{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,1,16]],"date-time":"2026-01-16T19:00:59Z","timestamp":1768590059913,"version":"3.49.0"},"reference-count":168,"publisher":"Wiley","issue":"71","license":[{"start":{"date-parts":[[2021,11,18]],"date-time":"2021-11-18T00:00:00Z","timestamp":1637193600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100000266","name":"Engineering and Physical Sciences Research Council","doi-asserted-by":"publisher","award":["DTP studentship"],"award-info":[{"award-number":["DTP studentship"]}],"id":[{"id":"10.13039\/501100000266","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100000704","name":"Royal Society of Chemistry","doi-asserted-by":"publisher","award":["Travel grant"],"award-info":[{"award-number":["Travel grant"]}],"id":[{"id":"10.13039\/501100000704","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Chemistry A European J"],"published-print":{"date-parts":[[2021,12,20]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Indenyl (Ind) rhodium N\u2010heterocyclic carbene (NHC) complexes [Rh(<jats:italic>\u03b7<\/jats:italic><jats:sup>5<\/jats:sup>\u2010Ind)(NHC)(L)] were synthesised for 1,3\u2010bis(2,6\u2010diisopropylphenyl)\u20104,5\u2010dihydroimidazol\u20102\u2010ylidene (SIPr) with L=C<jats:sub>2<\/jats:sub>H<jats:sub>4<\/jats:sub> (<jats:bold>1<\/jats:bold>), CO (<jats:bold>2\u2009a<\/jats:bold>) and cyclooctene (COE; <jats:bold>3<\/jats:bold>), for 1,3\u2010bis(2,4,6\u2010trimethylphenyl)\u20104,5\u2010dihydroimidazol\u20102\u2010ylidene (SIMes) with L=CO (<jats:bold>2\u2009b<\/jats:bold>) and COE (<jats:bold>4<\/jats:bold>), and 1,3\u2010bis(2,4,6\u2010trimethylphenyl)imidazol\u20102\u2010ylidene (IMes) with L=CO (<jats:bold>2\u2009c<\/jats:bold>) and COE (<jats:bold>5<\/jats:bold>). Reaction of SIPr with [Rh(Cp*)(C<jats:sub>2<\/jats:sub>H<jats:sub>4<\/jats:sub>)<jats:sub>2<\/jats:sub>] did not give the desired SIPr complex, thus demonstrating the \u201cindenyl effect\u201d in the synthesis of <jats:bold>1<\/jats:bold>. Oxidative addition of HSi(OEt)<jats:sub>3<\/jats:sub> to <jats:bold>3<\/jats:bold> proceeded under mild conditions to give the Rh silyl hydride complex [Rh(Ind){Si(OEt)<jats:sub>3<\/jats:sub>}(H)(SIPr)] (<jats:bold>6<\/jats:bold>) with loss of COE. Tethered\u2010fluorenyl NHC rhodium complexes [Rh{(<jats:italic>\u03b7<\/jats:italic><jats:sup>5<\/jats:sup>\u2010C<jats:sub>13<\/jats:sub>H<jats:sub>8<\/jats:sub>)C<jats:sub>2<\/jats:sub>H<jats:sub>4<\/jats:sub>N(C)C<jats:sub>2<\/jats:sub>H<jats:sub><jats:italic>x<\/jats:italic><\/jats:sub>NR}(L)] (<jats:italic>x<\/jats:italic>=4, R=Dipp, L=C<jats:sub>2<\/jats:sub>H<jats:sub>4<\/jats:sub>: <jats:bold>11<\/jats:bold>; L=COE: <jats:bold>12<\/jats:bold>; L=CO: <jats:bold>13<\/jats:bold>; R=Mes, L=COE: <jats:bold>14<\/jats:bold>; L=CO: <jats:bold>15<\/jats:bold>; <jats:italic>x<\/jats:italic>=2, R=Me, L=COE: <jats:bold>16<\/jats:bold>; L=CO: <jats:bold>17<\/jats:bold>) were synthesised in low yields (5\u201331\u2009%) in comparison to good yields for the monodentate complexes (49\u201379\u2009%). Compounds <jats:bold>3<\/jats:bold> and <jats:bold>1<\/jats:bold>, which contain labile alkene ligands, were successful catalysts for the catalytic borylation of benzene with B<jats:sub>2<\/jats:sub>pin<jats:sub>2<\/jats:sub> (Bpin=pinacolboronate, 97 and 93\u2009% PhBpin respectively with 5\u2005mol\u2009% catalyst, 24\u2005h, 80\u2009\u00b0C), with SIPr giving a more active catalyst than SIMes or IMes. Fluorenyl\u2010tethered NHC complexes were much less active as borylation catalysts, and the carbonyl complexes were inactive. The borylation of toluene, biphenyl, anisole and diphenyl ether proceeded to give <jats:italic>meta<\/jats:italic> substitutions as the major product, with smaller amounts of <jats:italic>para<\/jats:italic> substitution and almost no <jats:italic>ortho<\/jats:italic> product. The borylation of octane and decane with B<jats:sub>2<\/jats:sub>pin<jats:sub>2<\/jats:sub> at 120 and 140\u2009\u00b0C, respectively, was monitored by <jats:sup>11<\/jats:sup>B NMR spectroscopy, which showed high conversions into octyl and decylBpin over 4\u20137\u2005days, thus demonstrating catalysed sp<jats:sup>3<\/jats:sup> C\u2212H borylation with new piano stool rhodium indenyl complexes. Irradiation of the monodentate complexes with 400 or 420\u2005nm light confirmed the ready dissociation of C<jats:sub>2<\/jats:sub>H<jats:sub>4<\/jats:sub> and COE ligands, whereas CO complexes were inert. Evidence for C\u2212H bond activation in the alkyl groups of the NHC ligands was obtained.