{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,18]],"date-time":"2026-09-18T03:38:24Z","timestamp":1789702704105,"version":"4.0.1"},"reference-count":41,"publisher":"Wiley","issue":"65","license":[{"start":{"date-parts":[[2021,10,1]],"date-time":"2021-10-01T00:00:00Z","timestamp":1633046400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["91961108 and 21922111"],"award-info":[{"award-number":["91961108 and 21922111"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Chemistry A European J"],"published-print":{"date-parts":[[2021,11,22]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>In this work, the first examples of inorganic macrocyclic tin\u2010oxo clusters which are stabilized by sulfate ligands are reported. As determined by X\u2010ray diffraction and photoelectron spectroscopy analyses, the prepared inorganic Sn<jats:sub>10<\/jats:sub>\u2010oxo cluster displays interesting mixed valence behaviors, with 8 Sn<jats:sup>4+<\/jats:sup> located at the cyclic skeleton and two Sn<jats:sup>2+<\/jats:sup> encapsulated in the center. When further introducing Ti<jats:sup>4+<\/jats:sup> and In<jats:sup>3+<\/jats:sup> ions to the synthetic systems, heterometallic Sn<jats:sub>2<\/jats:sub>Ti<jats:sub>6<\/jats:sub> and SnIn<jats:sub>5<\/jats:sub>Ti<jats:sub>6<\/jats:sub> complexes with Ti<jats:sub>6<\/jats:sub>(SO<jats:sub>4<\/jats:sub>)<jats:sub>9<\/jats:sub> and SnIn<jats:sub>5<\/jats:sub>(SO<jats:sub>4<\/jats:sub>)<jats:sub>12<\/jats:sub> macrocyclic skeletons were prepared whose configuration and packing models were affected by the ionic radius of incorporated metals. Moreover, comparative CO<jats:sub>2<\/jats:sub> reduction experiments confirm that such heterometallic composition can significantly improve the catalytic activities of these inorganic macrocyclic oxo clusters. This work represents a milestone in constructing inorganic tin complexes and also macrocyclic metal oxo clusters with tunable configurations and properties.<\/jats:p>","DOI":"10.1002\/chem.202103226","type":"journal-article","created":{"date-parts":[[2021,9,9]],"date-time":"2021-09-09T22:02:58Z","timestamp":1631224978000},"page":"16117-16120","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":11,"title":["Macrocyclic Inorganic Tin\u2010Containing Oxo Clusters: Heterometallic Strategy for Configuration and Catalytic Activity Modulation"],"prefix":"10.1002","volume":"27","author":[{"given":"Di","family":"Wang","sequence":"first","affiliation":[{"name":"State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences  350002 Fuzhou P. R. China"},{"name":"University of Chinese Academy of Sciences  100049 Beijing P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Guang\u2010Hui","family":"Chen","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences  350002 Fuzhou P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lv\u2010Bing","family":"Yuan","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences  350002 Fuzhou P. R. China"},{"name":"University of Chinese Academy of Sciences  100049 Beijing P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Cheng\u2010Cheng","family":"Feng","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences  350002 Fuzhou P. R. China"},{"name":"University of Chinese Academy of Sciences  100049 Beijing P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jian","family":"Zhang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences  350002 Fuzhou P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7720-4667","authenticated-orcid":false,"given":"Lei","family":"Zhang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences  350002 Fuzhou