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A mild base and sustainable solvents allow all reactions to be conducted in air and at room temperature, leading to high yields of the targeted compounds even on multigram scales. The effect of various mild bases on the N\u2212H metallation was studied in silico and experimentally, while a mechanochemical, solvent\u2010free synthetic approach was also developed. Our photophysical studies on [M(NHC)(Cbz)] (Cbz=carbazolyl) indicate that the occurrence of fluorescent or phosphorescent states is determined primarily by the metal, providing control over the excited state properties. Consequently, we demonstrate the potential of the new CMAs beyond luminescence applications by employing a selected CMA as a photocatalyst. The exemplified synthetic ease is expected to accelerate the applications of CMAs in photocatalysis and materials chemistry.<\/jats:p>","DOI":"10.1002\/chem.202101476","type":"journal-article","created":{"date-parts":[[2021,5,26]],"date-time":"2021-05-26T08:41:51Z","timestamp":1622018511000},"page":"11904-11911","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":78,"title":["Simple Synthetic Routes to Carbene\u2010M\u2010Amido (M=Cu, Ag, Au) Complexes for Luminescence and Photocatalysis Applications"],"prefix":"10.1002","volume":"27","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-1718-0207","authenticated-orcid":false,"given":"Nikolaos V.","family":"Tzouras","sequence":"first","affiliation":[{"name":"Department of Chemistry and Centre for Sustainable Chemistry Ghent University  Krijgslaan 281,S-3 9000 Ghent Belgium"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6147-3288","authenticated-orcid":false,"given":"Ekaterina A.","family":"Martynova","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Centre for Sustainable Chemistry Ghent University  Krijgslaan 281,S-3 9000 Ghent Belgium"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xinyuan","family":"Ma","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Centre for Sustainable Chemistry Ghent University  Krijgslaan 281,S-3 9000 Ghent Belgium"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7345-9670","authenticated-orcid":false,"given":"Thomas","family":"Scattolin","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Centre for Sustainable Chemistry Ghent University  Krijgslaan 281,S-3 9000 Ghent Belgium"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Benjamin","family":"Hupp","sequence":"additional","affiliation":[{"name":"Faculty of Chemistry and Chemical Biology TU Dortmund University  Otto-Hahn-Str. 6 44227 Dortmund Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hendrik","family":"Busen","sequence":"additional","affiliation":[{"name":"Faculty of Chemistry and Chemical Biology TU Dortmund University  Otto-Hahn-Str. 6 44227 Dortmund Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Marina","family":"Saab","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Centre for Sustainable Chemistry Ghent University  Krijgslaan 281,S-3 9000 Ghent Belgium"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ziyun","family":"Zhang","sequence":"additional","affiliation":[{"name":"KAUST Catalysis Center Physical Sciences and Engineering Division King Abdullah University of Science and Technology  Thuwal 23955-6900 Saudi Arabia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Laura","family":"Falivene","sequence":"additional","affiliation":[{"name":"KAUST Catalysis Center Physical Sciences and Engineering Division King Abdullah University of Science and Technology  Thuwal 23955-6900 Saudi Arabia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7138-4353","authenticated-orcid":false,"given":"Gianmarco","family":"Pisan\u00f2","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Centre for Sustainable Chemistry Ghent University  Krijgslaan 281,S-3 9000 Ghent Belgium"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kristof","family":"Van Hecke","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Centre for Sustainable Chemistry Ghent University  Krijgslaan 281,S-3 9000 Ghent Belgium"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Luigi","family":"Cavallo","sequence":"additional","affiliation":[{"name":"KAUST Catalysis Center Physical Sciences and Engineering Division King Abdullah University of Science and Technology  Thuwal 23955-6900 Saudi Arabia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9094-8131","authenticated-orcid":false,"given":"Catherine S. 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