<\/jats:p>","DOI":"10.1002\/chem.202102961","type":"journal-article","created":{"date-parts":[[2021,10,17]],"date-time":"2021-10-17T15:05:36Z","timestamp":1634483136000},"page":"17824-17833","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":7,"title":["Rhodium Indenyl NHC and Fluorenyl\u2010Tethered NHC Half\u2010Sandwich Complexes: Synthesis, Structures and Applications in the Catalytic C\u2212H Borylation of Arenes and Alkanes"],"prefix":"10.1002","volume":"27","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-0111-1709","authenticated-orcid":false,"given":"Kieren J.","family":"Evans","sequence":"first","affiliation":[{"name":"Institute of Chemical Sciences Heriot-Watt University  Edinburgh EH14 4AS UK"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0079-5929","authenticated-orcid":false,"given":"Paul A.","family":"Morton","sequence":"additional","affiliation":[{"name":"Institute of Chemical Sciences Heriot-Watt University  Edinburgh EH14 4AS UK"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Christian","family":"Luz","sequence":"additional","affiliation":[{"name":"Institute of Chemical Sciences Heriot-Watt University  Edinburgh EH14 4AS UK"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Callum","family":"Miller","sequence":"additional","affiliation":[{"name":"Institute of Chemical Sciences Heriot-Watt University  Edinburgh EH14 4AS UK"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Olivia","family":"Raine","sequence":"additional","affiliation":[{"name":"Institute of Chemical Sciences Heriot-Watt University  Edinburgh EH14 4AS UK"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0103-9479","authenticated-orcid":false,"given":"Jason M.","family":"Lynam","sequence":"additional","affiliation":[{"name":"Department of Chemistry University of York  Heslington, York YO10 5DD UK"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9332-3698","authenticated-orcid":false,"given":"Stephen M.","family":"Mansell","sequence":"additional","affiliation":[{"name":"Institute of Chemical Sciences Heriot-Watt University  Edinburgh EH14 4AS UK"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2021,11,18]]},"reference":[{"key":"e_1_2_7_1_1","unstructured":"\u00a0"},{"key":"e_1_2_7_2_2","doi-asserted-by":"publisher","DOI":"10.1021\/ar00051a009"},{"key":"e_1_2_7_3_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr9411886"},{"key":"e_1_2_7_4_2","doi-asserted-by":"publisher","DOI":"10.1038\/417507a"},{"key":"e_1_2_7_5_2","doi-asserted-by":"publisher","DOI":"10.1038\/446391a"},{"key":"e_1_2_7_6_2","doi-asserted-by":"publisher","DOI":"10.1039\/C7SC03610H"},{"key":"e_1_2_7_7_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201804727"},{"key":"e_1_2_7_7_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201804727"},{"key":"e_1_2_7_8_1","unstructured":"\u00a0"},{"key":"e_1_2_7_9_2","doi-asserted-by":"publisher","DOI":"10.1039\/b103147n"},{"key":"e_1_2_7_10_2","doi-asserted-by":"publisher","DOI":"10.1021\/ar000209h"},{"key":"e_1_2_7_11_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr900184e"},{"key":"e_1_2_7_12_2","doi-asserted-by":"publisher","DOI":"10.1039\/c1cs15083a"},{"key":"e_1_2_7_13_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201203269"},{"key":"e_1_2_7_13_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201203269"},{"key":"e_1_2_7_14_2","doi-asserted-by":"publisher","DOI":"10.1021\/acscentsci.6b00032"},{"key":"e_1_2_7_15_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.molcata.2016.06.020"},{"key":"e_1_2_7_16_2","doi-asserted-by":"publisher","DOI":"10.1038\/nature07369"},{"key":"e_1_2_7_17_1","unstructured":"\u00a0"},{"key":"e_1_2_7_18_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.287.5460.1942"},{"key":"e_1_2_7_19_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5b08707"},{"key":"e_1_2_7_20_1","unstructured":"\u00a0"},{"key":"e_1_2_7_21_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr900005n"},{"key":"e_1_2_7_22_2","doi-asserted-by":"publisher","DOI":"10.1021\/ar200190g"},{"key":"e_1_2_7_23_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr100412j"},{"key":"e_1_2_7_24_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.6b11867"},{"key":"e_1_2_7_25_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja506229s"},{"key":"e_1_2_7_26_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.0c13415"},{"key":"e_1_2_7_27_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja8015878"},{"key":"e_1_2_7_28_1","doi-asserted-by":"publisher","DOI":"10.1080\/00958972.2013.797572"},{"key":"e_1_2_7_29_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.280.5363.560"},{"key":"e_1_2_7_30_1","unstructured":"\u00a0"},{"key":"e_1_2_7_31_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00365a091"},{"key":"e_1_2_7_32_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00377a032"},{"key":"e_1_2_7_33_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.223.4639.902"},{"key":"e_1_2_7_34_1","doi-asserted-by":"publisher","DOI":"10.1007\/1-4020-2000-7"},{"key":"e_1_2_7_35_1","unstructured":"\u00a0"},{"key":"e_1_2_7_36_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00318a018"},{"key":"e_1_2_7_37_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00249a048"},{"key":"e_1_2_7_38_2","doi-asserted-by":"publisher","DOI":"10.1039\/C39890000928"},{"key":"e_1_2_7_39_2","doi-asserted-by":"publisher","DOI":"10.1021\/om00014a025"},{"key":"e_1_2_7_40_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00214a025"},{"key":"e_1_2_7_41_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.7b00444"},{"key":"e_1_2_7_42_1","unstructured":"\u00a0"},{"key":"e_1_2_7_43_2","doi-asserted-by":"publisher","DOI":"10.1039\/c0cs00156b"},{"key":"e_1_2_7_44_2","doi-asserted-by":"publisher","DOI":"10.1021\/ar200206a"},{"key":"e_1_2_7_45_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.tet.2017.11.005"},{"key":"e_1_2_7_46_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr900206p"},{"key":"e_1_2_7_47_1","unstructured":"\u00a0"},{"key":"e_1_2_7_48_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr00039a007"},{"key":"e_1_2_7_49_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.9b00491"},{"key":"e_1_2_7_50_2","doi-asserted-by":"publisher","DOI":"10.1002\/ejoc.201701573"},{"key":"e_1_2_7_51_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr608202m"},{"key":"e_1_2_7_52_1","unstructured":"\u00a0"},{"key":"e_1_2_7_53_2","doi-asserted-by":"publisher","DOI":"10.1081\/CNV-120030218"},{"key":"e_1_2_7_54_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b12013"},{"key":"e_1_2_7_55_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jmedchem.5b00127"},{"key":"e_1_2_7_56_1","unstructured":"\u00a0"},{"key":"e_1_2_7_57_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00150a041"},{"key":"e_1_2_7_58_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.277.5323.211"},{"key":"e_1_2_7_59_1","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1521-3773(19991115)38:22<3391::AID-ANIE3391>3.0.CO;2-N"},{"key":"e_1_2_7_59_2","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1521-3757(19991115)111:22<3597::AID-ANGE3597>3.0.CO;2-4"},{"key":"e_1_2_7_60_1","unstructured":"\u00a0"},{"key":"e_1_2_7_61_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.287.5460.1995"},{"key":"e_1_2_7_62_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja991258w"},{"key":"e_1_2_7_63_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja0013069"},{"key":"e_1_2_7_64_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja044440s"},{"key":"e_1_2_7_65_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja015975d"},{"key":"e_1_2_7_66_1","unstructured":"\u00a0"},{"key":"e_1_2_7_67_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja045090c"},{"key":"e_1_2_7_68_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja909453g"},{"key":"e_1_2_7_69_1","unstructured":"\u00a0"},{"key":"e_1_2_7_70_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200603224"},{"key":"e_1_2_7_70_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200603224"},{"key":"e_1_2_7_71_2","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.7b03048"},{"key":"e_1_2_7_72_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja044933x"},{"key":"e_1_2_7_73_1","doi-asserted-by":"publisher","DOI":"10.1002\/1521-3773(20010601)40:11<2168::AID-ANIE2168>3.0.CO;2-0"},{"key":"e_1_2_7_73_2","doi-asserted-by":"publisher","DOI":"10.1002\/1521-3757(20010601)113:11<2226::AID-ANGE2226>3.0.CO;2-Q"},{"key":"e_1_2_7_74_1","doi-asserted-by":"publisher","DOI":"10.1039\/b009246k"},{"key":"e_1_2_7_75_1","unstructured":"\u00a0"},{"key":"e_1_2_7_76_2","doi-asserted-by":"publisher","DOI":"10.1039\/C8CC03144D"},{"key":"e_1_2_7_77_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201905924"},{"key":"e_1_2_7_77_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201905924"},{"key":"e_1_2_7_78_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja064092p"},{"key":"e_1_2_7_79_1","unstructured":"\u00a0"},{"key":"e_1_2_7_80_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja305596v"},{"key":"e_1_2_7_81_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja503676d"},{"key":"e_1_2_7_82_2","doi-asserted-by":"publisher","DOI":"10.1021\/om400900z"},{"key":"e_1_2_7_83_1","unstructured":"\u00a0"},{"key":"e_1_2_7_84_2","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.8b02771"},{"key":"e_1_2_7_85_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.aad9730"},{"key":"e_1_2_7_86_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.aad9289"},{"key":"e_1_2_7_87_1","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.2417"},{"key":"e_1_2_7_88_1","unstructured":"\u00a0"},{"key":"e_1_2_7_89_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja0173019"},{"key":"e_1_2_7_90_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.1067074"},{"key":"e_1_2_7_91_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b08920"},{"key":"e_1_2_7_92_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201914914"},{"key":"e_1_2_7_92_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201914914"},{"key":"e_1_2_7_93_2","doi-asserted-by":"publisher","DOI":"10.1039\/b501778e"},{"key":"e_1_2_7_94_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja053433g"},{"key":"e_1_2_7_95_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5b04899"},{"key":"e_1_2_7_96_1","unstructured":"\u00a0"},{"key":"e_1_2_7_97_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.organomet.8b00144"},{"key":"e_1_2_7_98_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5b12249"},{"key":"e_1_2_7_99_1","unstructured":"\u00a0"},{"key":"e_1_2_7_100_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.0c00524"},{"key":"e_1_2_7_101_2","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.1c00389"},{"key":"e_1_2_7_102_1","unstructured":"\u00a0"},{"key":"e_1_2_7_103_2","doi-asserted-by":"publisher","DOI":"10.1021\/om00041a013"},{"key":"e_1_2_7_104_2","doi-asserted-by":"publisher","DOI":"10.1021\/om00041a014"},{"key":"e_1_2_7_105_1","unstructured":"\u00a0"},{"key":"e_1_2_7_106_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2019.213027"},{"key":"e_1_2_7_107_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201609054"},{"key":"e_1_2_7_107_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201609054"},{"key":"e_1_2_7_108_1","doi-asserted-by":"publisher","DOI":"10.1039\/C6SC02587K"},{"key":"e_1_2_7_109_1","doi-asserted-by":"publisher","DOI":"10.1039\/b812259h"},{"key":"e_1_2_7_110_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja00073a075"},{"key":"e_1_2_7_111_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.9b00634"},{"key":"e_1_2_7_112_1","unstructured":"\u00a0"},{"key":"e_1_2_7_113_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic960395g"},{"key":"e_1_2_7_114_2","doi-asserted-by":"publisher","DOI":"10.1002\/ejic.200801162"},{"key":"e_1_2_7_115_2","doi-asserted-by":"publisher","DOI":"10.1002\/ejic.201100990"},{"key":"e_1_2_7_116_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.organomet.8b00164"},{"key":"e_1_2_7_117_2","doi-asserted-by":"publisher","DOI":"10.1039\/C3DT53089B"},{"key":"e_1_2_7_118_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja974323f"},{"key":"e_1_2_7_119_1","doi-asserted-by":"publisher","DOI":"10.1021\/om050438d"},{"key":"e_1_2_7_120_1","doi-asserted-by":"publisher","DOI":"10.1039\/C7DT03395H"},{"key":"e_1_2_7_121_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2005.10.022"},{"key":"e_1_2_7_122_1","volume-title":"PhD