{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,1,17]],"date-time":"2026-01-17T22:47:34Z","timestamp":1768690054743,"version":"3.49.0"},"reference-count":83,"publisher":"Wiley","issue":"45","license":[{"start":{"date-parts":[[2021,6,1]],"date-time":"2021-06-01T00:00:00Z","timestamp":1622505600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by-nc\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100001659","name":"Deutsche Forschungsgemeinschaft","doi-asserted-by":"publisher","award":["Sche 384\/32-2"],"award-info":[{"award-number":["Sche 384\/32-2"]}],"id":[{"id":"10.13039\/501100001659","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Chemistry A European J"],"published-print":{"date-parts":[[2021,8,11]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>The use of [Cp\u2032\u2032<jats:sub>2<\/jats:sub>Zr(\u03b7<jats:sup>1:1<\/jats:sup>\u2010E<jats:sub>4<\/jats:sub>)] (E=P (<jats:bold>1\u2009a<\/jats:bold>), As (<jats:bold>1\u2009b<\/jats:bold>), Cp\u2032\u2032=1,3\u2010di\u2010<jats:italic>tert<\/jats:italic>\u2010butyl\u2010cyclopentadienyl) as phosphorus or arsenic source, respectively, gives access to novel stable polypnictogen transition metal complexes at ambient temperatures. The reaction of <jats:bold>1\u2009a\/1\u2009b<\/jats:bold> with [Cp<jats:sup>R<\/jats:sup>NiBr]<jats:sub>2<\/jats:sub> (Cp<jats:sup>R<\/jats:sup>=Cp<jats:sup>Bn<\/jats:sup> (1,2,3,4,5\u2010pentabenzyl\u2010cyclopentadienyl), Cp\u2032\u2032\u2032 (1,2,4\u2010tri\u2010<jats:italic>tert<\/jats:italic>\u2010butyl\u2010cyclopentadienyl)) was studied, to yield novel complexes depending on steric effects and stoichiometric ratios. Besides the transfer of the complete E<jats:sub>n<\/jats:sub> unit, a degradation as well as aggregation can be observed. Thus, the prismane derivatives [(Cp\u2032\u2032\u2032Ni)<jats:sub>2<\/jats:sub>(\u03bc,\u03b7<jats:sup>3:3<\/jats:sup>\u2010E<jats:sub>4<\/jats:sub>)] (<jats:bold>2\u2009a<\/jats:bold> (E=P); <jats:bold>2\u2009b<\/jats:bold> (E=As)) or the arsenic containing cubane [(Cp\u2032\u2032\u2032Ni)<jats:sub>3<\/jats:sub>(\u03bc<jats:sub>3<\/jats:sub>\u2010As)(As<jats:sub>4<\/jats:sub>)] (<jats:bold>5<\/jats:bold>) are formed. Furthermore, the bromine bridged cubanes of the type [(Cp<jats:sup>R<\/jats:sup>Ni)<jats:sub>3<\/jats:sub>{Ni(\u03bc\u2010Br)}(\u03bc<jats:sub>3<\/jats:sub>\u2010E)<jats:sub>4<\/jats:sub>]<jats:sub>2<\/jats:sub> (Cp<jats:sup>R<\/jats:sup>=Cp\u2032\u2032\u2032: <jats:bold>6\u2009a<\/jats:bold> (E=P), <jats:bold>6\u2009b<\/jats:bold> (E=As), Cp<jats:sup>R<\/jats:sup>=Cp<jats:sup>Bn<\/jats:sup>: <jats:bold>8\u2009a<\/jats:bold> (E=P), <jats:bold>8\u2009b<\/jats:bold> (E=As)) can be isolated. Here, a stepwise transfer of E<jats:sub>n<\/jats:sub> units is possible, with a cyclo\u2010E<jats:sub>4<\/jats:sub><jats:sup>2\u2212<\/jats:sup> ligand being introduced and unprecedented triple\u2010decker compounds of the type [{(Cp<jats:sup>R<\/jats:sup>Ni)<jats:sub>3<\/jats:sub>Ni(\u03bc<jats:sub>3<\/jats:sub>\u2010E)<jats:sub>4<\/jats:sub>}<jats:sub>2<\/jats:sub>(\u03bc,\u03b7<jats:sup>4:4<\/jats:sup>\u2010E\u2032<jats:sub>4<\/jats:sub>)] (Cp<jats:sup>R<\/jats:sup>=Cp<jats:sup>Bn<\/jats:sup>, Cp\u2032\u2032\u2032; E\/E\u2032=P, As) are obtained.<\/jats:p>","DOI":"10.1002\/chem.202101119","type":"journal-article","created":{"date-parts":[[2021,5,10]],"date-time":"2021-05-10T17:27:40Z","timestamp":1620667660000},"page":"11649-11655","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":8,"title":["E<sub>4<\/sub> Transfer (E=P, As) to Ni Complexes"],"prefix":"10.1002","volume":"27","author":[{"given":"Veronika","family":"Heinl","sequence":"first","affiliation":[{"name":"Institute of Inorganic Chemistry University of Regensburg  93053 Regensburg Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Monika","family":"Schmidt","sequence":"additional","affiliation":[{"name":"Institute of Inorganic Chemistry University of Regensburg  93053 Regensburg Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Maria","family":"Eckhardt","sequence":"additional","affiliation":[{"name":"Institute of Inorganic Chemistry University of Regensburg  93053 Regensburg Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Miriam","family":"Eberl","sequence":"additional","affiliation":[{"name":"Institute of Inorganic Chemistry University of Regensburg  93053 Regensburg Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Andreas E.","family":"Seitz","sequence":"additional","affiliation":[{"name":"Institute of Inorganic Chemistry University of Regensburg  93053 