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The coordination polymerization of diphenylphosphinostyrene (<jats:italic>p<\/jats:italic>\u2010StPPh<jats:sub>2<\/jats:sub> and <jats:italic>o<\/jats:italic>\u2010StPPh<jats:sub>2<\/jats:sub>) and its copolymerization with styrene (St) by (C<jats:sub>5<\/jats:sub>Me<jats:sub>4<\/jats:sub>SiMe<jats:sub>3<\/jats:sub>)Sc(CH<jats:sub>2<\/jats:sub>C<jats:sub>6<\/jats:sub>H<jats:sub>4<\/jats:sub>NMe<jats:sub>2<\/jats:sub>\u2010<jats:italic>o<\/jats:italic>)<jats:sub>2<\/jats:sub> have been achieved for the first time to afford a new series of phosphine functionalized syndiotactic polystyrene. By the design of the polymer structure, the copolymer of <jats:italic>o<\/jats:italic>\u2010StPPh<jats:sub>2<\/jats:sub> and St (poly(<jats:italic>o<\/jats:italic>\u2010StPPh<jats:sub>2<\/jats:sub>\u2010<jats:italic>alt<\/jats:italic>\u2010St)\u2010<jats:italic>b<\/jats:italic>\u2010<jats:italic>s<\/jats:italic>PS) containing <jats:italic>o<\/jats:italic>\u2010StPPh<jats:sub>2<\/jats:sub> and St atactic alternating copolymer block and syndiotactic polystyrene block (<jats:italic>s<\/jats:italic>PS) showed excellent thermal stability and chemical resistance. The simple combination of the triphenylphosphine and syndiotactic polystyrene realized the stable immobilization of metal nanoparticles to afford highly robust metal@poly(<jats:italic>o<\/jats:italic>\u2010StPPh<jats:sub>2<\/jats:sub>\u2010<jats:italic>alt<\/jats:italic>\u2010St)\u2010<jats:italic>b<\/jats:italic>\u2010<jats:italic>s<\/jats:italic>PS nanocatalysts at high temperature and various atmospheres. The Cu@poly(<jats:italic>o<\/jats:italic>\u2010StPPh<jats:sub>2<\/jats:sub>\u2010<jats:italic>alt<\/jats:italic>\u2010St)\u2010<jats:italic>b<\/jats:italic>\u2010<jats:italic>s<\/jats:italic>PS catalyst can serve as a highly efficient heterogeneous catalyst for the synthesis of quinoline derivatives by acceptorless dehydrogenative coupling of <jats:italic>o<\/jats:italic>\u2010aminobenzylalcohol with ketones.<\/jats:p>","DOI":"10.1002\/chem.202202113","type":"journal-article","created":{"date-parts":[[2022,7,12]],"date-time":"2022-07-12T06:30:42Z","timestamp":1657607442000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Phosphine\u2010Functionalized Syndiotactic Polystyrenes: Synthesis and Application to Immobilization of Transition Metal Nanoparticle Catalysts"],"prefix":"10.1002","volume":"28","author":[{"given":"Lei","family":"Jiang","sequence":"first","affiliation":[{"name":"State Key Laboratory of Fine Chemicals Department of Polymer Science and Engineering School of Chemical Engineering Dalian University of Technology  Dalian 116012 China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Yinran","family":"Wang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Fine Chemicals Department of Polymer Science and Engineering School of Chemical Engineering Dalian University of Technology  Dalian 116012 China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Hanyang","family":"Sun","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Fine Chemicals Department of Polymer Science and Engineering School of Chemical Engineering Dalian University of Technology  Dalian 116012 China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Tingting","family":"Fu","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Fine Chemicals Department of Polymer Science and Engineering School of Chemical Engineering Dalian University of Technology  Dalian 116012 China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2841-5120","authenticated-orcid":false,"given":"Zhaomin","family":"Hou","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Fine Chemicals Department of Polymer Science and Engineering School of Chemical Engineering Dalian University of Technology  Dalian 116012 China"},{"name":"Organometallic Chemistry Laboratory RIKEN Cluster for Pioneering Research Advanced Catalysis Research Group RIKEN Center for Sustainable Resource Science  2-1 Hirosawa Wako Saitama 351-0198 Japan"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5114-6534","authenticated-orcid":false,"given":"Fang","family":"Guo","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Fine Chemicals Department of Polymer Science and Engineering School of Chemical Engineering Dalian University of Technology  Dalian 116012 China"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2022,9]]},"reference":[{"doi-asserted-by":"publisher","key":"e_1_2_7_1_1","DOI":"10.1126\/science.1238149"},{"unstructured":"\u00a0","key":"e_1_2_7_2_1"},{"doi-asserted-by":"publisher","key":"e_1_2_7_3_2","DOI":"10.1126\/science.1229753"},{"doi-asserted-by":"publisher","key":"e_1_2_7_4_2","DOI":"10.1038\/nchem.2346"},{"unstructured":"\u00a0","key":"e_1_2_7_5_1"},{"doi-asserted-by":"crossref","unstructured":"J.\u2005M.\u2005G. 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