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After oxidative addition, the resulting compounds (<jats:italic>o<\/jats:italic>\u2010PPh<jats:sub>2<\/jats:sub>)C<jats:sub>6<\/jats:sub>H<jats:sub>4<\/jats:sub>(Ar*)Ge(Cl)ECl<jats:sub>2<\/jats:sub> (<jats:bold>2<\/jats:bold>: E=P, <jats:bold>3<\/jats:bold>: E=As, <jats:bold>4<\/jats:bold>: E=Sb) were reduced by using sodium metal or LiHBEt<jats:sub>3<\/jats:sub>. The molecular structures of the phosphine\u2010stabilized phosphinidene (<jats:italic>o<\/jats:italic>\u2010PPh<jats:sub>2<\/jats:sub>)C<jats:sub>6<\/jats:sub>H<jats:sub>4<\/jats:sub>(Ar*)Ge(Cl)P (<jats:bold>5<\/jats:bold>), arsinidene (<jats:italic>o<\/jats:italic>\u2010PPh<jats:sub>2<\/jats:sub>)C<jats:sub>6<\/jats:sub>H<jats:sub>4<\/jats:sub>(Ar*)Ge(Cl)As (<jats:bold>6<\/jats:bold>) and stibinidene (<jats:italic>o<\/jats:italic>\u2010PPh<jats:sub>2<\/jats:sub>)C<jats:sub>6<\/jats:sub>H<jats:sub>4<\/jats:sub>(Ar*)Ge(Cl)Sb (<jats:bold>7<\/jats:bold>) are presented; they feature a two\u2010coordinate low\u2010valent Group 15 element. After chloride abstraction, a cyclic germaphosphene [(<jats:italic>o<\/jats:italic>\u2010PPh<jats:sub>2<\/jats:sub>)C<jats:sub>6<\/jats:sub>H<jats:sub>4<\/jats:sub>(Ar*)GeP] [B(C<jats:sub>6<\/jats:sub>H<jats:sub>3<\/jats:sub>(CF<jats:sub>3<\/jats:sub>)<jats:sub>2<\/jats:sub>)<jats:sub>4<\/jats:sub>] (<jats:bold>8<\/jats:bold>) was isolated. The <jats:sup>31<\/jats:sup>P NMR data of the germaphosphene were compared with literature examples and analyzed by quantum chemical calculations. The phosphinidene was treated with [<jats:italic>i<\/jats:italic>Bu<jats:sub>2<\/jats:sub>AlH]<jats:sub>2<\/jats:sub>, and the product of an Al\u2212H addition to the low\u2010valent phosphorus atom (<jats:italic>o<\/jats:italic>\u2010PPh<jats:sub>2<\/jats:sub>)C<jats:sub>6<\/jats:sub>H<jats:sub>4<\/jats:sub>(Ar*)Ge(H)P(H)Al(C<jats:sub>4<\/jats:sub>H<jats:sub>9<\/jats:sub>)<jats:sub>2<\/jats:sub> (<jats:bold>9<\/jats:bold>) was characterized.<\/jats:p>","DOI":"10.1002\/chem.202102320","type":"journal-article","created":{"date-parts":[[2021,7,22]],"date-time":"2021-07-22T04:47:53Z","timestamp":1626929273000},"page":"14073-14080","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":23,"title":["Phosphine\u2010Stabilized Pnictinidenes"],"prefix":"10.1002","volume":"27","author":[{"given":"Dominik","family":"Raiser","sequence":"first","affiliation":[{"name":"Institut f\u00fcr Anorganische Chemie Universit\u00e4t T\u00fcbingen  Auf der Morgenstelle 18 72076 T\u00fcbingen Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Klaus","family":"Eichele","sequence":"additional","affiliation":[{"name":"Institut f\u00fcr Anorganische Chemie Universit\u00e4t T\u00fcbingen  Auf der Morgenstelle 18 72076 T\u00fcbingen Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hartmut","family":"Schubert","sequence":"additional","affiliation":[{"name":"Institut f\u00fcr Anorganische Chemie Universit\u00e4t T\u00fcbingen  Auf der Morgenstelle 18 72076 T\u00fcbingen Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lars","family":"Wesemann","sequence":"additional","affiliation":[{"name":"Institut f\u00fcr Anorganische Chemie Universit\u00e4t T\u00fcbingen  Auf der Morgenstelle 18 72076 T\u00fcbingen Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2021,8,20]]},"reference":[{"key":"e_1_2_7_1_1","unstructured":"\u00a0"},{"key":"e_1_2_7_2_2","unstructured":"M. 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