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Although there are several extra\u2010large pore zeolites reported, stable ones are rare. Thus, their stabilization is a feasible strategy for industrial applications. Here, an extra\u2010large\u2010pore zeolite EWT with boron substitution is presented, and the resulting zeolite B\u2010RZM\u20103 increased the thermal stability from 600\u2009\u00b0C in its silica form to 850\u2009\u00b0C. The crystal structure, determined by combining continuous rotation electron diffraction (cRED) and powder X\u2010ray diffraction (PXRD), shows that B atoms preferentially substitute the interrupted (HO)T(OT)<jats:sub>3<\/jats:sub> (Q<jats:sup>3<\/jats:sup>) sites and are partially converted into 3\u2010coordination to relax framework deformation upon heating. After Al\u2010reinsertion post\u2010treatment, Al\u2010B\u2010RZM\u20103 shows higher ethylbenzene selectivity and ethylene conversion rate per mol acid site than commercial ZSM\u20105 and Beta zeolite in benzene alkylation reaction. Synthesizing extra\u2010large\u2010pore zeolite in borosilicate form is a potential approach to stabilize interrupted zeolites for commercial applications.<\/jats:p>","DOI":"10.1002\/chem.202202170","type":"journal-article","created":{"date-parts":[[2022,9,6]],"date-time":"2022-09-06T10:18:58Z","timestamp":1662459538000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":5,"title":["Stabilization of Extra\u2010Large\u2010Pore Zeolite by Boron Substitution for the Production of Commercially Applicable Catalysts"],"prefix":"10.1002","volume":"28","author":[{"given":"Pohua","family":"Chen","sequence":"first","affiliation":[{"name":"College of Chemistry and Molecular Engineering Beijing National Laboratory for Molecular Sciences Peking University  Beijing 100871 P. R. 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