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The latter were obtained in high yield and characterized among others by X\u2010ray analysis and elemental analysis. Complex <jats:bold>[L<jats:sub>2<\/jats:sub>CoBr](PF<jats:sub>6<\/jats:sub>)<\/jats:bold> showed a very good catalytic activity for the hydrosilylation of various ketones. The catalysis proceeds at a low catalytic loading (1\u2005mol\u2009%) with only 1 equivalent of Ph<jats:sub>2<\/jats:sub>SiH<jats:sub>2<\/jats:sub> in mild conditions and was efficient with aliphatic or aromatic ketones giving moderate to excellent yields of the corresponding silylated ether.<\/jats:p>","DOI":"10.1002\/chem.202200437","type":"journal-article","created":{"date-parts":[[2022,4,11]],"date-time":"2022-04-11T10:24:47Z","timestamp":1649672687000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":18,"title":["Cobalt Complexes Supported by Phosphinoquinoline Ligands for the Catalyzed Hydrosilylation of Carbonyl Compounds"],"prefix":"10.1002","volume":"28","author":[{"given":"Pauline","family":"Schiltz","sequence":"first","affiliation":[{"name":"Laboratoire de Chimie Mol\u00e9culaire (LCM) CNRS Ecole Polytechnique, Institut Polytechnique de Paris  Route de Saclay 91120 Palaiseau France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0636-983X","authenticated-orcid":false,"given":"Nicolas","family":"Casaretto","sequence":"additional","affiliation":[{"name":"Laboratoire de Chimie Mol\u00e9culaire (LCM) CNRS Ecole Polytechnique, Institut Polytechnique de Paris  Route de Saclay 91120 Palaiseau France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6952-4775","authenticated-orcid":false,"given":"Audrey","family":"Auffrant","sequence":"additional","affiliation":[{"name":"Laboratoire de Chimie Mol\u00e9culaire (LCM) CNRS Ecole Polytechnique, Institut Polytechnique de Paris  Route de Saclay 91120 Palaiseau France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1355-2301","authenticated-orcid":false,"given":"Corinne","family":"Gosmini","sequence":"additional","affiliation":[{"name":"Laboratoire de Chimie Mol\u00e9culaire (LCM) CNRS Ecole Polytechnique, Institut Polytechnique de Paris  Route de Saclay 91120 Palaiseau France"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2022,4,26]]},"reference":[{"key":"e_1_2_8_1_1","unstructured":"\u00a0"},{"key":"e_1_2_8_2_2","doi-asserted-by":"publisher","DOI":"10.1021\/jm200609t"},{"key":"e_1_2_8_3_2","doi-asserted-by":"publisher","DOI":"10.1039\/c4np00011k"},{"key":"e_1_2_8_4_1","unstructured":"\u00a0"},{"key":"e_1_2_8_5_2","doi-asserted-by":"publisher","DOI":"10.1021\/np070421v"},{"key":"e_1_2_8_6_2","doi-asserted-by":"publisher","DOI":"10.1039\/C9NP00070D"},{"key":"e_1_2_8_7_1","unstructured":"\u00a0"},{"key":"e_1_2_8_8_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00434a020"},{"key":"e_1_2_8_9_2","doi-asserted-by":"publisher","DOI":"10.1021\/jo00145a018"},{"key":"e_1_2_8_10_1","unstructured":"\u00a0"},{"key":"e_1_2_8_11_2","doi-asserted-by":"publisher","DOI":"10.1039\/C5CS00038F"},{"key":"e_1_2_8_12_2","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.9b01584"},{"key":"e_1_2_8_13_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.8b00555"},{"key":"e_1_2_8_14_1","unstructured":"\u00a0"},{"key":"e_1_2_8_15_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.5b00203"},{"key":"e_1_2_8_16_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201500937"},{"key":"e_1_2_8_17_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.5b00043"},{"key":"e_1_2_8_18_1","unstructured":"\u00a0"},{"key":"e_1_2_8_19_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr00102a004"},{"key":"e_1_2_8_20_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.6b00034"},{"key":"e_1_2_8_21_2","doi-asserted-by":"publisher","DOI":"10.1007\/s41061-015-0002-2"},{"key":"e_1_2_8_22_1","unstructured":"\u00a0"},{"key":"e_1_2_8_23_2","doi-asserted-by":"publisher","DOI":"10.1002\/cjoc.201800314"},{"key":"e_1_2_8_24_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.1c00212"},{"key":"e_1_2_8_25_1","unstructured":"\u00a0"},{"key":"e_1_2_8_26_2","unstructured":"B. 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