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Reaction of these salts with [Cu(PPh<jats:sub>3<\/jats:sub>)<jats:sub>3<\/jats:sub>Cl] gave a series of organotetrel\u2013copper chalcogenide clusters [(CuPPh<jats:sub>3<\/jats:sub>)<jats:sub>6<\/jats:sub>(PhTE<jats:sub>3<\/jats:sub>)<jats:sub>2<\/jats:sub>] with T\/E=Si\/S; (<jats:bold>5<\/jats:bold>), Si\/Se (<jats:bold>6<\/jats:bold>), Sn\/S (<jats:bold>7<\/jats:bold>) and Sn\/Se (<jats:bold>8<\/jats:bold>). Compounds <jats:bold>5<\/jats:bold>\u2013<jats:bold>8<\/jats:bold> share a common structural motif with two intact {PhTE<jats:sub>3<\/jats:sub>} units coordinating a Cu<jats:sub>6<\/jats:sub> moiety, which was previously reported with other ligands, and for the Sn and Ge congeners only. If the Sn\/Se reaction system was allowed to crystallize more slowly, single crystals of compound [(CuPPh<jats:sub>3<\/jats:sub>)<jats:sub>6<\/jats:sub>(PhSnSe<jats:sub>3<\/jats:sub>)<jats:sub>3<\/jats:sub>Cu<jats:sub>3<\/jats:sub>SnSe] (<jats:bold>9<\/jats:bold>) were obtained, which are based on a larger cluster structure. Hence, <jats:bold>9<\/jats:bold> might form from <jats:bold>8<\/jats:bold> through incorporation of additional cluster fragments. The experimentally and quantum chemically determined optical properties were compared to related clusters.<\/jats:p>","DOI":"10.1002\/chem.202101139","type":"journal-article","created":{"date-parts":[[2021,4,19]],"date-time":"2021-04-19T15:11:29Z","timestamp":1618845089000},"page":"11167-11174","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":6,"title":["Systematic Access of Ternary Organotetrel\u2010Copper Chalcogenide Clusters by [PhTE<sub>3<\/sub>]<sup>3\u2212<\/sup> Anions (T=Si, Sn; E=S, Se)"],"prefix":"10.1002","volume":"27","author":[{"given":"Niklas","family":"Rinn","sequence":"first","affiliation":[{"name":"Fachbereich Chemie Philipps Universit\u00e4t Marburg  Hans-Meerwein Stra\u00dfe 4 35037 Marburg 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