{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,8]],"date-time":"2026-07-08T00:15:04Z","timestamp":1783469704937,"version":"3.55.0"},"reference-count":78,"publisher":"Wiley","issue":"19","license":[{"start":{"date-parts":[[2022,3,8]],"date-time":"2022-03-08T00:00:00Z","timestamp":1646697600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22031009"],"award-info":[{"award-number":["22031009"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["21875248"],"award-info":[{"award-number":["21875248"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["21921001"],"award-info":[{"award-number":["21921001"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["21975256"],"award-info":[{"award-number":["21975256"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Chemistry A European J"],"published-print":{"date-parts":[[2022,4]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Through systematic experiments, two novel mercury iodate sulfates, namely, Hg<jats:sub>2<\/jats:sub>(IO<jats:sub>3<\/jats:sub>)<jats:sub>2<\/jats:sub>(SO<jats:sub>4<\/jats:sub>)(H<jats:sub>2<\/jats:sub>O) and Hg<jats:sub>2<\/jats:sub>(IO<jats:sub>3<\/jats:sub>)<jats:sub>2<\/jats:sub>(SO<jats:sub>4<\/jats:sub>) were obtained. They crystallize in monoclinic space group <jats:italic>C<\/jats:italic>2 and <jats:italic>C<\/jats:italic>2\/<jats:italic>c<\/jats:italic>, respectively. Hg<jats:sub>2<\/jats:sub>(IO<jats:sub>3<\/jats:sub>)<jats:sub>2<\/jats:sub>(SO<jats:sub>4<\/jats:sub>)(H<jats:sub>2<\/jats:sub>O) exhibits the [Hg(IO<jats:sub>3<\/jats:sub>)]<jats:sup>+<\/jats:sup> polar cationic layer inherited from Hg(IO<jats:sub>3<\/jats:sub>)<jats:sub>2<\/jats:sub> and the three\u2010dimensional (3D) framework inherited from HgSO<jats:sub>4<\/jats:sub>. This enables Hg<jats:sub>2<\/jats:sub>(IO<jats:sub>3<\/jats:sub>)<jats:sub>2<\/jats:sub>(SO<jats:sub>4<\/jats:sub>)(H<jats:sub>2<\/jats:sub>O) to generate a strong second harmonic generation (SHG) response of 6 times that of KH<jats:sub>2<\/jats:sub>PO<jats:sub>4<\/jats:sub> (KDP). The structure of Hg<jats:sub>2<\/jats:sub>(IO<jats:sub>3<\/jats:sub>)<jats:sub>2<\/jats:sub>(SO<jats:sub>4<\/jats:sub>) is very similar to that of Hg<jats:sub>2<\/jats:sub>(IO<jats:sub>3<\/jats:sub>)<jats:sub>2<\/jats:sub>(SO<jats:sub>4<\/jats:sub>)(H<jats:sub>2<\/jats:sub>O), and they can be transformed into each other. Hg<jats:sub>2<\/jats:sub>(IO<jats:sub>3<\/jats:sub>)<jats:sub>2<\/jats:sub>(SO<jats:sub>4<\/jats:sub>)(H<jats:sub>2<\/jats:sub>O) shows a large optical band gap of 3.98\u2005eV and a high dehydration temperature of 250\u2009\u00b0C. This study indicates that by reasonable design, the introduction of multiple functional groups into a compound may combine their advantages to achieve good overall optical performance.<\/jats:p>","DOI":"10.1002\/chem.202200001","type":"journal-article","created":{"date-parts":[[2022,2,14]],"date-time":"2022-02-14T09:32:35Z","timestamp":1644831155000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":9,"title":["Explorations of New SHG Materials in Mercury Iodate Sulfate System**"],"prefix":"10.1002","volume":"28","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-8095-5330","authenticated-orcid":false,"given":"Yi\u2010Lin","family":"Li","sequence":"first","affiliation":[{"name":"State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences  Fuzhou 350002 China"},{"name":"School of Physical Science and Technology ShanghaiTech University  Shanghai 201210 China"},{"name":"Shanghai Advanced Research Institute Chinese Academy of Sciences  Shanghai 201210 China"},{"name":"University of Chinese Academy of Sciences  Beijing 100049 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Meng\u2010Ya","family":"Ji","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences  Fuzhou 350002 China"},{"name":"University of Chinese Academy of Sciences  Beijing 100049 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chun\u2010Li","family":"Hu","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences  Fuzhou 350002 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jin","family":"Chen","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences  Fuzhou 350002 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Bing\u2010Xuan","family":"Li","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences  Fuzhou 350002 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yuan","family":"Lin","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences  Fuzhou 350002 China"},{"name":"Strait Institute of Flexible Electronics (SIFE, Future Technologies) Fujian Normal University  Fuzhou 350117, Fujian China"},{"name":"Strait Laboratory of Flexible Electronics (SLoFE)  Fuzhou 350117, Fujian China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5101-8898","authenticated-orcid":false,"given":"Jiang\u2010Gao","family":"Mao","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences  Fuzhou 350002 China"},{"name":"University of Chinese Academy of Sciences  Beijing 100049 China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2022,3,8]]},"reference":[{"key":"e_1_2_7_1_1","unstructured":"\u00a0"},{"key":"e_1_2_7_2_2","first-page":"13","volume":"142","author":"Pan C. Y.","year":"2020","journal-title":"J. Am. Chem. Soc."},{"key":"e_1_2_7_3_2","doi-asserted-by":"publisher","DOI":"10.1007\/s11433-021-1720-3"},{"key":"e_1_2_7_4_1","unstructured":"\u00a0"},{"key":"e_1_2_7_5_2","first-page":"235","volume":"28","author":"Chen C. T.","year":"1985","journal-title":"Sci. China Ser. B"},{"key":"e_1_2_7_6_2","doi-asserted-by":"publisher","DOI":"10.1016\/0022-0248(93)90089-F"},{"key":"e_1_2_7_7_2","doi-asserted-by":"publisher","DOI":"10.1364\/AO.1.000661"},{"key":"e_1_2_7_8_2","doi-asserted-by":"publisher","DOI":"10.1063\/1.322459"},{"key":"e_1_2_7_9_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0030-4018(98)00397-6"},{"key":"e_1_2_7_10_2","doi-asserted-by":"publisher","DOI":"10.1063\/1.1653673"},{"key":"e_1_2_7_11_1","unstructured":"\u00a0"},{"key":"e_1_2_7_12_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.1c01181"},{"key":"e_1_2_7_13_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202103657"},{"key":"e_1_2_7_13_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.202103657"},{"key":"e_1_2_7_14_2","doi-asserted-by":"publisher","DOI":"10.1039\/D1QI00595B"},{"key":"e_1_2_7_15_2","doi-asserted-by":"publisher","DOI":"10.1039\/D1TC01806J"},{"key":"e_1_2_7_16_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201909735"},{"key":"e_1_2_7_16_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201909735"},{"key":"e_1_2_7_17_1","doi-asserted-by":"publisher","DOI":"10.1002\/advs.202003594"},{"key":"e_1_2_7_18_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b00138"},{"key":"e_1_2_7_19_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201900637"},{"key":"e_1_2_7_19_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201900637"},{"key":"e_1_2_7_20_1","author":"Dong X. H.","year":"2022","journal-title":"Angew. Chem. Int. Ed."},{"key":"e_1_2_7_21_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.1c00416"},{"key":"e_1_2_7_22_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.1c01401"},{"key":"e_1_2_7_23_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9TC03105G"},{"key":"e_1_2_7_24_1","unstructured":"\u00a0"},{"key":"e_1_2_7_25_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja9030566"},{"key":"e_1_2_7_26_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja205456b"},{"key":"e_1_2_7_27_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201908935"},{"key":"e_1_2_7_27_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201908935"},{"key":"e_1_2_7_28_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201913287"},{"key":"e_1_2_7_28_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201913287"},{"key":"e_1_2_7_29_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.1c00188"},{"key":"e_1_2_7_30_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202000587"},{"key":"e_1_2_7_30_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.202000587"},{"key":"e_1_2_7_31_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemmater.0c01452"},{"key":"e_1_2_7_32_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9SC04832D"},{"key":"e_1_2_7_33_1","unstructured":"\u00a0"},{"key":"e_1_2_7_34_2","doi-asserted-by":"publisher","DOI":"10.1021\/cm500898q"},{"key":"e_1_2_7_35_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201904383"},{"key":"e_1_2_7_35_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201904383"},{"key":"e_1_2_7_36_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemmater.0c00878"},{"key":"e_1_2_7_37_1","doi-asserted-by":"crossref","unstructured":"Q.\u2005Q. Chen C.\u2005L. Hu J. Chen Y.\u2005L. Li B.\u2005X. Li J.