{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,5]],"date-time":"2026-10-05T20:10:13Z","timestamp":1791231013680,"version":"4.1.0"},"reference-count":46,"publisher":"Wiley","issue":"35","license":[{"start":{"date-parts":[[2022,4,29]],"date-time":"2022-04-29T00:00:00Z","timestamp":1651190400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by-nc-nd\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100001659","name":"Deutsche Forschungsgemeinschaft","doi-asserted-by":"publisher","award":["BU2725\/8-1"],"award-info":[{"award-number":["BU2725\/8-1"]}],"id":[{"id":"10.13039\/501100001659","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Chemistry A European J"],"published-print":{"date-parts":[[2022,6,21]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Diphenylberyllium [Be\n                    <jats:sub>3<\/jats:sub>\n                    Ph\n                    <jats:sub>6<\/jats:sub>\n                    ] is shown here to react cleanly as a Br\u00f8nsted base with a vast variety of protic compounds. Through the addition of the simple molecules\n                    <jats:italic>t<\/jats:italic>\n                    BuOH, HNPh\n                    <jats:sub>2<\/jats:sub>\n                    and HPPh\n                    <jats:sub>2<\/jats:sub>\n                    , as well as the more complex 1,3\u2010bis\u2010(2,6\u2010diisopropylphenyl)imidazolinium chloride, one or two phenyl groups in diphenylberyllium were protonated. As a result, the long\u2010postulated structures of [Be\n                    <jats:sub>3<\/jats:sub>\n                    (O\n                    <jats:italic>t<\/jats:italic>\n                    Bu)\n                    <jats:sub>6<\/jats:sub>\n                    ] and [Be(\u03bc\u2010NPh\n                    <jats:sub>2<\/jats:sub>\n                    )Ph]\n                    <jats:sub>2<\/jats:sub>\n                    have finally been verified and shown to be static in solution. Additionally [Be(\u03bc\u2010PPh\n                    <jats:sub>2<\/jats:sub>\n                    )(HPPh\n                    <jats:sub>2<\/jats:sub>\n                    )Ph]\n                    <jats:sub>2<\/jats:sub>\n                    was generated, which is only the second beryllium\u2010phospanide to be prepared; the stark differences between its behaviour and that of the analogous amide were also examined. The first crystalline example of a beryllium Grignard reagent with a non\u2010bulky aryl group has also been prepared; it is stabilised with an N\u2010heterocyclic carbene.\n                  <\/jats:p>","DOI":"10.1002\/chem.202200851","type":"journal-article","created":{"date-parts":[[2022,4,7]],"date-time":"2022-04-07T09:35:33Z","timestamp":1649324133000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":17,"title":["Reactivity of Diphenylberyllium as a Br\u00f8nsted Base and Its Synthetic Application"],"prefix":"10.1002","volume":"28","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-2895-6931","authenticated-orcid":false,"given":"Lewis R.","family":"Thomas\u2010Hargreaves","sequence":"first","affiliation":[{"name":"Fachbereich Chemie Philipps-Universit\u00e4t Marburg  35043 Marburg Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chantsalmaa","family":"Berthold","sequence":"additional","affiliation":[{"name":"Fachbereich Chemie Philipps-Universit\u00e4t Marburg  35043 Marburg Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"William","family":"Augustinov","sequence":"additional","affiliation":[{"name":"Fachbereich Chemie Philipps-Universit\u00e4t Marburg  35043 Marburg Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Matthias","family":"M\u00fcller","sequence":"additional","affiliation":[{"name":"Fachbereich Chemie Philipps-Universit\u00e4t Marburg  35043 Marburg Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sergei I.","family":"Ivlev","sequence":"additional","affiliation":[{"name":"Fachbereich Chemie Philipps-Universit\u00e4t Marburg  35043 Marburg Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3242-6797","authenticated-orcid":false,"given":"Magnus R.","family":"Buchner","sequence":"additional","affiliation":[{"name":"Fachbereich Chemie Philipps-Universit\u00e4t Marburg  35043 Marburg Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2022,4,29]]},"reference":[{"key":"e_1_2_3_1_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201601809"},{"key":"e_1_2_3_1_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201601809"},{"key":"e_1_2_3_2_1","doi-asserted-by":"publisher","DOI":"10.1515\/znb-2020-0006"},{"key":"e_1_2_3_3_1","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.2542"},{"key":"e_1_2_3_4_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b13777"},{"key":"e_1_2_3_5_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.organomet.0c00434"},{"key":"e_1_2_3_6_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202016027"},{"key":"e_1_2_3_6_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.202016027"},{"key":"e_1_2_3_7_1","doi-asserted-by":"publisher","DOI":"10.1016\/B978-0-08-097774-4.00145-5"},{"key":"e_1_2_3_8_1","first-page":"10.1002","volume-title":"Encyclopedia of Inorganic and Bioinorganic Chemistry","author":"Mason M. 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