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We have designed and synthesized 1,n\u2032\u2010disubstituted ferrocene\u2010azobenzene\u2010long alkyl chains, Fc(CONH\u2010Azo\u2010TDP)<jats:sub>2<\/jats:sub>, to afford SPs with a high probability. The design exploits the \u2018\u2018molecular ball\u2010bearing\u2019\u2019 property of the ferrocene core, which allows two azobenzene arms to rotate in the planes of cyclopentadienyl rings, generating the most suitable molecular conformation required for SP formation. This ferrocene monomer formed a supergel consisting of SPs supported by strong intermolecular (H\u2010bonding and \u03c0\u2010\u03c0 stacking) interactions and higher enthalpy gain than the reference molecules, where the central ferrocene core was replaced by flexible aliphatic as well as rigid benzene linkers. The molecular conformation involved in SPs, the strength of noncovalent interactions, and the process of supramolecular polymerization were investigated through NMR, UV\u2010Vis, XRD and TEM studies. The results demonstrate that ferrocene may act as a good modulator for constructing efficient SPs.<\/jats:p>","DOI":"10.1002\/chem.202202711","type":"journal-article","created":{"date-parts":[[2022,9,30]],"date-time":"2022-09-30T09:33:56Z","timestamp":1664530436000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":3,"title":["Introduction of Ferrocene as a Facilitator for the Construction of Supramolecular Polymers"],"prefix":"10.1002","volume":"29","author":[{"given":"Mohammad","family":"Umer Lone","sequence":"first","affiliation":[{"name":"Department of Chemical Sciences Indian Institute of Science Education and Research (IISER) Mohali  Knowledge City, Sector 81, Manauli PO 140306 S.\u2005A.\u2005S. 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