{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,28]],"date-time":"2026-09-28T23:32:35Z","timestamp":1790638355001,"version":"4.1.0"},"reference-count":62,"publisher":"Wiley","issue":"53","license":[{"start":{"date-parts":[[2022,8,3]],"date-time":"2022-08-03T00:00:00Z","timestamp":1659484800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by-nc\/4.0\/"}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Chemistry A European J"],"published-print":{"date-parts":[[2022,9,22]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>The one\u2010electron reduction of the nonheme iron(III)\u2010hydroperoxo complex, [Fe<jats:sup>III<\/jats:sup>(OOH)(L<jats:sub>5<\/jats:sub><jats:sup>2<\/jats:sup>)]<jats:sup>2+<\/jats:sup> (L<jats:sub>5<\/jats:sub><jats:sup>2<\/jats:sup>=<jats:italic>N<\/jats:italic>\u2010methyl\u2010<jats:italic>N<\/jats:italic>,<jats:italic>N\u2019<\/jats:italic>,<jats:italic>N\u2019<\/jats:italic>\u2010tris(2\u2010pyridylmethyl)ethane\u20101,2\u2010diamine), carried out at \u221270\u2009\u00b0C results in the release of dioxygen and in the formation of [Fe<jats:sup>II<\/jats:sup>(OH)(L<jats:sub>5<\/jats:sub><jats:sup>2<\/jats:sup>)]<jats:sup>+<\/jats:sup> following a bimolecular process. This reaction can be performed either with cobaltocene as chemical reductant, or electrochemically. These experimental observations are consistent with the disproportionation of the hydroperoxo group in the putative Fe<jats:sup>II<\/jats:sup>(OOH) intermediate generated upon reduction of the Fe<jats:sup>III<\/jats:sup>(OOH) starting complex. One plausible mechanistic scenario is that this disproportionation reaction follows an O\u2212O heterolytic cleavage pathway via a Fe<jats:sup>IV<\/jats:sup>\u2010oxo species.<\/jats:p>","DOI":"10.1002\/chem.202201600","type":"journal-article","created":{"date-parts":[[2022,6,23]],"date-time":"2022-06-23T05:49:20Z","timestamp":1655963360000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":10,"title":["Heterolytic O\u2212O Bond Cleavage Upon Single Electron Transfer to a Nonheme Fe(III)\u2212OOH Complex"],"prefix":"10.1002","volume":"28","author":[{"given":"Antoine","family":"Bohn","sequence":"first","affiliation":[{"name":"Institut de Chimie Mol\u00e9culaire et des Mat\u00e9riaux d'Orsay Universit\u00e9 Paris-Saclay CNRS  91405 Orsay France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Katell","family":"S\u00e9n\u00e9chal\u2010David","sequence":"additional","affiliation":[{"name":"Institut de Chimie Mol\u00e9culaire et des Mat\u00e9riaux d'Orsay Universit\u00e9 Paris-Saclay CNRS  91405 Orsay France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jean\u2010No\u00ebl","family":"Rebilly","sequence":"additional","affiliation":[{"name":"Institut de Chimie Mol\u00e9culaire et des Mat\u00e9riaux d'Orsay Universit\u00e9 Paris-Saclay CNRS  91405 Orsay France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Christian","family":"Herrero","sequence":"additional","affiliation":[{"name":"Institut de Chimie Mol\u00e9culaire et des Mat\u00e9riaux d'Orsay Universit\u00e9 Paris-Saclay CNRS  91405 Orsay France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Winfried","family":"Leibl","sequence":"additional","affiliation":[{"name":"Institute for Integrative Biology of the Cell (I2BC) Universit\u00e9 Paris-Saclay, CEA CNRS  91198 Gif-sur-Yvette France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Elodie","family":"Anxolab\u00e9h\u00e8re\u2010Mallart","sequence":"additional","affiliation":[{"name":"Laboratoire d'Electrochimie Mol\u00e9culaire Universit\u00e9 Paris Cit\u00e9 CNRS  75013 Paris France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8289-4965","authenticated-orcid":false,"given":"Fr\u00e9d\u00e9ric","family":"Banse","sequence":"additional","affiliation":[{"name":"Institut de Chimie Mol\u00e9culaire et des Mat\u00e9riaux d'Orsay Universit\u00e9 Paris-Saclay CNRS  91405 Orsay France"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2022,8,3]]},"reference":[{"key":"e_1_2_8_1_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr020443g"},{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr0307143"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr400415k"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.abb.2012.01.015"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2012.02.003"},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.1021\/jp036905r"},{"key":"e_1_2_8_7_1","doi-asserted-by":"publisher","DOI":"10.1021\/ic048714o"},{"key":"e_1_2_8_8_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.7b03559"},{"key":"e_1_2_8_9_1","doi-asserted-by":"publisher","DOI":"10.1039\/a607779j"},{"key":"e_1_2_8_10_1","doi-asserted-by":"publisher","DOI":"10.1002\/cssc.201300378"},{"key":"e_1_2_8_11_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.8b02326"},{"key":"e_1_2_8_12_1","doi-asserted-by":"publisher","DOI":"10.1007\/3-540-46592-8_6"},{"key":"e_1_2_8_13_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr020628n"},{"key":"e_1_2_8_14_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2014.06.009"},{"key":"e_1_2_8_15_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja010310x"},{"key":"e_1_2_8_16_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja0120025"},{"key":"e_1_2_8_17_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja402759c"},{"key":"e_1_2_8_18