\u2005G. Mao Angew. Chem. Int. Ed.2021 60 17426\u201317429;Angew. Chem.2021 133 17566\u201317569.","DOI":"10.1002\/anie.202106592"},{"key":"e_1_2_7_38_1","unstructured":"\u00a0"},{"key":"e_1_2_7_39_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemmater.1c00222"},{"key":"e_1_2_7_40_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201611770"},{"key":"e_1_2_7_40_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201611770"},{"key":"e_1_2_7_41_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1SC01401C"},{"key":"e_1_2_7_42_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201412344"},{"key":"e_1_2_7_42_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201412344"},{"key":"e_1_2_7_42_3","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202105777"},{"key":"e_1_2_7_42_4","doi-asserted-by":"publisher","DOI":"10.1002\/ange.202105777"},{"key":"e_1_2_7_43_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201813122"},{"key":"e_1_2_7_43_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201813122"},{"key":"e_1_2_7_44_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0CC07862J"},{"key":"e_1_2_7_45_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1CC03483A"},{"key":"e_1_2_7_46_1","unstructured":"\u00a0"},{"key":"e_1_2_7_47_2","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.1c06933"},{"key":"e_1_2_7_48_2","doi-asserted-by":"publisher","DOI":"10.1002\/adom.202100563"},{"key":"e_1_2_7_49_2","doi-asserted-by":"publisher","DOI":"10.1039\/D0TC05093H"},{"key":"e_1_2_7_50_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b05125"},{"key":"e_1_2_7_51_1","unstructured":"J.\u2005G. Speight Lange's Handbook Of Chemistry McGraw-Hill New York 2005 p. 337."},{"key":"e_1_2_7_52_1","doi-asserted-by":"publisher","DOI":"10.1016\/S1293-2558(03)00004-9"},{"key":"e_1_2_7_53_1","unstructured":"\u00a0"},{"key":"e_1_2_7_54_2","doi-asserted-by":"publisher","DOI":"10.1107\/S0567740880002361"},{"key":"e_1_2_7_55_2","doi-asserted-by":"publisher","DOI":"10.1107\/S1600536814011155"},{"key":"e_1_2_7_56_2","first-page":"113","volume":"390","author":"Ahmed M. A. K.","year":"2002","journal-title":"Acta"},{"key":"e_1_2_7_57_1","unstructured":"Deposition Numbers2114042 [for Hg2(IO3)2(SO4)(H2O)] and 2114043 [for Hg2(IO3)2(SO4)]contain the supplementary crystallographic data for this paper. These data are provided free of charge by the joint Cambridge Crystallographic Data Centre and Fachinformationszentrum KarlsruheAccess Structures service."},{"key":"e_1_2_7_58_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9CC02774B"},{"key":"e_1_2_7_59_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.1c00269"},{"key":"e_1_2_7_60_1","doi-asserted-by":"crossref","unstructured":"K. Nakamoto Infrared and Raman Spectra of Inorganic and Coordination Compounds Part A: Theory and Applications in Inorganic Chemistry Wiley Hoboken 2009 p168\u2013202.","DOI":"10.1002\/9780470405840"},{"key":"e_1_2_7_61_1","first-page":"756","volume":"22","author":"Chen C. T.","year":"1979","journal-title":"Sci. China"},{"key":"e_1_2_7_62_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201813968"},{"key":"e_1_2_7_62_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201813968"},{"key":"e_1_2_7_63_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.36.6497"},{"key":"e_1_2_7_64_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202014279"},{"key":"e_1_2_7_64_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.202014279"}],"updated-by":[{"DOI":"10.1002\/chem.202201757","type":"correction","label":"Correction","source":"publisher","updated":{"date-parts":[[2022,6,24]],"date-time":"2022-06-24T00:00:00Z","timestamp":1656028800000}}],"container-title":["Chemistry \u2013 A European Journal"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/chem.202200001","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/chem.202200001","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/chem.202200001","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,12]],"date-time":"2025-10-12T14:27:53Z","timestamp":1760279273000},"score":1,"resource":{"primary":{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/10.1002\/chem.202200001"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2022,3,8]]},"references-count":78,"journal-issue":{"issue":"19","published-print":{"date-parts":[[2022,4]]}},"alternative-id":["10.1002\/chem.202200001"],"URL":"https:\/\/doi.org\/10.1002\/chem.202200001","archive":["Portico"],"relation":{"correction":[{"id-type":"doi","id":"10.1002\/chem.202201757","asserted-by":"object"}]},"ISSN":["0947-6539","1521-3765"],"issn-type":[{"value":"0947-6539","type":"print"},{"value":"1521-3765","type":"electronic"}],"subject":[],"published":{"date-parts":[[2022,3,8]]},"assertion":[{"value":"2022-01-01","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2022-03-08","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e202200001"}}