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Herein, the preparation of a series of ylide\u2010substituted cations of type [YPR]<jats:sup>+<\/jats:sup> (with Y=Ph<jats:sub>3<\/jats:sub>PC(Ph), R=Ph, Cy or Y) and their structural and coordination properties are reported. Although the diylide\u2010substituted cation forms spontaneous from the chlorophosphine precursor, the monoylidylphosphenium ions required the addition of a halide\u2010abstraction reagent. The molecular structures of the cations reflected the different degrees of electron donation from the ylide to the phosphorus center depending on the second substituent. Molecular orbital analysis confirmed the stronger donor properties of the ylide systems compared to NHPs with the mono\u2010ylide substituted cations featuring a more pronounced electrophilicity. This was mirrored by the reaction of the cations towards gold chloride, in which only the diylide\u2010substituted cation [Y<jats:sub>2<\/jats:sub>P]<jats:sup>+<\/jats:sup> formed the expected LAuCl]<jats:sup>+<\/jats:sup> complex, while the monoylide\u2010substituted compounds reacted to the chlorophosphine ligands by transfer of the chloride from gold to the phosphorus center. These results demonstrate the tunability of ylide\u2010functionalized phosphorus cations, which should allow for further applications in coordination chemistry in the future.<\/jats:p>","DOI":"10.1002\/chem.202104074","type":"journal-article","created":{"date-parts":[[2021,12,10]],"date-time":"2021-12-10T09:30:56Z","timestamp":1639128656000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":13,"title":["Ylide\u2010Stabilized Phosphenium Cations: Impact of the Substitution Pattern on the Coordination Chemistry"],"prefix":"10.1002","volume":"28","author":[{"given":"Tobias","family":"Stalder","sequence":"first","affiliation":[{"name":"Chair of Inorganic Chemistry II Faculty of Chemistry and Biochemistry Ruhr-University Bochum  Universit\u00e4tsstra\u00dfe 150 44801 Bochum Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Felix","family":"Krischer","sequence":"additional","affiliation":[{"name":"Chair of Inorganic Chemistry II Faculty of Chemistry and Biochemistry Ruhr-University Bochum  Universit\u00e4tsstra\u00dfe 150 44801 Bochum Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1327-2801","authenticated-orcid":false,"given":"Henning","family":"Steinert","sequence":"additional","affiliation":[{"name":"Chair of Inorganic Chemistry II Faculty of Chemistry and Biochemistry Ruhr-University Bochum  Universit\u00e4tsstra\u00dfe 150 44801 Bochum Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Philipp","family":"Neigenfind","sequence":"additional","affiliation":[{"name":"Chair of Inorganic Chemistry II Faculty of Chemistry and Biochemistry Ruhr-University Bochum  Universit\u00e4tsstra\u00dfe 150 44801 Bochum Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6557-2366","authenticated-orcid":false,"given":"Viktoria 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