{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,10,13]],"date-time":"2025-10-13T00:35:01Z","timestamp":1760315701037,"version":"build-2065373602"},"reference-count":60,"publisher":"Wiley","issue":"72","license":[{"start":{"date-parts":[[2022,11,10]],"date-time":"2022-11-10T00:00:00Z","timestamp":1668038400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100004052","name":"King Abdullah University of Science and Technology","doi-asserted-by":"publisher","award":["Startup funds"],"award-info":[{"award-number":["Startup funds"]}],"id":[{"id":"10.13039\/501100004052","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100003725","name":"National Research Foundation of Korea","doi-asserted-by":"publisher","award":["NRF-2017M3A7B4042140","NRF-2017M3A7B4042273"],"award-info":[{"award-number":["NRF-2017M3A7B4042140","NRF-2017M3A7B4042273"]}],"id":[{"id":"10.13039\/501100003725","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Chemistry A European J"],"published-print":{"date-parts":[[2022,12,27]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Through accumulation, mercury contamination in aquatic systems still poses serious health risks despite the strict regulations on drinking water and industrial discharge. One effective strategy against this is adsorptive removal, in which a suitably functionalized porous material is added to water treatment protocols. Thiol (SH) group\u2010grafted structures perform commendably; however, insufficient attention is paid to the cost, scalability, and reusability or how the arrangement of sulfur atoms could affect the Hg<jats:sup>II<\/jats:sup> binding strength. We used an inexpensive and scalable porous covalent organic polymer (COP\u2010130) to systematically introduce thiol functional groups with precise chain lengths and sulfur content. Thiol\u2010functionalized COP\u2010130 demonstrates enhanced wettability and excellent Hg<jats:sup>II<\/jats:sup> uptake of up to 936\u2005mg\u2009g<jats:sup>\u22121<\/jats:sup>, with fast kinetics and exceptionally high selectivity. These Hg adsorbents are easily regenerated with HCl and can be used at least six times without loss of capacity even after treatment with strong acid, a rare performance in the domain of Hg\u2010removal research.<\/jats:p>","DOI":"10.1002\/chem.202202340","type":"journal-article","created":{"date-parts":[[2022,9,28]],"date-time":"2022-09-28T10:04:02Z","timestamp":1664359442000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Systematic Modulation of Thiol Functionalities in Inexpensive Porous Polymers for Effective Mercury Removal"],"prefix":"10.1002","volume":"28","author":[{"given":"Sirinapa","family":"Wongwilawan","sequence":"first","affiliation":[{"name":"Department of Chemical and Biomolecular Engineering Korea Advanced Institute of Science and Technology (KAIST)  291 Daehak-ro, Yuseong-gu Daejeon 34141 (Republic of Korea"},{"name":"PTT Global Chemical Public Company Ltd.  Bangkok 10900 Thailand"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Doyun","family":"Kim","sequence":"additional","affiliation":[{"name":"Department of Chemical and Biomolecular Engineering Korea Advanced Institute of Science and Technology (KAIST)  291 Daehak-ro, Yuseong-gu Daejeon 34141 (Republic of Korea"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Thien S.","family":"Nguyen","sequence":"additional","affiliation":[{"name":"Department of Chemical and Biomolecular Engineering Korea Advanced Institute of Science and Technology (KAIST)  291 Daehak-ro, Yuseong-gu Daejeon 34141 (Republic of Korea"},{"name":"Oxide &amp; Organic Nanomaterials for Energy &amp; Environment Laboratory Physical Science &amp; Engineering (PSE) King Abdullah University of Science and Technology (KAUST)  Thuwal 23955 Saudi Arabia"},{"name":"Advanced Membranes &amp; Porous Materials Center Physical Science &amp; Engineering (PSE) King Abdullah University of Science and Technology (KAUST)  Thuwal 23955 Saudi Arabia"},{"name":"KAUST Catalysis Center Physical Science &amp; Engineering (PSE) King Abdullah University of Science