) and thermogravimetric analysis (TGA) for selected compounds. Furthermore, investigations of the materials were carried out regarding their sensitivity toward impact (IS), friction (FS), ball drop impact (BDIS) and electrostatic discharge (ESD). In addition, hot plate and hot needle tests were performed. Complex [Cu(AMT)<jats:sub>4<\/jats:sub>(H<jats:sub>2<\/jats:sub>O)](DN)<jats:sub>2<\/jats:sub>, based on 1\u2010amino\u20105\u2010methyltetrazole (AMT), is most outstanding for its detonative behavior and thus also capable of initiating PETN in classical initiation experiments. Laser ignition experiments at a wavelength of 915\u2005nm were performed for all substances and solid\u2010state UV\u2010Vis spectra were recorded to apprehend the ignition mechanism.<\/jats:p>","DOI":"10.1002\/chem.202100747","type":"journal-article","created":{"date-parts":[[2021,4,26]],"date-time":"2021-04-26T08:16:12Z","timestamp":1619424972000},"page":"9112-9123","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":21,"title":["A Smart Access to the Dinitramide Anion \u2013 The Use of Dinitraminic Acid for the Preparation of Nitrogen\u2010Rich Energetic Copper(II) Complexes"],"prefix":"10.1002","volume":"27","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-9866-1875","authenticated-orcid":false,"given":"Michael S.","family":"Gruhne","sequence":"first","affiliation":[{"name":"Energetic Materials Research Department of Chemistry University of Munich (LMU)  Butenandtstr. 5\u201313 81377 M\u00fcnchen Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Maximilian H. 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