P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2021,10]]},"reference":[{"key":"e_1_2_2_1_1","doi-asserted-by":"publisher","DOI":"10.1039\/C2CS35218D"},{"key":"e_1_2_2_2_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201709096"},{"key":"e_1_2_2_2_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201709096"},{"key":"e_1_2_2_3_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b11112"},{"key":"e_1_2_2_4_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.5b00142"},{"key":"e_1_2_2_5_1","doi-asserted-by":"publisher","DOI":"10.1038\/ncomms15898"},{"key":"e_1_2_2_6_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja9048042"},{"key":"e_1_2_2_7_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.199521221"},{"key":"e_1_2_2_7_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.19951071911"},{"key":"e_1_2_2_8_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201901818"},{"key":"e_1_2_2_8_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201901818"},{"key":"e_1_2_2_9_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.0c03041"},{"key":"e_1_2_2_10_1","doi-asserted-by":"publisher","DOI":"10.1039\/b510396g"},{"key":"e_1_2_2_11_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.molstruc.2007.03.021"},{"key":"e_1_2_2_12_1","doi-asserted-by":"publisher","DOI":"10.31635\/ccschem.020.202000128"},{"key":"e_1_2_2_13_1","doi-asserted-by":"publisher","DOI":"10.1021\/ic100648c"},{"key":"e_1_2_2_14_1","doi-asserted-by":"publisher","DOI":"10.1039\/c2cc36056j"},{"key":"e_1_2_2_15_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202010847"},{"key":"e_1_2_2_15_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.202010847"},{"key":"e_1_2_2_16_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.7b12968"},{"key":"e_1_2_2_17_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.201602204"},{"key":"e_1_2_2_18_1","doi-asserted-by":"publisher","DOI":"10.1117\/1.JMM.16.3.033510"},{"key":"e_1_2_2_19_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.9b19004"},{"key":"e_1_2_2_20_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.mee.2014.04.024"},{"key":"e_1_2_2_21_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.201706289"},{"key":"e_1_2_2_22_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201608279"},{"key":"e_1_2_2_22_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201608279"},{"key":"e_1_2_2_23_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201701703"},{"key":"e_1_2_2_23_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201701703"},{"key":"e_1_2_2_24_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.199711121"},{"key":"e_1_2_2_24_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.19971091023"},{"key":"e_1_2_2_25_1","doi-asserted-by":"publisher","DOI":"10.1021\/ic00207a004"},{"key":"e_1_2_2_26_1","doi-asserted-by":"publisher","DOI":"10.31635\/ccschem.020.202000546"},{"key":"e_1_2_2_27_1","doi-asserted-by":"publisher","DOI":"10.1039\/C6CC05284C"},{"key":"e_1_2_2_28_1","doi-asserted-by":"publisher","DOI":"10.1039\/c0cc04697c"},{"key":"e_1_2_2_29_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja5060127"},{"key":"e_1_2_2_30_1","doi-asserted-by":"publisher","DOI":"10.1039\/B910889K"},{"key":"e_1_2_2_31_1","doi-asserted-by":"publisher","DOI":"10.1021\/ic800852d"},{"key":"e_1_2_2_32_1","unstructured":"Deposition Number(s)2089426 (forTOC-34) 2089427 (forTOC-35) 2089428 (forTOC-36)contain(s) the supplementary crystallographic data for this paper. These data are provided free of charge by the joint Cambridge Crystallographic Data Centre and Fachinformationszentrum KarlsruheAccess Structures service."},{"key":"e_1_2_2_33_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202004149"},{"key":"e_1_2_2_33_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.202004149"}],"container-title":["Chemistry \u2013 A European Journal"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/chem.202103226","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/chem.202103226","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/chem.202103226","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,12]],"date-time":"2025-10-12T15:22:27Z","timestamp":1760282547000},"score":1,"resource":{"primary":{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/10.1002\/chem.202103226"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2021,10]]},"references-count":41,"journal-issue":{"issue":"65","published-print":{"date-parts":[[2021,11,22]]}},"alternative-id":["10.1002\/chem.202103226"],"URL":"https:\/\/doi.org\/10.1002\/chem.202103226","archive":["Portico"],"relation":{},"ISSN":["0947-6539","1521-3765"],"issn-type":[{"value":"0947-6539","type":"print"},{"value":"1521-3765","type":"electronic"}],"subject":[],"published":{"date-parts":[[2021,10]]},"assertion":[{"value":"2021-09-06","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2021-10-01","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}]}}