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The complexes activate hydrogen and they appear to be more active in hydrogenation of ketones and imines than their tridentate pincer analogs. This is thought, in part, to be due to the lack of trailing third phosphorus arm present in previous work. DFT computations reveal a sigma\u2010bond metathesis mechanism is comparable to an alternative aromatization\/dearomatization metal\u2010ligand cooperative mechanism.<\/jats:p>","DOI":"10.1002\/chem.202201042","type":"journal-article","created":{"date-parts":[[2022,5,6]],"date-time":"2022-05-06T10:45:25Z","timestamp":1651833925000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":12,"title":["Hydrogenative Catalysis with Three\u2010Coordinate Zinc Complexes Supported with PN Ligands is Enhanced Compared to PNP Analogs"],"prefix":"10.1002","volume":"28","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-6535-2777","authenticated-orcid":false,"given":"Sanchita","family":"Paul","sequence":"first","affiliation":[{"name":"Department of Chemistry University at Buffalo State University of New York, Buffalo  New York 14260 United States"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7522-2535","authenticated-orcid":false,"given":"Pierpaolo","family":"Morgante","sequence":"additional","affiliation":[{"name":"Department of Chemistry University at Buffalo State University of New York, Buffalo  New York 14260 United States"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Samantha N.","family":"MacMillan","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Chemical Biology Cornell University, Ithaca  New York 14853 United States"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9392-877X","authenticated-orcid":false,"given":"Jochen","family":"Autschbach","sequence":"additional","affiliation":[{"name":"Department of Chemistry University at Buffalo State University of New York, Buffalo  New York 14260 United States"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5546-5081","authenticated-orcid":false,"given":"David C.","family":"Lacy","sequence":"additional","affiliation":[{"name":"Department of Chemistry University at Buffalo State University of New York, Buffalo  New York 14260 United States"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2022,5,31]]},"reference":[{"key":"e_1_2_3_1_1","unstructured":"\u00a0"},{"key":"e_1_2_3_2_2","doi-asserted-by":"crossref","first-page":"175","DOI":"10.1002\/9783527818020.ch7","volume-title":"Early Main Group Metal Catalysis: Concepts and Reactions","author":"Bauer H.","year":"2020"},{"key":"e_1_2_3_3_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.202003108"},{"key":"e_1_2_3_4_2","doi-asserted-by":"publisher","DOI":"10.1021\/om2008138"},{"key":"e_1_2_3_5_2","doi-asserted-by":"publisher","DOI":"10.1039\/C7QI00459A"},{"key":"e_1_2_3_6_1","unstructured":"\u00a0"},{"key":"e_1_2_3_7_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.1c10845"},{"key":"e_1_2_3_8_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.202100641"},{"key":"e_1_2_3_9_2","first-page":"167","volume-title":"Homogeneous hydrogenation with non-precious catalysts","author":"Paradies J.","year":"2020"},{"key":"e_1_2_3_10_2","doi-asserted-by":"publisher","DOI":"10.1039\/C7CS00154A"},{"key":"e_1_2_3_11_1","unstructured":"\u00a0"},{"key":"e_1_2_3_12_2","first-page":"2020","author":"Greb L.","year":"2020","journal-title":"Eur. 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