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For Li[SeCN] only ball\u2010milling and subsequent annealing led to the isolation of the quasibinary selenocyanate. Their structures were refined from single\u2010crystal and powder X\u2010ray data. The respective solid\u2010state IR and Raman spectra were interpreted with the aid of solid\u2010state quantum\u2010mechanical calculations and DSC\u2010TGA measurements allowed for extraction of melting points. Only for Li[SeCN] a possible phase transition was observed that is discussed on the basis of VT\u2010PXRD experiments. It is also the only quasibinary selenocyanate to form a hydrate (Li[SeCN]\u2009\u22c5\u20092H<jats:sub>2<\/jats:sub>O).<\/jats:p>","DOI":"10.1002\/chem.202102058","type":"journal-article","created":{"date-parts":[[2021,7,16]],"date-time":"2021-07-16T08:57:25Z","timestamp":1626425845000},"page":"13552-13557","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":15,"title":["A Comprehensive Study on the Full Series of Alkali\u2010Metal Selenocyanates <i>A<\/i><sup>I<\/sup>[SeCN] (<i>A<\/i><sup>I<\/sup>=Li\u2212Cs)"],"prefix":"10.1002","volume":"27","author":[{"given":"Alena","family":"Shlyaykher","sequence":"first","affiliation":[{"name":"Fachbereich Chemie and Wissenschaftlichen Zentrum f\u00fcr Materialwissenschaften (WZMW) Philipps-Universit\u00e4t Marburg  Hans-Meerwein-Strasse 4 35043 Marburg Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Marvin","family":"Ehmann","sequence":"additional","affiliation":[{"name":"Fachbereich Chemie and Wissenschaftlichen Zentrum f\u00fcr Materialwissenschaften (WZMW) Philipps-Universit\u00e4t Marburg  Hans-Meerwein-Strasse 4 35043 Marburg Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Antti J.","family":"Karttunen","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Materials Science Aalto University  Kemistintie 1 02150 Espoo Finland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Frank","family":"Tambornino","sequence":"additional","affiliation":[{"name":"Fachbereich Chemie and Wissenschaftlichen Zentrum f\u00fcr Materialwissenschaften (WZMW) Philipps-Universit\u00e4t Marburg  Hans-Meerwein-Strasse 4 35043 Marburg Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2021,8,19]]},"reference":[{"key":"e_1_2_7_1_1","first-page":"49","volume":"1","author":"Berzelius J. 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