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The GBB\u20103CR process gives access to skeletally\u2010diverse cyclophanyl imidazole ligands, namely 3\u2010amino\u2010imidazo[1,2\u2010\n                    <jats:italic>a<\/jats:italic>\n                    ]pyridines and imidazo[1,2\u2010\n                    <jats:italic>a<\/jats:italic>\n                    ]pyrazines. Additionally, a one\u2010pot protocol for the GBB\u20103CR by an in\u2005situ generation of cyclophanyl isocyanide is demonstrated. The products were analyzed by detailed spectroscopic techniques, and the cyclophanyl imidazo[1,2\u2010\n                    <jats:italic>a<\/jats:italic>\n                    ]pyridine was confirmed unambiguously by single\u2010crystal X\u2010Ray crystallography. The cyclophanyl imidazole ligands can be readily transformed to showcase their useful utility in preparing N,C\u2010palladacycles through regioselective\n                    <jats:italic>ortho<\/jats:italic>\n                    \u2010palladation.\n                  <\/jats:p>","DOI":"10.1002\/chem.202103511","type":"journal-article","created":{"date-parts":[[2021,11,18]],"date-time":"2021-11-18T10:52:55Z","timestamp":1637232775000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":11,"title":["Diversity\u2010Oriented Synthesis of [2.2]Paracyclophane\u2010derived Fused Imidazo[1,2\u2010\n                    <i>a<\/i>\n                    ]heterocycles by Groebke\u2010Blackburn\u2010Bienaym\u00e9 Reaction: Accessing Cyclophanyl Imidazole Ligands Library"],"prefix":"10.1002","volume":"28","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-2150-9634","authenticated-orcid":false,"given":"Mareen","family":"Stahlberger","sequence":"first","affiliation":[{"name":"Institute of Organic Chemistry (IOC) Karlsruhe Institute of Technology (KIT)  Fritz-Haber-Weg 6 76131 Karlsruhe Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Noah","family":"Schwarz","sequence":"additional","affiliation":[{"name":"Institute of Organic Chemistry (IOC) Karlsruhe Institute of Technology (KIT)  Fritz-Haber-Weg 6 76131 Karlsruhe Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9279-1476","authenticated-orcid":false,"given":"Christoph","family":"Zippel","sequence":"additional","affiliation":[{"name":"Institute of Organic Chemistry (IOC) Karlsruhe Institute of Technology (KIT)  Fritz-Haber-Weg 6 76131 Karlsruhe Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jens","family":"Hohmann","sequence":"additional","affiliation":[{"name":"Institute of Organic Chemistry (IOC) Karlsruhe Institute of Technology (KIT)  Fritz-Haber-Weg 6 76131 Karlsruhe Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1677-0109","authenticated-orcid":false,"given":"Martin","family":"Nieger","sequence":"additional","affiliation":[{"name":"Department of Chemistry University of Helsinki  P. 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