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These properties mainly rely on maximizing the number of strong covalent bonds, with crosslinked XN\n                    <jats:sub>6<\/jats:sub>\n                    octahedra frameworks being particularly attractive. In this study, the phosphorus\u2013nitrogen system was studied up to 137\u2005GPa in laser\u2010heated diamond anvil cells, and three previously unobserved phases were synthesized and characterized by single\u2010crystal X\u2010ray diffraction, Raman spectroscopy measurements and density functional theory calculations. \u03b4\u2010P\n                    <jats:sub>3<\/jats:sub>\n                    N\n                    <jats:sub>5<\/jats:sub>\n                    and PN\n                    <jats:sub>2<\/jats:sub>\n                    were found to form at 72 and 134\u2005GPa, respectively, and both feature dense 3D networks of the so far elusive PN\n                    <jats:sub>6<\/jats:sub>\n                    units. The two compounds are ultra\u2010incompressible, having a bulk modulus of\n                    <jats:italic>K<\/jats:italic>\n                    <jats:sub>0<\/jats:sub>\n                    =322\u2005GPa for \u03b4\u2010P\n                    <jats:sub>3<\/jats:sub>\n                    N\n                    <jats:sub>5<\/jats:sub>\n                    and 339\u2005GPa for PN\n                    <jats:sub>2<\/jats:sub>\n                    . Upon decompression below 7\u2005GPa, \u03b4\u2010P\n                    <jats:sub>3<\/jats:sub>\n                    N\n                    <jats:sub>5<\/jats:sub>\n                    undergoes a transformation into a novel \u03b1\u2032\u2010P\n                    <jats:sub>3<\/jats:sub>\n                    N\n                    <jats:sub>5<\/jats:sub>\n                    solid, stable at ambient conditions, that has a unique structure type based on PN\n                    <jats:sub>4<\/jats:sub>\n                    tetrahedra. The formation of \u03b1\u2032\u2010P\n                    <jats:sub>3<\/jats:sub>\n                    N\n                    <jats:sub>5<\/jats:sub>\n                    underlines that a phase space otherwise inaccessible can be explored through materials formed under high pressure.\n                  <\/jats:p>","DOI":"10.1002\/chem.202201998","type":"journal-article","created":{"date-parts":[[2022,8,23]],"date-time":"2022-08-23T05:46:26Z","timestamp":1661233586000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":19,"title":["Revealing Phosphorus Nitrides up to the Megabar Regime: Synthesis of \u03b1\u2032\u2010P\n                    <sub>3<\/sub>\n                    N\n                    <sub>5,<\/sub>\n                    \u03b4\u2010P\n                    <sub>3<\/sub>\n                    N\n                    <sub>5<\/sub>\n                    and PN\n                    <sub>2<\/sub>"],"prefix":"10.1002","volume":"28","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-6889-9820","authenticated-orcid":false,"given":"Dominique","family":"Laniel","sequence":"first","affiliation":[{"name":"Material Physics and Technology at Extreme Conditions Laboratory of Crystallography University of Bayreuth  95440 Bayreuth Germany"},{"name":"Centre for Science at Extreme Conditions and School of Physics and Astronomy University of Edinburgh  EH9 3FD Edinburgh UK"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Florian","family":"Trybel","sequence":"additional","affiliation":[{"name":"Department of Physics Chemistry and Biology (IFM) Link\u00f6ping University  58183 Link\u00f6ping Sweden"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Adrien","family":"N\u00e9ri","sequence":"additional","affiliation":[{"name":"Bayerisches Geoinstitut University of Bayreuth  95440 Bayreuth Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yuqing","family":"Yin","sequence":"additional","affiliation":[{"name":"Material Physics and Technology at Extreme Conditions Laboratory of Crystallography University of Bayreuth  95440 Bayreuth Germany"},{"name":"State Key Laboratory of Crystal Materials Shandong University  Jinan 250100 P. 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