{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,18]],"date-time":"2026-09-18T22:13:19Z","timestamp":1789769599526,"version":"4.0.1"},"reference-count":113,"publisher":"Wiley","issue":"2","license":[{"start":{"date-parts":[[2022,11,7]],"date-time":"2022-11-07T00:00:00Z","timestamp":1667779200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by-nc\/4.0\/"}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Chemistry A European J"],"published-print":{"date-parts":[[2023,1,9]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Manganese\u2010catalyzed hydrogenation reactions have aroused widespread interest in recent years. Among the catalytic systems described, especially PNP\u2010 and NNP\u2013Mn pincer catalysts have been reported for the hydrogenation of aldehydes, ketones, nitriles, aldimines and esters. Furthermore, NNP\u2212Mn pincer compounds are efficient catalysts for the hydrogenolysis of less reactive amides, ureas, carbonates, and carbamates. Herein, the synthesis and application of specific imidazolylaminophosphine ligands and the corresponding Mn pincer complexes are described. These new catalysts have been characterized and studied by a combination of experimental and theoretical investigations, and their catalytic activities have been tested in several hydrogenation reactions with good to excellent performance. Especially, the reduction of N\u2010heterocycles can be performed under very mild conditions.<\/jats:p>","DOI":"10.1002\/chem.202202774","type":"journal-article","created":{"date-parts":[[2022,10,4]],"date-time":"2022-10-04T06:36:56Z","timestamp":1664865416000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":38,"title":["Efficient Hydrogenation of N\u2010Heterocycles Catalyzed by NNP\u2013Manganese(I) Pincer Complexes at Ambient Temperature"],"prefix":"10.1002","volume":"29","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-8107-7162","authenticated-orcid":false,"given":"Veronica","family":"Papa","sequence":"first","affiliation":[{"name":"Leibniz-Institut f\u00fcr Katalyse e.\u2005V.  Albert-Einstein-Stra\u00dfe 29A 18059 Rostock Germany"},{"name":"Istituto italiano di tecnologia  Via Morego 30 16163 Genova Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2395-8572","authenticated-orcid":false,"given":"Johannes","family":"Fessler","sequence":"additional","affiliation":[{"name":"Leibniz-Institut f\u00fcr Katalyse e.\u2005V.  Albert-Einstein-Stra\u00dfe 29A 18059 Rostock Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8760-8638","authenticated-orcid":false,"given":"Francesco","family":"Zaccaria","sequence":"additional","affiliation":[{"name":"Dipartimento di Chimica, Biologia e Biotecnologie and CIRCC Universit\u00e0 degli Studi di Perugia  06123 Perugia Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5229-6400","authenticated-orcid":false,"given":"Julien","family":"Hervochon","sequence":"additional","affiliation":[{"name":"Leibniz-Institut f\u00fcr Katalyse e.\u2005V.  Albert-Einstein-Stra\u00dfe 29A 18059 Rostock Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3438-181X","authenticated-orcid":false,"given":"Phong","family":"Dam","sequence":"additional","affiliation":[{"name":"Leibniz-Institut f\u00fcr Katalyse e.\u2005V.  Albert-Einstein-Stra\u00dfe 29A 18059 Rostock Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9549-2455","authenticated-orcid":false,"given":"Christoph","family":"Kubis","sequence":"additional","affiliation":[{"name":"Leibniz-Institut f\u00fcr Katalyse e.\u2005V.  Albert-Einstein-Stra\u00dfe 29A 18059 Rostock Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Anke","family":"Spannenberg","sequence":"additional","affiliation":[{"name":"Leibniz-Institut f\u00fcr Katalyse e.\u2005V.  Albert-Einstein-Stra\u00dfe 29A 18059 Rostock Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9460-7908","authenticated-orcid":false,"given":"Zhihong","family":"Wei","sequence":"additional","affiliation":[{"name":"Leibniz-Institut f\u00fcr Katalyse e.\u2005V.  Albert-Einstein-Stra\u00dfe 29A 18059 Rostock Germany"},{"name":"Institute of Molecular Science Key Laboratory of Materials for Energy Conversion and Storage of Shanxi Province Shanxi University  030006 Taiyuan P.\u2005R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2947-5937","authenticated-orcid":false,"given":"Haijun","family":"Jiao","sequence":"additional","affiliation":[{"name":"Leibniz-Institut f\u00fcr Katalyse e.\u2005V.  Albert-Einstein-Stra\u00dfe 29A 18059 Rostock Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9835-2818","authenticated-orcid":false,"given":"Cristiano","family":"Zuccaccia","sequence":"additional","affiliation":[{"name":"Dipartimento di Chimica, Biologia e Biotecnologie and CIRCC Universit\u00e0 degli Studi di Perugia  06123 Perugia Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7866-8332","authenticated-orcid":false,"given":"Alceo","family":"Macchioni","sequence":"additional","affiliation":[{"name":"Dipartimento di Chimica, Biologia e Biotecnologie and CIRCC Universit\u00e0 degli Studi di Perugia  06123 Perugia Italy"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7044-8888","authenticated-orcid":false,"given":"Kathrin","family":"Junge","sequence":"additional","affiliation":[{"name":"Leibniz-Institut f\u00fcr Katalyse e.