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The molecular structure of\n                    <jats:bold>1<\/jats:bold>\n                    reveals a dearomatized form of the ligand. The protonation of\n                    <jats:bold>1<\/jats:bold>\n                    with HBF\n                    <jats:sub>4<\/jats:sub>\n                    in tetrahydrofuran gives the corresponding aromatized complex [Cp*Ir(L\n                    <jats:sup>1<\/jats:sup>\n                    H)Cl]BF\n                    <jats:sub>4<\/jats:sub>\n                    (\n                    <jats:bold>2<\/jats:bold>\n                    ). Both compounds are characterized spectroscopically and by X\u2010ray crystallography. The protonation of\n                    <jats:bold>1<\/jats:bold>\n                    with acid is examined by\n                    <jats:sup>1<\/jats:sup>\n                    H NMR and UV\u2010vis spectra. The proton\u2010responsive character of\n                    <jats:bold>1<\/jats:bold>\n                    is exploited for catalyzing\n                    <jats:italic>\u03b1<\/jats:italic>\n                    \u2010alkylation of ketones and\n                    <jats:italic>\u03b2<\/jats:italic>\n                    \u2010alkylation of secondary alcohols using primary alcohols as alkylating agents through hydrogen\u2010borrowing methodology. Compound\n                    <jats:bold>1<\/jats:bold>\n                    is an effective catalyst for these reactions and exhibits a superior activity in comparison to a structurally similar iridium complex [Cp*Ir(L\n                    <jats:sup>2<\/jats:sup>\n                    )Cl]PF\n                    <jats:sub>6<\/jats:sub>\n                    (\n                    <jats:bold>3<\/jats:bold>\n                    ) lacking a proton\u2010responsive pendant amide moiety. The catalytic alkylation is characterized by a wide substrate scope, low catalyst and base loadings, and a short reaction time. The catalytic efficacy of\n                    <jats:bold>1<\/jats:bold>\n                    is also demonstrated for the syntheses of quinoline and lactone derivatives via acceptorless dehydrogenation, and selective alkylation of two steroids, pregnenolone and testosterone. Detailed mechanistic investigations and DFT calculations substantiate the role of the proton\u2010responsive ligand in the hydrogen\u2010borrowing process.\n                  <\/jats:p>","DOI":"10.1002\/chem.202101360","type":"journal-article","created":{"date-parts":[[2021,5,17]],"date-time":"2021-05-17T07:51:32Z","timestamp":1621237892000},"page":"10737-10748","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":43,"title":["A Proton\u2010Responsive Pyridyl(benzamide)\u2010Functionalized NHC Ligand on Ir Complex for Alkylation of Ketones and Secondary Alcohols"],"prefix":"10.1002","volume":"27","author":[{"given":"Mandeep","family":"Kaur","sequence":"first","affiliation":[{"name":"Department of Chemistry and Center for Environmental Sciences and Engineering Indian Institute of Technology Kanpur  Kanpur 208016 India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Noor","family":"U Din Reshi","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Center for Environmental Sciences and Engineering Indian Institute of Technology Kanpur  Kanpur 208016 India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kamaless","family":"Patra","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Center for Environmental Sciences and Engineering Indian Institute of Technology Kanpur  Kanpur 208016 India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Arindom","family":"Bhattacherya","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Center for Environmental Sciences and Engineering Indian Institute of Technology Kanpur  Kanpur 208016 India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sooraj","family":"Kunnikuruvan","sequence":"additional","affiliation":[{"name":"School of Chemistry Indian Institute of Science Education and Research Thiruvananthapuram  Vithura Thiruvananthapuram 695551 India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5689-8863","authenticated-orcid":false,"given":"Jitendra K.","family":"Bera","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Center for Environmental Sciences and Engineering Indian Institute of Technology Kanpur  Kanpur 208016 India"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2021,6,8]]},"reference":[{"key":"e_1_2_7_1_1","doi-asserted-by":"publisher","DOI":"10.1039\/C4CC04457F"},{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201503873"},{"key":"e_1_2_7_2_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201503873"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1002\/tcr.201700023"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.201801275"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.8b04495"},{"key":"e_1_2_7_6_1","doi-asserted-by":"publisher","DOI":"10.1246\/bcsj.20180301"},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201003296"},{"key":"e_1_2_7_8_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201702142"},{"key":"e_1_2_7_8_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201702142"},{"key":"e_1_2_7_9_1","doi-asserted-by":"publisher","DOI":"10.1002\/cctc.201200567"},{"key":"e_1_2_7_10_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.6b00695"},{"key":"e_1_2_7_11_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9CC00972H"},{"key":"e_1_2_7_12_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201201845"},{"key":"e_1_2_7_13_1","doi-asserted-by":"publisher","DOI":"10.1038\/ncomms6602"},{"key":"e_1_2_7_14_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9NJ02542A"},{"key":"e_1_2_7_15_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201909035"},{"key":"e_1_2_7_15_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201909035"},{"key":"e_1_2_7_16_1","doi-asserted-by":"publisher","DOI":"10.1002\/adsc.201800924"},{"key":"e_1_2_7_17_1","first-page":"202004499","author":"Kumar A.","year":"2021","journal-title":"Chem. 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