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However, the self\u2010poisoning caused by the strongly adsorbed reaction intermediates (typically, CO) is a critical problem in ethanol oxidation reaction. To address this issue, we proposed a joint use of two strategies, alloying of Pt with other metals and building Pt\/metal\u2010oxide interfaces, to achieve high\u2010performance electrocatalytic ethanol oxidation. For this, a well\u2010designed synthetic route combining wet impregnation with a two\u2010step thermal treatment process was established to construct PtSn\/SnO\n                    <jats:sub>x<\/jats:sub>\n                    interfaces on carbon nanotubes. Using this route, the alloying of Pt\u2212Sn and formation of PtSn\u2212SnO\n                    <jats:sub>x<\/jats:sub>\n                    interfaces can simultaneously be achieved, and the coverage of SnO\n                    <jats:sub>x<\/jats:sub>\n                    thin films on PtSn alloy nanoparticles can be facilely tuned by the strong interaction between Pt and SnO\n                    <jats:sub>x<\/jats:sub>\n                    . The results revealed that the partial coverage of SnO\n                    <jats:sub>x<\/jats:sub>\n                    species not only retained the active sites, but also enhanced the CO anti\u2010poisoning ability of the catalyst. Consequently, the H\u2212PtSn\/SnO\n                    <jats:sub>x<\/jats:sub>\n                    \/CNT\u20102 catalyst with an optimized PtSn\u2212SnO\n                    <jats:sub>x<\/jats:sub>\n                    interface showed significantly improved performances toward the ethanol oxidation reaction (825\u2005mA\u2009mg\n                    <jats:sub>Pt<\/jats:sub>\n                    <jats:sup>\u22121<\/jats:sup>\n                    ). This study provides deep insights into the structure\u2010performance relationship of PtSn\/metal oxide composite catalysts, which would be helpful for the future design and fabrication of high\u2010performance Pt\u2010based ethanol oxidation reaction catalysts.\n                  <\/jats:p>","DOI":"10.1002\/chem.202103521","type":"journal-article","created":{"date-parts":[[2021,11,17]],"date-time":"2021-11-17T12:15:44Z","timestamp":1637151344000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":9,"title":["Platinum\u2010Tin\/Tin Oxide\/CNT Catalysts for High\u2010Performance Electrocatalytic Ethanol Oxidation"],"prefix":"10.1002","volume":"28","author":[{"given":"Zhiping","family":"Zheng","sequence":"first","affiliation":[{"name":"State Key Laboratory of Physical Chemistry of Solid Surfaces and Collaborative Innovation Center of Chemistry for Energy Materials (iChEM) College of Chemistry and Chemical Engineering Xiamen University  Xiamen 361005, Fujian P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Qiaorong","family":"Jiang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Physical Chemistry of Solid Surfaces and Collaborative Innovation Center of Chemistry for Energy Materials (iChEM) College of Chemistry and Chemical Engineering Xiamen University  Xiamen 361005, Fujian P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiqing","family":"Cheng","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Physical Chemistry of Solid Surfaces and Collaborative Innovation Center of Chemistry for Energy Materials (iChEM) College of Chemistry and Chemical Engineering Xiamen University  Xiamen 361005, Fujian P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiao","family":"Han","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Physical Chemistry of Solid Surfaces and Collaborative Innovation Center of Chemistry for Energy Materials (iChEM) College of Chemistry and Chemical Engineering Xiamen University  Xiamen 361005, Fujian P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4111-291X","authenticated-orcid":false,"given":"Qin","family":"Kuang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Physical Chemistry of Solid Surfaces and Collaborative Innovation Center of Chemistry for Energy Materials (iChEM) College of Chemistry and Chemical Engineering Xiamen University  Xiamen 361005, Fujian P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhaoxiong","family":"Xie","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Physical Chemistry of Solid Surfaces and Collaborative Innovation Center of Chemistry for Energy Materials (iChEM) College of Chemistry and Chemical Engineering Xiamen University  Xiamen 361005, Fujian P. R. China"},{"name":"Pen-Tung Sah Institute of Micro-Nano Science and Technology Xiamen University  Xiamen 361005, Fujian P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2021,12,8]]},"reference":[{"key":"e_1_2_7_1_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.1137013"},{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apenergy.2015.02.002"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1021\/cs500147p"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jpowsour.2007.04.009"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.8b00588"},{"key":"e_1_2_7_6_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201805833"},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.elecom.2015.03.019"},{"key":"e_1_2_7_8_1","doi-asserted-by":"publisher","DOI":"10.1021\/jp014645c"},{"key":"e_1_2_7_9_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.201806300"},{"key":"e_1_2_7_10_1","doi-asserted-by":"publisher","DOI":"10.1016\/0013-4686(94)80097-9"},{"key":"e_1_2_7_11_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201804074"},{"key":"e_1_2_7_12_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201906137"},{"key":"e_1_2_7_12_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201906137"},{"key":"e_1_2_7_13_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jpowsour.2014.11.050"},{"key":"e_1_2_7_14_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2016.07.011"},{"key":"e_1_2_7_15_1","doi-asserted-by":"publisher","DOI":"10.3390\/molecules21091225"},{"key":"e_1_2_7_16_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja505456w"},{"key":"e_1_2_7_17_1","doi-asserted-by":"publisher","DOI":"10.1021\/jp408207u"},{"key":"e_1_2_7_18_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2015.08.044"},{"key":"e_1_2_7_19_1","doi-asserted-by":"publisher","DOI":"10.1002\/celc.201402390"},{"key":"e_1_2_7_20_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja102931d"},{"key":"e_1_2_7_21_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.8b01573"},{"key":"e_1_2_7_22_1","doi-asserted-by":"publisher","DOI":"10.1021\/jz3015925"},{"key":"e_1_2_7_23_1","doi-asserted-by":"publisher","DOI":"10.1038\/nmat2359"},{"key":"e_1_2_7_24_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b02286"},{"key":"e_1_2_7_25_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja00469a029"},{"key":"e_1_2_7_26_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.211.4487.1121"},{"key":"e_1_2_7_27_1","doi-asserted-by":"publisher","DOI":"10.1021\/ar00143a001"},{"key":"e_1_2_7_28_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.aad5705"},{"key":"e_1_2_7_29_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-019-13755-5"},{"key":"e_1_2_7_30_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2008.01.011"},{"key":"e_1_2_7_31_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.surfrep.2007.07.001"},{"key":"e_1_2_7_32_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-021-24228-z"}],"container-title":["Chemistry \u2013 A European Journal"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/chem.202103521","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/chem.202103521","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/chem.202103521","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,12]],"date-time":"2025-10-12T10:22:48Z","timestamp":1760264568000},"score":1,"resource":{"primary":{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/10.1002\/chem.202103521"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2021,12,8]]},"references-count":33,"journal-issue":{"issue":"4","published-print":{"date-parts":[[2022,1,19]]}},"alternative-id":["10.1002\/chem.202103521"],"URL":"https:\/\/doi.org\/10.1002\/chem.202103521","archive":["Portico"],"relation":{},"ISSN":["0947-6539","1521-3765"],"issn-type":[{"value":"0947-6539","type":"print"},{"value":"1521-3765","type":"electronic"}],"subject":[],"published":{"date-parts":[[2021,12,8]]},"assertion":[{"value":"2021-09-28","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2021-12-08","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e202103521"}}