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Their synthesis exploits the reactivity of the organophosphonate\u2010functionalized precursor [P<jats:sub>4<\/jats:sub>W<jats:sub>24<\/jats:sub>O<jats:sub>92<\/jats:sub>(C<jats:sub>6<\/jats:sub>H<jats:sub>5<\/jats:sub>P<jats:sup>V<\/jats:sup>O)<jats:sub>2<\/jats:sub>]<jats:sup>16\u2212<\/jats:sup> with heterometal ions and yields hydrated potassium or mixed lithium\/potassium salts of composition K<jats:sub><jats:italic>x<\/jats:italic><\/jats:sub>Ln<jats:sub><jats:italic>y<\/jats:italic><\/jats:sub>H<jats:sub>12\u2013<jats:italic>x<\/jats:italic>\u2013<jats:italic>y<\/jats:italic><\/jats:sub>[Na\u2282{Ln(H<jats:sub>2<\/jats:sub>O)}{WO(H<jats:sub>2<\/jats:sub>O)}P<jats:sub>4<\/jats:sub>W<jats:sub>26<\/jats:sub>O<jats:sub>98<\/jats:sub>]\u22c5<jats:italic>n<\/jats:italic>H<jats:sub>2<\/jats:sub>O\u22c5<jats:italic>m<\/jats:italic>LiCl (<jats:italic>x<\/jats:italic>=8.5\u201311; <jats:italic>y<\/jats:italic>=0\u20132; <jats:italic>n<\/jats:italic>=24\u201334; <jats:italic>m<\/jats:italic>=0\u20131.5). The Dy, Ho, Er and Yb derivatives are characterized by slow magnetization relaxation.<\/jats:p>","DOI":"10.1002\/chem.202101474","type":"journal-article","created":{"date-parts":[[2021,7,14]],"date-time":"2021-07-14T07:33:04Z","timestamp":1626247984000},"page":"13376-13383","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":12,"title":["Trigonal Prismatic Coordination of Discrete Rare Earth Ions, Enforced by the Polyoxotungstate [P<sub>4<\/sub>W<sub>27<\/sub>O<sub>99<\/sub>(H<sub>2<\/sub>O)]<sup>16\u2013<\/sup>"],"prefix":"10.1002","volume":"27","author":[{"given":"Tuba","family":"Iftikhar","sequence":"first","affiliation":[{"name":"Institute of Inorganic Chemistry RWTH Aachen University  D-52074 Aachen Germany"},{"name":"J\u00fclich-Aachen Research Alliance (JARA-FIT) and Peter Gr\u00fcnberg Institute 6 Forschungszentrum J\u00fclich  D-52425 J\u00fclich Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Natalya V.","family":"Izarova","sequence":"additional","affiliation":[{"name":"Institute of Inorganic Chemistry RWTH Aachen University  D-52074 Aachen Germany"},{"name":"J\u00fclich-Aachen Research Alliance (JARA-FIT) and Peter Gr\u00fcnberg Institute 6 Forschungszentrum J\u00fclich  D-52425 J\u00fclich Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jan","family":"van Leusen","sequence":"additional","affiliation":[{"name":"Institute of Inorganic Chemistry RWTH Aachen University  D-52074 Aachen Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7831-3953","authenticated-orcid":false,"given":"Paul","family":"K\u00f6gerler","sequence":"additional","affiliation":[{"name":"Institute of Inorganic Chemistry RWTH Aachen University  D-52074 Aachen Germany"},{"name":"J\u00fclich-Aachen Research Alliance (JARA-FIT) and Peter Gr\u00fcnberg Institute 6 Forschungszentrum J\u00fclich  D-52425 J\u00fclich Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2021,8,19]]},"reference":[{"key":"e_1_2_6_1_1","unstructured":"\u00a0"},{"key":"e_1_2_6_2_2","doi-asserted-by":"crossref","unstructured":"Q. 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