{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,19]],"date-time":"2026-08-19T20:15:12Z","timestamp":1787170512657,"version":"build-2736575974"},"reference-count":47,"publisher":"Wiley","issue":"61","license":[{"start":{"date-parts":[[2022,9,1]],"date-time":"2022-09-01T00:00:00Z","timestamp":1661990400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by-nc-nd\/4.0\/"}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Chemistry A European J"],"published-print":{"date-parts":[[2022,11,2]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Metal chalcogenides \u2013 because of their excellent optical and electrical properties \u2013 are important semiconductor materials for optical devices, such as solar cells, sensors, and photocatalysts. The challenges associated with metal chalcogenides are the complexity of the conventional synthesis methods and the stringent synthesis conditions. In this study, the synthesis conditions were simplified in a solvent\u2010free synthesis method using cadmium precursor, thiourea and selenium to synthesize metal chalcogenides, such as CdS and CdSe, which have particularly suitable band gaps for the optical devices. CdS\n                    <jats:sub>x<\/jats:sub>\n                    Se\n                    <jats:sub>1\u2010x<\/jats:sub>\n                    solid solution was successfully synthesized under molten thiourea as the reactive reaction medium at relatively low temperatures, even at 180\u2009\u00b0C, with residual melamine derivatives in the solid phase. The luminescence properties of CdS\n                    <jats:sub>x<\/jats:sub>\n                    Se\n                    <jats:sub>1\u2010x<\/jats:sub>\n                    and the products in the gas and solid phases were investigated. Optimization of the synthesis conditions for solid solutions of CdS\n                    <jats:sub>x<\/jats:sub>\n                    Se\n                    <jats:sub>1\u2010x<\/jats:sub>\n                    and the role of organic compounds in the formation of metal chalcogenides are discussed.\n                  <\/jats:p>","DOI":"10.1002\/chem.202201951","type":"journal-article","created":{"date-parts":[[2022,8,5]],"date-time":"2022-08-05T22:49:10Z","timestamp":1659739750000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":3,"title":["Synthesis of Metal Chalcogenide Semiconductors by Thermal Decomposition of Organosulfur and Organoselenium Compounds"],"prefix":"10.1002","volume":"28","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-3544-9505","authenticated-orcid":false,"given":"Keisuke","family":"Obata","sequence":"first","affiliation":[{"name":"Department of Chemical System Engineering School of Engineering The University of Tokyo  7-3-1 Hongo, Bunkyo-ku Tokyo 113-8656 Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3310-1487","authenticated-orcid":false,"given":"Tomohiro","family":"Higashi","sequence":"additional","affiliation":[{"name":"Institute for Tenure Track Promotion University of Miyazaki  Nishi 1\u20131 Gakuen-Kibanadai Miyazaki 889-2192 Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Motoki","family":"Hasegawa","sequence":"additional","affiliation":[{"name":"Department of Chemical System Engineering School of Engineering The University of Tokyo  7-3-1 Hongo, Bunkyo-ku Tokyo 113-8656 Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Masao","family":"Katayama","sequence":"additional","affiliation":[{"name":"Department of Chemical System Engineering School of Engineering The University of Tokyo  7-3-1 Hongo, Bunkyo-ku Tokyo 113-8656 Japan"},{"name":"Environmental Science Center The University of Tokyo  7-3-1, Hongo, Bunkyo-ku Tokyo 113-0033 Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5374-9451","authenticated-orcid":false,"given":"Kazuhiro","family":"Takanabe","sequence":"additional","affiliation":[{"name":"Department of Chemical System Engineering School of Engineering The University of Tokyo  7-3-1 Hongo, Bunkyo-ku Tokyo 113-8656 Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2022,9]]},"reference":[{"key":"e_1_2_8_1_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.spmi.2015.10.044"},{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1021\/jz401198e"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1021\/la960426k"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1088\/1674-1056\/25\/12\/123101"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1021\/jp0266805"},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.1021\/jp9535506"},{"key":"e_1_2_8_7_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpcc.5b03603"},{"key":"e_1_2_8_8_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.nanoen.2016.12.014"},{"key":"e_1_2_8_9_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsphotonics.7b00724"},{"key":"e_1_2_8_10_1","doi-asserted-by":"publisher","DOI":"10.1021\/jp9013509"},{"key":"e_1_2_8_11_1","doi-asserted-by":"publisher","DOI":"10.1007\/s12274-015-0977-6"},{"key":"e_1_2_8_12_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpcc.5b11651"},{"key":"e_1_2_8_13_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr900137k"},{"key":"e_1_2_8_14_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.5b00063"},{"key":"e_1_2_8_15_1","doi-asserted-by":"publisher","DOI":"10.1021\/jp064664s"},{"key":"e_1_2_8_16_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jallcom.2015.06.231"},{"key":"e_1_2_8_17_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apsusc.2018.05.141"},{"key":"e_1_2_8_18_1","doi-asserted-by":"publisher","DOI":"10.1149\/1.2128120"},{"key":"e_1_2_8_19_1","doi-asserted-by":"publisher","DOI":"10.1021\/ar600028s"},{"key":"e_1_2_8_20_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja905922j"},{"key":"e_1_2_8_21_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201411329"},{"key":"e_1_2_8_21_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201411329"},{"key":"e_1_2_8_22_1","doi-asserted-by":"publisher","DOI":"10.1021\/cm5028964"},{"key":"e_1_2_8_23_1","doi-asserted-by":"publisher","DOI":"10.1002\/ppsc.201700183"},{"key":"e_1_2_8_24_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.matchemphys.2008.05.078"},{"key":"e_1_2_8_25_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201503353"},{"key":"e_1_2_8_25_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201503353"},{"key":"e_1_2_8_26_1","doi-asserted-by":"publisher","DOI":"10.1021\/jp051620v"},{"key":"e_1_2_8_27_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.62.13064"},{"key":"e_1_2_8_28_1","doi-asserted-by":"publisher","DOI":"10.1016\/0022-0248(91)90101-A"},{"key":"e_1_2_8_29_1","doi-asserted-by":"publisher","DOI":"10.1134\/S0036023611040218"},{"key":"e_1_2_8_30_1","doi-asserted-by":"publisher","DOI":"10.1023\/A:1017594228500"},{"key":"e_1_2_8_31_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9TB02377A"},{"key":"e_1_2_8_32_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemmater.0c02593"},{"key":"e_1_2_8_33_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.0c12185"},{"key":"e_1_2_8_34_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpcc.7b12087"},{"key":"e_1_2_8_35_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.mssp.2019.104743"},{"key":"e_1_2_8_36_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201501939"},{"key":"e_1_2_8_37_1","doi-asserted-by":"publisher","DOI":"10.1039\/c2jm00097k"},{"key":"e_1_2_8_38_1","doi-asserted-by":"publisher","DOI":"10.1021\/jp809119m"},{"key":"e_1_2_8_39_1","doi-asserted-by":"publisher","DOI":"10.1039\/C8CC06326E"},{"key":"e_1_2_8_40_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2014.01.064"},{"key":"e_1_2_8_41_1","doi-asserted-by":"publisher","DOI":"10.1002\/bio.2909"},{"key":"e_1_2_8_42_1","doi-asserted-by":"publisher","DOI":"10.1071\/CH18100"},{"key":"e_1_2_8_43_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.mssp.2016.10.022"},{"key":"e_1_2_8_44_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.est.1c03804"},{"key":"e_1_2_8_45_1","doi-asserted-by":"publisher","DOI":"10.1134\/S106378261912008X"}],"container-title":["Chemistry \u2013 A European Journal"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/chem.202201951","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/chem.202201951","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/chem.202201951","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,12]],"date-time":"2025-10-12T11:41:45Z","timestamp":1760269305000},"score":1,"resource":{"primary":{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/10.1002\/chem.202201951"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2022,9]]},"references-count":47,"journal-issue":{"issue":"61","published-print":{"date-parts":[[2022,11,2]]}},"alternative-id":["10.1002\/chem.202201951"],"URL":"https:\/\/doi.org\/10.1002\/chem.202201951","archive":["Portico"],"relation":{},"ISSN":["0947-6539","1521-3765"],"issn-type":[{"value":"0947-6539","type":"print"},{"value":"1521-3765","type":"electronic"}],"subject":[],"published":{"date-parts":[[2022,9]]},"assertion":[{"value":"2022-06-23","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2022-09-01","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e202201951"}}