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The highly economic, low\u2010sensitive and low\u2010priced reaction gives a mixture of polysulfides, whose distribution can be influenced by the addition of different amounts of carbon disulfide as co\u2010solvent. To describe the variable distribution function of the polysulfides, a novel parameter, the \u201cabsorbance average <jats:styled-content>s<\/jats:styled-content>ulfur <jats:styled-content>a<\/jats:styled-content>mount in <jats:styled-content>p<\/jats:styled-content>olysulfides\u201d (SAP) was introduced and defined on the basis of the \u201cnumber average molar mass\u201d used in polymer chemistry. Various organic polysulfides were synthesized with variable volume fractions of carbon disulfide, and the yield of each polysulfide was determined by quantitative <jats:sup>13<\/jats:sup>C NMR. Moreover, by using two symmetrical disulfides or a disulfide and a thiol as starting materials, a mixture of symmetrical and asymmetrical polysulfides could be obtained.<\/jats:p>","DOI":"10.1002\/chem.202101023","type":"journal-article","created":{"date-parts":[[2021,5,2]],"date-time":"2021-05-02T22:15:01Z","timestamp":1619993701000},"page":"11141-11149","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":8,"title":["Electrochemical Synthesis of Organic Polysulfides from Disulfides by Sulfur Insertion from S<sub>8<\/sub> and an Unexpected Solvent Effect on the Product Distribution"],"prefix":"10.1002","volume":"27","author":[{"given":"Jan","family":"F\u00e4hrmann","sequence":"first","affiliation":[{"name":"Institut f\u00fcr Chemie Universit\u00e4t Oldenburg  Carl-von-Ossietzky-Stra\u00dfe 9\u201311 26111 Oldenburg 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