Regensburg Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"G\u00e1bor","family":"Bal\u00e1zs","sequence":"additional","affiliation":[{"name":"Institute of Inorganic Chemistry University of Regensburg  93053 Regensburg Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Michael","family":"Seidl","sequence":"additional","affiliation":[{"name":"Institute of Inorganic Chemistry University of Regensburg  93053 Regensburg Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2182-5020","authenticated-orcid":false,"given":"Manfred","family":"Scheer","sequence":"additional","affiliation":[{"name":"Institute of Inorganic Chemistry University of Regensburg  93053 Regensburg Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2021,6]]},"reference":[{"key":"e_1_2_7_1_1","unstructured":"\u00a0"},{"key":"e_1_2_7_2_2","doi-asserted-by":"publisher","DOI":"10.1021\/ar970317c"},{"key":"e_1_2_7_3_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2010.12.016"},{"key":"e_1_2_7_4_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr900349u"},{"key":"e_1_2_7_5_2","doi-asserted-by":"publisher","DOI":"10.1002\/cjoc.201900181"},{"key":"e_1_2_7_6_2","doi-asserted-by":"publisher","DOI":"10.1016\/bs.adomc.2019.06.001"},{"key":"e_1_2_7_7_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.8b00713"},{"key":"e_1_2_7_8_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr100010e"},{"key":"e_1_2_7_9_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr9003709"},{"key":"e_1_2_7_10_1","unstructured":"\u00a0"},{"key":"e_1_2_7_11_2","doi-asserted-by":"crossref","unstructured":"W.\u2005B. Tolman Activation of Small Molecules: Organometallic and Bioinorganic Perspectives Wiley 2006;","DOI":"10.1002\/3527609350"},{"key":"e_1_2_7_12_2","doi-asserted-by":"publisher","DOI":"10.1016\/0022-328X(95)00522-R"},{"key":"e_1_2_7_13_2","doi-asserted-by":"publisher","DOI":"10.1038\/nature02311"},{"key":"e_1_2_7_14_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.1139322"},{"key":"e_1_2_7_15_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.1132898"},{"key":"e_1_2_7_16_2","doi-asserted-by":"publisher","DOI":"10.1039\/b819621d"},{"key":"e_1_2_7_17_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201409800"},{"key":"e_1_2_7_17_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201409800"},{"key":"e_1_2_7_18_1","unstructured":"\u00a0"},{"key":"e_1_2_7_19_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja808783u"},{"key":"e_1_2_7_20_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja016094"},{"key":"e_1_2_7_21_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja017820b"},{"key":"e_1_2_7_22_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201411451"},{"key":"e_1_2_7_22_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201411451"},{"key":"e_1_2_7_23_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201510716"},{"key":"e_1_2_7_23_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201510716"},{"key":"e_1_2_7_24_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5CC00147A"},{"key":"e_1_2_7_25_1","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201409469"},{"key":"e_1_2_7_25_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201409604"},{"key":"e_1_2_7_26_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.200902820"},{"key":"e_1_2_7_27_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201605451"},{"key":"e_1_2_7_28_1","unstructured":"\u00a0"},{"key":"e_1_2_7_29_2","doi-asserted-by":"publisher","DOI":"10.1039\/C4SC01213E"},{"key":"e_1_2_7_30_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201404653"},{"key":"e_1_2_7_30_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201404653"},{"key":"e_1_2_7_31_1","unstructured":"\u00a0"},{"key":"e_1_2_7_32_2","doi-asserted-by":"publisher","DOI":"10.1021\/om00058a013"},{"key":"e_1_2_7_33_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201001000"},{"key":"e_1_2_7_33_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201001000"},{"key":"e_1_2_7_34_2","doi-asserted-by":"publisher","DOI":"10.1016\/0022-328X(92)80030-2"},{"key":"e_1_2_7_35_2","doi-asserted-by":"publisher","DOI":"10.1039\/C4SC03543G"},{"key":"e_1_2_7_36_1","unstructured":"\u00a0"},{"key":"e_1_2_7_37_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201711130"},{"key":"e_1_2_7_38_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201610967"},{"key":"e_1_2_7_39_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201900778"},{"key":"e_1_2_7_40_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.199207581"},{"key":"e_1_2_7_40_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.19921040618"},{"key":"