Thesis","author":"Caddy P.","year":"1977"},{"key":"e_1_2_7_123_1","doi-asserted-by":"publisher","DOI":"10.1021\/om060576i"},{"key":"e_1_2_7_124_1","doi-asserted-by":"publisher","DOI":"10.1039\/b408750j"},{"key":"e_1_2_7_125_1","doi-asserted-by":"publisher","DOI":"10.1039\/j19700002875"},{"key":"e_1_2_7_126_1","doi-asserted-by":"publisher","DOI":"10.1039\/C39780000839"},{"key":"e_1_2_7_127_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja00301a052"},{"key":"e_1_2_7_128_1","doi-asserted-by":"publisher","DOI":"10.1002\/1521-3765(20010417)7:8<1679::AID-CHEM16790>3.0.CO;2-5"},{"key":"e_1_2_7_129_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja00262a042"},{"key":"e_1_2_7_130_1","doi-asserted-by":"publisher","DOI":"10.1021\/om060500m"},{"key":"e_1_2_7_131_1","doi-asserted-by":"publisher","DOI":"10.1039\/a803048k"},{"key":"e_1_2_7_132_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja00057a028"},{"key":"e_1_2_7_133_1","unstructured":"\u00a0"},{"key":"e_1_2_7_134_2","doi-asserted-by":"publisher","DOI":"10.1021\/om100412q"},{"key":"e_1_2_7_135_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00331a013"},{"key":"e_1_2_7_136_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200460430"},{"key":"e_1_2_7_136_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200460430"},{"key":"e_1_2_7_137_1","doi-asserted-by":"publisher","DOI":"10.1021\/om00152a041"},{"key":"e_1_2_7_138_1","doi-asserted-by":"publisher","DOI":"10.1021\/om00139a024"},{"key":"e_1_2_7_139_1","doi-asserted-by":"publisher","DOI":"10.1021\/ed082p1334"},{"key":"e_1_2_7_140_1","doi-asserted-by":"publisher","DOI":"10.1021\/om00097a013"},{"key":"e_1_2_7_141_1","doi-asserted-by":"publisher","DOI":"10.1021\/om00037a022"},{"key":"e_1_2_7_142_1","unstructured":"\u00a0"},{"key":"e_1_2_7_143_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.5b00559"},{"key":"e_1_2_7_144_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.organomet.9b00179"},{"key":"e_1_2_7_145_1","unstructured":"\u00a0"},{"key":"e_1_2_7_146_2","doi-asserted-by":"publisher","DOI":"10.1021\/om00083a016"},{"key":"e_1_2_7_147_2","doi-asserted-by":"publisher","DOI":"10.1021\/om000195j"},{"key":"e_1_2_7_148_1","unstructured":"\u00a0"},{"key":"e_1_2_7_149_2","doi-asserted-by":"publisher","DOI":"10.1002\/ejic.201901003"},{"key":"e_1_2_7_150_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201806278"},{"key":"e_1_2_7_151_1","unstructured":"\u00a0"},{"key":"e_1_2_7_152_2","doi-asserted-by":"publisher","DOI":"10.1039\/C5DT04060D"},{"key":"e_1_2_7_153_2","doi-asserted-by":"publisher","DOI":"10.1107\/S205698902000047X"},{"key":"e_1_2_7_154_1","unstructured":"\u00a0"},{"key":"e_1_2_7_155_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja01500a074"},{"key":"e_1_2_7_156_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200604409"},{"key":"e_1_2_7_156_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200604409"},{"key":"e_1_2_7_157_1","doi-asserted-by":"publisher","DOI":"10.1039\/c4dt00080c"},{"key":"e_1_2_7_158_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.6b00193"}],"container-title":["Chemistry \u2013 A European Journal"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/chem.202102961","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/chem.202102961","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/chem.202102961","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,12]],"date-time":"2025-10-12T13:49:23Z","timestamp":1760276963000},"score":1,"resource":{"primary":{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/10.1002\/chem.202102961"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2021,11,18]]},"references-count":168,"journal-issue":{"issue":"71","published-print":{"date-parts":[[2021,12,20]]}},"alternative-id":["10.1002\/chem.202102961"],"URL":"https:\/\/doi.org\/10.1002\/chem.202102961","archive":["Portico"],"relation":{},"ISSN":["0947-6539","1521-3765"],"issn-type":[{"value":"0947-6539","type":"print"},{"value":"1521-3765","type":"electronic"}],"subject":[],"published":{"date-parts":[[2021,11,18]]},"assertion":[{"value":"2021-08-13","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2021-11-18","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}]}}