_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201300110"},{"key":"e_1_2_8_19_1","doi-asserted-by":"publisher","DOI":"10.1039\/C8CC03990A"},{"key":"e_1_2_8_20_1","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.1132"},{"key":"e_1_2_8_21_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-019-08668-2"},{"key":"e_1_2_8_22_1","doi-asserted-by":"publisher","DOI":"10.1007\/s00775-016-1434-z"},{"key":"e_1_2_8_23_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201102252"},{"key":"e_1_2_8_24_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201404918"},{"key":"e_1_2_8_25_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201903239"},{"key":"e_1_2_8_26_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201404556"},{"key":"e_1_2_8_26_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201404556"},{"key":"e_1_2_8_27_1","doi-asserted-by":"publisher","DOI":"10.1039\/c3sc51864g"},{"key":"e_1_2_8_28_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201103971"},{"key":"e_1_2_8_28_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201103971"},{"key":"e_1_2_8_29_1","doi-asserted-by":"publisher","DOI":"10.1021\/ic402443r"},{"key":"e_1_2_8_30_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201502229"},{"key":"e_1_2_8_30_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201502229"},{"key":"e_1_2_8_31_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.200701592"},{"key":"e_1_2_8_32_1","doi-asserted-by":"publisher","DOI":"10.1002\/1099-0682(200007)2000:7<1627::AID-EJIC1627>3.0.CO;2-9"},{"key":"e_1_2_8_33_1","doi-asserted-by":"publisher","DOI":"10.1039\/C4SC01891E"},{"key":"e_1_2_8_34_1","unstructured":"From a simple electrostatic model based on the Born equation it can be shown that the redox potential value of similar species increases with their size as observed when going from L52(Me substituent) to TPEN (pyridyl substituent). see Ref.\u2005[35]."},{"key":"e_1_2_8_35_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0020-1693(99)00502-2"},{"key":"e_1_2_8_36_1","doi-asserted-by":"publisher","DOI":"10.1021\/ic301834x"},{"key":"e_1_2_8_37_1","doi-asserted-by":"publisher","DOI":"10.1071\/CH13454"},{"key":"e_1_2_8_38_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5SC00024F"},{"key":"e_1_2_8_39_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr940053x"},{"key":"e_1_2_8_40_1","doi-asserted-by":"publisher","DOI":"10.1201\/9781420059588"},{"key":"e_1_2_8_41_1","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1099-0682(199906)1999:6<993::AID-EJIC993>3.0.CO;2-6"},{"key":"e_1_2_8_42_1","doi-asserted-by":"publisher","DOI":"10.1021\/ic010635e"},{"key":"e_1_2_8_43_1","unstructured":"This reaction and its products were not analyzed further."},{"key":"e_1_2_8_44_1","unstructured":"The amount of dissolved dioxygen could not be estimated by analysis of the fluorescence quenching due to our particular experimental condions. See Supporting Information for details."},{"key":"e_1_2_8_45_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b05389"},{"key":"e_1_2_8_46_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja506934k"},{"key":"e_1_2_8_47_1","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.2055"},{"key":"e_1_2_8_48_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201610828"},{"key":"e_1_2_8_48_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201610828"},{"key":"e_1_2_8_49_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja9101908"},{"key":"e_1_2_8_50_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201812724"},{"key":"e_1_2_8_50_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201812724"},{"key":"e_1_2_8_51_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9DT03487K"},{"key":"e_1_2_8_52_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja306089q"},{"key":"e_1_2_8_53_1","doi-asserted-by":"publisher","DOI":"10.1039\/C3SC51541A"},{"key":"e_1_2_8_54_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201102326"},{"key":"e_1_2_8_55_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja808166d"},{"key":"e_1_2_8_56_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja8022576"},{"key":"e_1_2_8_57_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201704977"}],"container-title":["Chemistry \u2013 A European Journal"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/chem.202201600","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/chem.202201600","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/chem.202201600","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,12]],"date-time":"2025-10-12T16:19:20Z","timestamp":1760285960000},"score":1,"resource":{"primary":{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/10.1002\/chem.202201600"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2022,8,3]]},"references-count":62,"journal-issue":{"issue":"53","published-print":{"date-parts":[[2022,9,22]]}},"alternative-id":["10.1002\/chem.202201600"],"URL":"https:\/\/doi.org\/10.1002\/chem.202201600","archive":["Portico"],"relation":{},"ISSN":["0947-6539","1521-3765"],"issn-type":[{"value":"0947-6539","type":"print"},{"value":"1521-3765","type":"electronic"}],"subject":[],"published":{"date-parts":[[2022,8,3]]},"assertion":[{"value":"2022-05-25","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2022-08-03","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e202201600"}}