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The relative intensities of luminescence of Tb<jats:sup>3+<\/jats:sup> and Eu<jats:sup>3+<\/jats:sup> are governed by Tb<jats:sup>3+<\/jats:sup>\u2010to\u2010Eu<jats:sup>3+<\/jats:sup> phonon\u2010assisted energy transfer and Tb<jats:sup>3+<\/jats:sup>\u2010to\u2010ligand back transfer and are responsible for the differing temperature\u2010dependent luminescence of the two ions. This provides a ratiometric luminescent thermometer in the 288\u2013573\u2005K temperature range, not previously seen for MOF materials, with a high sensitivity, 1.69\u00b10.04\u2009%\u2009K<jats:sup>\u22121<\/jats:sup> at 523\u2005K. In aqueous conditions, loosely bound H<jats:sub>2<\/jats:sub>O can be replaced by D<jats:sub>2<\/jats:sub>O in the same material, which modifies decay lifetimes to yield a quantitative luminescent D<jats:sub>2<\/jats:sub>O sensor with a useful sensitivity for practical application.<\/jats:p>","DOI":"10.1002\/chem.202200410","type":"journal-article","created":{"date-parts":[[2022,2,14]],"date-time":"2022-02-14T11:56:27Z","timestamp":1644839787000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":20,"title":["A Highly Stable Yttrium Organic Framework as a Host for Optical Thermometry and D<sub>2<\/sub>O Detection"],"prefix":"10.1002","volume":"28","author":[{"given":"Thomas W.","family":"Chamberlain","sequence":"first","affiliation":[{"name":"Department of Chemistry University of Warwick  Coventry CV4 7AL UK"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Rafael 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