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In the crystalline state of the unsubstituted derivative, intermolecular \u03c0\u2013\u03c0 and CH\u2013\u03c0 interactions between the anthracene units drive the formation of the two\u2010dimensional packing structure. Owing to though\u2010space \u03c0\u2010conjugation between anthracene units, the substances have unique electronic properties. The excited\u2010state dynamic behavior occurring between the three anthracene moieties, such as exciton localization\/delocalization, was elucidated by means of transient absorption measurements and quantum chemical calculations. Interestingly, even though the three anthracenes are closely oriented with approximately 3.0\u2005\u00c5 between their C\u20109 positions, exciton localization on two anthracene units is energetically favorable because of the flexible nature of the radially arranged aromatic rings.<\/jats:p>","DOI":"10.1002\/chem.202104245","type":"journal-article","created":{"date-parts":[[2021,12,15]],"date-time":"2021-12-15T04:17:13Z","timestamp":1639541833000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":11,"title":["1,2,3\u2010Tri(9\u2010anthryl)benzene: Photophysical Properties and Solid\u2010State Intermolecular Interactions of Radially Arranged, Congested Aromatic \u03c0\u2010Planes**"],"prefix":"10.1002","volume":"28","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-2113-0731","authenticated-orcid":false,"given":"Tomohiko","family":"Nishiuchi","sequence":"first","affiliation":[{"name":"Department of Chemistry, Graduate School of Science Osaka University  1-1 Machikaneyama, Toyonaka Osaka 560-0043 Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6391-1851","authenticated-orcid":false,"given":"Hikaru","family":"Sotome","sequence":"additional","affiliation":[{"name":"Division of Frontier Materials Science and Center for Advanced Interdisciplinary Research Graduate School of Engineering Science Osaka University  1-3 Machikaneyama, Toyonaka Osaka 560-8531 Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kazuto","family":"Shimizu","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Graduate School of Science Osaka University  1-1 Machikaneyama, Toyonaka Osaka 560-0043 Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6020-6591","authenticated-orcid":false,"given":"Hiroshi","family":"Miyasaka","sequence":"additional","affiliation":[{"name":"Division of Frontier Materials Science and Center for Advanced Interdisciplinary Research Graduate School of Engineering Science Osaka University  1-3 Machikaneyama, Toyonaka Osaka 560-8531 Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6809-7396","authenticated-orcid":false,"given":"Takashi","family":"Kubo","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Graduate School of Science Osaka University  1-1 Machikaneyama, Toyonaka Osaka 560-0043 Japan"},{"name":"Innovative Catalysis Science Division Institute for Open and Transdisciplinary Research Initiatives (ICS-OTRI) Osaka University  Suita Osaka 565-0871 Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2022,1,3]]},"reference":[{"key":"e_1_2_8_1_1","unstructured":"\u00a0"},{"key":"e_1_2_8_2_2","doi-asserted-by":"crossref","first-page":"915","DOI":"10.1038\/164915b0","volume":"164","author":"Brown C. 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