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Here, we report a synthetic route for the covalent linkage of BODIPY\u2010dyes to Anderson\u2010type polyoxomolybdates by using CLICK chemistry (i.\u2009e. copper\u2010catalyzed azide\u2010alkyne cycloaddition, CuAAC). Photophysical properties of the dyad were investigated by combined experimental and theoretical methods and highlight the role of both sub\u2010components for the charge\u2010separation properties. The study demonstrates how CLICK chemistry can be used for the versatile linkage of organic functional units to molecular metal oxide clusters.<\/jats:p>","DOI":"10.1002\/chem.202102897","type":"journal-article","created":{"date-parts":[[2021,9,14]],"date-time":"2021-09-14T05:45:14Z","timestamp":1631598314000},"page":"17181-17187","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":25,"title":["Covalent Linkage of BODIPY\u2010Photosensitizers to Anderson\u2010Type Polyoxometalates Using CLICK Chemistry"],"prefix":"10.1002","volume":"27","author":[{"given":"Seda","family":"Cetindere","sequence":"first","affiliation":[{"name":"Institute of Inorganic Chemistry I Ulm University  Albert-Einstein-Allee 11 89081 Ulm Germany"},{"name":"Department of Chemistry Faculty of Science Gebze Technical University  41400 Gebze\/Kocaeli Turkey"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Simon T.","family":"Clausing","sequence":"additional","affiliation":[{"name":"Institute of Inorganic Chemistry I Ulm University  Albert-Einstein-Allee 11 89081 Ulm Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Montaha","family":"Anjass","sequence":"additional","affiliation":[{"name":"Institute of Inorganic Chemistry I Ulm University  Albert-Einstein-Allee 11 89081 Ulm Germany"},{"name":"Helmholtz-Institute Ulm  Helmholtzstr. 11 89081 Ulm Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yusen","family":"Luo","sequence":"additional","affiliation":[{"name":"Institute of Physical Chemistry and Abbe Center of Photonics Friedrich-Schiller University Jena  Helmholtzweg 4 07743 Jena Germany"},{"name":"Department Functional Interfaces Leibniz Institute of Photonic Technology (IPHT)  Albert-Einstein-Strasse 9 07745 Jena Germany"},{"name":"Center for Energy and Environmental Chemistry Jena (CEEC-Jena) Friedrich-Schiller University Jena  Philosophenweg 7a 07743 Jena Germany"},{"name":"Current address: Department of Chemistry and Pharmacy Interdisciplinary Center for Molecular Materials (ICMM) Friedrich-Alexander-Universit\u00e4t Erlangen-N\u00fcrnberg  Egerlandstr. 3 91058 Erlangen Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Stephan","family":"Kupfer","sequence":"additional","affiliation":[{"name":"Institute of Physical Chemistry Friedrich-Schiller University Jena  Helmholtzweg 4 07743 Jena Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Benjamin","family":"Dietzek","sequence":"additional","affiliation":[{"name":"Institute of Physical Chemistry and Abbe Center of Photonics Friedrich-Schiller University Jena  Helmholtzweg 4 07743 Jena Germany"},{"name":"Department Functional Interfaces Leibniz Institute of Photonic Technology (IPHT)  Albert-Einstein-Strasse 9 07745 Jena Germany"},{"name":"Center for Energy and Environmental Chemistry Jena (CEEC-Jena) Friedrich-Schiller University Jena  Philosophenweg 7a 07743 Jena Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Carsten","family":"Streb","sequence":"additional","affiliation":[{"name":"Institute of Inorganic Chemistry I Ulm University  Albert-Einstein-Allee 11 89081 Ulm Germany"},{"name":"Helmholtz-Institute Ulm  Helmholtzstr. 11 89081 Ulm Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2021,9,29]]},"reference":[{"key":"e_1_2_7_1_1","doi-asserted-by":"publisher","DOI":"10.1002\/1521-4095(200102)13:3<163::AID-ADMA163>3.0.CO;2-U"},{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1039\/b715502f"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1039\/JM9960600511"},{"key":"e_1_2_7_4_1","doi-asserted-by":"crossref","unstructured":"POM-themed issue: L. 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