e_1_2_7_41_1","doi-asserted-by":"publisher","DOI":"10.1039\/b517710c"},{"key":"e_1_2_7_42_1","doi-asserted-by":"publisher","DOI":"10.1002\/cber.19951280110"},{"key":"e_1_2_7_43_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.1129630"},{"key":"e_1_2_7_44_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.1168260"},{"key":"e_1_2_7_45_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201803888"},{"key":"e_1_2_7_45_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201803888"},{"key":"e_1_2_7_46_1","doi-asserted-by":"publisher","DOI":"10.1039\/C3SC53140F"},{"key":"e_1_2_7_47_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.198806941"},{"key":"e_1_2_7_47_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.19881000531"},{"key":"e_1_2_7_48_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b07354"},{"key":"e_1_2_7_49_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.6b07389"},{"key":"e_1_2_7_50_1","unstructured":"\u00a0"},{"key":"e_1_2_7_51_2","doi-asserted-by":"publisher","DOI":"10.1039\/C6CC06883A"},{"key":"e_1_2_7_52_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.202003291"},{"key":"e_1_2_7_53_1","doi-asserted-by":"publisher","DOI":"10.1002\/cber.19901230310"},{"key":"e_1_2_7_54_1","doi-asserted-by":"publisher","DOI":"10.1002\/cber.19921251207"},{"key":"e_1_2_7_55_1","unstructured":"The crude NMR spectra of 6b show the formation of a complex mixture which has to be separated by column chromatography. Therefore the isolated yield is moderate."},{"key":"e_1_2_7_56_1","doi-asserted-by":"publisher","DOI":"10.1021\/om400606t"},{"key":"e_1_2_7_57_1","doi-asserted-by":"publisher","DOI":"10.1016\/0022-328X(88)80385-1"},{"key":"e_1_2_7_58_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.200800987"},{"key":"e_1_2_7_59_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201601775"},{"key":"e_1_2_7_59_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201601775"},{"key":"e_1_2_7_60_1","unstructured":"The crude NMR spectra of the triple-decker compounds show the formation of a complex mixture which has to be separated by column chromatography. Therefore the isolated yields are moderate."},{"key":"e_1_2_7_61_1","doi-asserted-by":"crossref","unstructured":"A.\u2005F. Holleman N. Wiberg Lehrbuch der Anorganischen Chemie Berlin Boston: De Gruyter 2007.","DOI":"10.1515\/9783110206845"},{"key":"e_1_2_7_62_1","doi-asserted-by":"publisher","DOI":"10.1021\/ic0514445"},{"key":"e_1_2_7_63_1","doi-asserted-by":"publisher","DOI":"10.1016\/0022-328X(89)85154-X"},{"key":"e_1_2_7_64_1","doi-asserted-by":"crossref","unstructured":"O.\u2005J. Scherer R. Winter C. Wolmersh\u00e4user Z. Anorg. Allg. Chem.1993 619 827\u2013883.","DOI":"10.1002\/zaac.19936190504"},{"key":"e_1_2_7_65_1","unstructured":"\u00a0"},{"key":"e_1_2_7_66_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.19911030836"},{"key":"e_1_2_7_67_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201102361"},{"key":"e_1_2_7_67_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201102361"},{"key":"e_1_2_7_68_2","doi-asserted-by":"publisher","DOI":"10.1016\/0022-328X(96)06305-X"},{"key":"e_1_2_7_69_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201916622"},{"key":"e_1_2_7_69_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201916622"},{"key":"e_1_2_7_70_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201802888"},{"key":"e_1_2_7_70_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201802888"}],"container-title":["Chemistry \u2013 A European Journal"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/chem.202101119","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/chem.202101119","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/chem.202101119","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,12]],"date-time":"2025-10-12T20:46:21Z","timestamp":1760301981000},"score":1,"resource":{"primary":{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/10.1002\/chem.202101119"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2021,6]]},"references-count":83,"journal-issue":{"issue":"45","published-print":{"date-parts":[[2021,8,11]]}},"alternative-id":["10.1002\/chem.202101119"],"URL":"https:\/\/doi.org\/10.1002\/chem.202101119","archive":["Portico"],"relation":{},"ISSN":["0947-6539","1521-3765"],"issn-type":[{"value":"0947-6539","type":"print"},{"value":"1521-3765","type":"electronic"}],"subject":[],"published":{"date-parts":[[2021,6]]},"assertion":[{"value":"2021-03-29","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2021-06-01","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}]}}