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The homologous complexes of germanium and lead, [Cp*<jats:sub>2<\/jats:sub>Ln(\u03bc\u2010H)<jats:sub>2<\/jats:sub>EAr*] (E = Ge, Pb), were accessed via addition of low\u2010valent [(Ar*EH)<jats:sub>2<\/jats:sub>] to the rare\u2010earth\u2010metal hydrides [(Cp*<jats:sub>2<\/jats:sub>LnH)<jats:sub>2<\/jats:sub>]. The lead compounds [Cp*<jats:sub>2<\/jats:sub>Ln(\u03bc\u2010H)<jats:sub>2<\/jats:sub>PbAr*] exhibit H\/D exchange in reactions with deuterated solvents or dihydrogen.<\/jats:p>","DOI":"10.1002\/chem.202201032","type":"journal-article","created":{"date-parts":[[2022,5,27]],"date-time":"2022-05-27T03:04:05Z","timestamp":1653620645000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":5,"title":["Molecular Ln(III)\u2212H\u2212E(II) Linkages (Ln=Y, Lu; E=Ge, Sn, Pb)"],"prefix":"10.1002","volume":"28","author":[{"given":"Max","family":"Widemann","sequence":"first","affiliation":[{"name":"Institut f\u00fcr Anorganische Chemie Eberhard Karls Universit\u00e4t T\u00fcbingen  Auf der Morgenstelle 18 72076 T\u00fcbingen Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Frederik S. 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