and Technology (KAUST)  Thuwal 23955 Saudi Arabia"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Wonki","family":"Lim","sequence":"additional","affiliation":[{"name":"Department of Chemical and Biomolecular Engineering Korea Advanced Institute of Science and Technology (KAIST)  291 Daehak-ro, Yuseong-gu Daejeon 34141 (Republic of Korea"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Sheng","family":"Li","sequence":"additional","affiliation":[{"name":"Department of Chemical and Biomolecular Engineering Korea Advanced Institute of Science and Technology (KAIST)  291 Daehak-ro, Yuseong-gu Daejeon 34141 (Republic of Korea"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0580-3331","authenticated-orcid":false,"given":"Cafer T.","family":"Yavuz","sequence":"additional","affiliation":[{"name":"Department of Chemical and Biomolecular Engineering Korea Advanced Institute of Science and Technology (KAIST)  291 Daehak-ro, Yuseong-gu Daejeon 34141 (Republic of Korea"},{"name":"Oxide &amp; Organic Nanomaterials for Energy &amp; Environment Laboratory Physical Science &amp; Engineering (PSE) King Abdullah University of Science and Technology (KAUST)  Thuwal 23955 Saudi Arabia"},{"name":"Advanced Membranes &amp; Porous Materials Center Physical Science &amp; Engineering (PSE) King Abdullah University of Science and Technology (KAUST)  Thuwal 23955 Saudi Arabia"},{"name":"KAUST Catalysis Center Physical Science &amp; Engineering (PSE) King Abdullah University of Science and Technology (KAUST)  Thuwal 23955 Saudi Arabia"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2022,11,10]]},"reference":[{"key":"e_1_2_7_1_1","doi-asserted-by":"publisher","DOI":"10.1007\/s10661-019-7743-2"},{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.envint.2019.105281"},{"key":"e_1_2_7_3_1","unstructured":"World Health Organization 2017 https:\/\/www.who.int\/news-room\/fact-sheets\/detail\/mercury-and-health."},{"key":"e_1_2_7_4_1","unstructured":"United States Environmental Protection Agency National Primary Drinking Water Regulations 2022 https:\/\/www.epa.gov\/ground-water-and-drinking-water\/national-primary-drinking-water-regulations."},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jece.2019.103350"},{"key":"e_1_2_7_6_1","doi-asserted-by":"publisher","DOI":"10.1007\/s11356-015-5880-x"},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja00905a001"},{"key":"e_1_2_7_8_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.6b12885"},{"key":"e_1_2_7_9_1","doi-asserted-by":"publisher","DOI":"10.1039\/C7TA05588A"},{"key":"e_1_2_7_10_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2013.05.063"},{"key":"e_1_2_7_11_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2018.08.041"},{"key":"e_1_2_7_12_1","doi-asserted-by":"publisher","DOI":"10.1038\/ncomms6537"},{"key":"e_1_2_7_13_1","doi-asserted-by":"publisher","DOI":"10.1039\/C7FD00012J"},{"key":"e_1_2_7_14_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jhazmat.2011.08.069"},{"key":"e_1_2_7_15_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apsusc.2017.03.303"},{"key":"e_1_2_7_16_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.psep.2015.12.006"},{"key":"e_1_2_7_17_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.iecr.7b03093"},{"key":"e_1_2_7_18_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jtice.2016.08.029"},{"key":"e_1_2_7_19_1","doi-asserted-by":"publisher","DOI":"10.1080\/01496399908951084"},{"key":"e_1_2_7_20_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsomega.9b03607"},{"key":"e_1_2_7_21_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jhazmat.2018.05.055"},{"key":"e_1_2_7_22_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201700665"},{"key":"e_1_2_7_23_1","doi-asserted-by":"publisher","DOI":"10.1039\/C7NJ00663B"},{"key":"e_1_2_7_24_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsomega.9b00572"},{"key":"e_1_2_7_25_1","doi-asserted-by":"publisher","DOI":"10.1039\/C8TA04020F"},{"key":"e_1_2_7_26_1","doi-asserted-by":"publisher","DOI":"10.1021\/acssuschemeng.8b00768"},{"key":"e_1_2_7_27_