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However, they have been investigated far less than pure oxides. The compounds Sc<jats:sub>5<\/jats:sub>P<jats:sub>12<\/jats:sub>N<jats:sub>23<\/jats:sub>O<jats:sub>3<\/jats:sub> and Ti<jats:sub>5<\/jats:sub>P<jats:sub>12<\/jats:sub>N<jats:sub>24<\/jats:sub>O<jats:sub>2<\/jats:sub> have now been synthesized from the binary nitrides ScN and TiN, respectively, by following a high\u2010pressure high\u2010temperature approach at 8\u2005GPa and 1400\u2009\u00b0C. NH<jats:sub>4<\/jats:sub>F acts as a mineralizing agent that supports product formation and crystallization. The starting materials ScN and TiN are seemingly an uncommon choice because of their chemical inertness but, nevertheless, react under these conditions. Sc<jats:sub>5<\/jats:sub>P<jats:sub>12<\/jats:sub>N<jats:sub>23<\/jats:sub>O<jats:sub>3<\/jats:sub> and Ti<jats:sub>5<\/jats:sub>P<jats:sub>12<\/jats:sub>N<jats:sub>24<\/jats:sub>O<jats:sub>2<\/jats:sub> crystallize isotypically with Ti<jats:sub>5<\/jats:sub>B<jats:sub>12<\/jats:sub>O<jats:sub>26<\/jats:sub>, consisting of solely vertex\u2010sharing P(O\/N)<jats:sub>4<\/jats:sub> tetrahedra forming two independent interpenetrating diamond\u2010like nets that host <jats:italic>TM<\/jats:italic>(O\/N)<jats:sub>6<\/jats:sub> (<jats:italic>TM<\/jats:italic>=Sc, Ti) octahedra. Ti<jats:sub>5<\/jats:sub>P<jats:sub>12<\/jats:sub>N<jats:sub>24<\/jats:sub>O<jats:sub>2<\/jats:sub> is a mixed\u2010valence compound and shows ordering of Ti<jats:sup>3+<\/jats:sup> and Ti<jats:sup>4+<\/jats:sup> ions.<\/jats:p>","DOI":"10.1002\/chem.202101858","type":"journal-article","created":{"date-parts":[[2021,8,18]],"date-time":"2021-08-18T14:35:54Z","timestamp":1629297354000},"page":"14184-14188","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":12,"title":["High\u2010Pressure Synthesis of Sc<sub>5<\/sub>P<sub>12<\/sub>N<sub>23<\/sub>O<sub>3<\/sub> and Ti<sub>5<\/sub>P<sub>12<\/sub>N<sub>24<\/sub>O<sub>2<\/sub> by Activation of the Binary Nitrides ScN and TiN with NH<sub>4<\/sub>F"],"prefix":"10.1002","volume":"27","author":[{"given":"Lucien","family":"Eisenburger","sequence":"first","affiliation":[{"name":"Department of Chemistry University of Munich (LMU)  Butenandtstra\u00dfe 5\u201313 81377 Munich 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