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.8b03505"},{"key":"e_1_2_7_28_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.9b17508"},{"key":"e_1_2_7_29_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5TA01484K"},{"key":"e_1_2_7_30_1","doi-asserted-by":"publisher","DOI":"10.1039\/C6TA00343E"},{"key":"e_1_2_7_31_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9CC06255F"},{"key":"e_1_2_7_32_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jhazmat.2019.01.025"},{"key":"e_1_2_7_33_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apsusc.2009.12.139"},{"key":"e_1_2_7_34_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9NJ01111K"},{"key":"e_1_2_7_35_1","volume":"398","author":"Li Y. F.","year":"2020","journal-title":"Chem. Eng. J."},{"key":"e_1_2_7_36_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jhazmat.2017.06.051"},{"key":"e_1_2_7_37_1","doi-asserted-by":"publisher","DOI":"10.1039\/C6TA03257E"},{"key":"e_1_2_7_38_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chempr.2021.01.002"},{"key":"e_1_2_7_39_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202109215"},{"key":"e_1_2_7_40_1","doi-asserted-by":"publisher","DOI":"10.1039\/C6TA06089G"},{"key":"e_1_2_7_41_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41560-019-0427-x"},{"key":"e_1_2_7_42_1","doi-asserted-by":"publisher","DOI":"10.1002\/cssc.202002190"},{"key":"e_1_2_7_43_1","doi-asserted-by":"publisher","DOI":"10.1002\/aesr.202100064"},{"key":"e_1_2_7_44_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cattod.2020.03.050"},{"key":"e_1_2_7_45_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9NR02708D"},{"key":"e_1_2_7_46_1","doi-asserted-by":"publisher","DOI":"10.1002\/smsc.202000078"},{"key":"e_1_2_7_47_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.eng.2018.06.001"},{"key":"e_1_2_7_48_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemmater.9b01447"},{"key":"e_1_2_7_49_1","doi-asserted-by":"publisher","DOI":"10.1038\/ncomms13377"},{"key":"e_1_2_7_50_1","doi-asserted-by":"publisher","DOI":"10.1021\/ar300265y"},{"key":"e_1_2_7_51_1","doi-asserted-by":"publisher","DOI":"10.1007\/s42452-020-2736-x"},{"key":"e_1_2_7_52_1","doi-asserted-by":"publisher","DOI":"10.3390\/w12082105"},{"key":"e_1_2_7_53_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0032-9592(98)00112-5"},{"key":"e_1_2_7_54_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.200601230"},{"key":"e_1_2_7_55_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.5b06951"},{"key":"e_1_2_7_56_1","doi-asserted-by":"publisher","DOI":"10.1021\/jp910121m"},{"key":"e_1_2_7_57_1","doi-asserted-by":"publisher","DOI":"10.1021\/acssuschemeng.8b02965"},{"key":"e_1_2_7_58_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2017.02.073"},{"key":"e_1_2_7_59_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1EN00448D"},{"key":"e_1_2_7_60_1","doi-asserted-by":"publisher","DOI":"10.1039\/C6CP01382A"}],"container-title":["Chemistry \u2013 A European Journal"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/chem.202202340","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/chem.202202340","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/chem.202202340","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,12]],"date-time":"2025-10-12T12:41:46Z","timestamp":1760272906000},"score":1,"resource":{"primary":{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/10.1002\/chem.202202340"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2022,11,10]]},"references-count":60,"journal-issue":{"issue":"72","published-print":{"date-parts":[[2022,12,27]]}},"alternative-id":["10.1002\/chem.202202340"],"URL":"https:\/\/doi.org\/10.1002\/chem.202202340","archive":["Portico"],"relation":{},"ISSN":["0947-6539","1521-3765"],"issn-type":[{"type":"print","value":"0947-6539"},{"type":"electronic","value":"1521-3765"}],"subject":[],"published":{"date-parts":[[2022,11,10]]},"assertion":[{"value":"2022-07-27","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2022-11-10","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e202202340"}}