\u2005V.  Albert-Einstein-Stra\u00dfe 29A 18059 Rostock Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5709-0965","authenticated-orcid":false,"given":"Matthias","family":"Beller","sequence":"additional","affiliation":[{"name":"Leibniz-Institut f\u00fcr Katalyse e.\u2005V.  Albert-Einstein-Stra\u00dfe 29A 18059 Rostock Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2022,11,7]]},"reference":[{"key":"e_1_2_8_1_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr5002782"},{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1002\/adsc.201400777"},{"key":"e_1_2_8_3_1","unstructured":"\u00a0"},{"key":"e_1_2_8_4_2","doi-asserted-by":"publisher","DOI":"10.1016\/B978-044453138-4\/50010-6"},{"key":"e_1_2_8_5_2","doi-asserted-by":"publisher","DOI":"10.1039\/c1dt10339c"},{"key":"e_1_2_8_6_2","doi-asserted-by":"publisher","DOI":"10.1007\/978-3-642-31081-2"},{"key":"e_1_2_8_7_1","doi-asserted-by":"publisher","DOI":"10.1021\/jo010721w"},{"key":"e_1_2_8_8_1","unstructured":"\u00a0"},{"key":"e_1_2_8_9_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200903193"},{"key":"e_1_2_8_9_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200903193"},{"key":"e_1_2_8_10_2","doi-asserted-by":"publisher","DOI":"10.1021\/cs3005083"},{"key":"e_1_2_8_11_2","doi-asserted-by":"publisher","DOI":"10.1039\/c3ra40618k"},{"key":"e_1_2_8_12_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201503873"},{"key":"e_1_2_8_12_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201503873"},{"key":"e_1_2_8_13_1","doi-asserted-by":"publisher","DOI":"10.1021\/ar2000265"},{"key":"e_1_2_8_14_1","doi-asserted-by":"publisher","DOI":"10.1002\/ejic.201100880"},{"key":"e_1_2_8_15_1","first-page":"1959","volume":"47","author":"Peris E.","year":"2018","journal-title":"Chem. Rev."},{"key":"e_1_2_8_16_1","doi-asserted-by":"publisher","DOI":"10.1039\/C7SC00138J"},{"key":"e_1_2_8_17_1","unstructured":"For selected examples see:"},{"key":"e_1_2_8_18_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja052862b"},{"key":"e_1_2_8_19_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200503771"},{"key":"e_1_2_8_19_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200503771"},{"key":"e_1_2_8_20_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.1145295"},{"key":"e_1_2_8_21_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja1080019"},{"key":"e_1_2_8_22_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201108956"},{"key":"e_1_2_8_22_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201108956"},{"key":"e_1_2_8_23_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja512389y"},{"key":"e_1_2_8_24_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b08341"},{"key":"e_1_2_8_25_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201806289"},{"key":"e_1_2_8_25_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201806289"},{"key":"e_1_2_8_26_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201805630"},{"key":"e_1_2_8_26_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201805630"},{"key":"e_1_2_8_27_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b05591"},{"key":"e_1_2_8_28_1","unstructured":"\u00a0"},{"key":"e_1_2_8_29_2","doi-asserted-by":"publisher","DOI":"10.1002\/1521-3773(20010216)40:4<680::AID-ANIE6800>3.0.CO;2-0"},{"key":"e_1_2_8_29_3","doi-asserted-by":"publisher","DOI":"10.1002\/1521-3757(20010216)113:4<702::AID-ANGE7020>3.0.CO;2-W"},{"key":"e_1_2_8_30_2","doi-asserted-by":"publisher","DOI":"10.1002\/ejic.200600212"},{"key":"e_1_2_8_31_2","doi-asserted-by":"publisher","DOI":"10.1021\/om100804k"},{"key":"e_1_2_8_32_1","unstructured":"\u00a0"},{"key":"e_1_2_8_33_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr500425u"},{"key":"e_1_2_8_34_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.5b00385"},{"key":"e_1_2_8_35_2","doi-asserted-by":"publisher","DOI":"10.1039\/C7CS00334J"},{"key":"e_1_2_8_36_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201709010"},{"key":"e_1_2_8_36_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201709010"},{"key":"e_1_2_8_37_2","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.8b02869"},{"key":"e_1_2_8_38_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.8b00149"},{"key":"e_1_2_8_39_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.8b00262"},{"key":"e_1_2_8_40_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.8b00404"},{"key":"e_1_2_8_41_1","unstructured":"\u00a0"},{"key":"e_1_2_8_42_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.6b03709"},{"key":"e_1_2_8_43_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201606218"},{"key":"e_1_2_8_43_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201606218"},{"key":"e_1_2_8_44_2","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.8b00153"},{"key":"e_1_2_8_45_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b05024"},{"key":"e_1_2_8_46_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41557-022-01036-6"},{"key":"e_1_2_8_47_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.catcom.2016.12.017"},{"key":"e_1_2_8_48_1","unstructured":"\u00a0"},{"key":"e_1_2_8_49_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b08990"},{"key":"e_1_2_8_50_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacsau.0c00091"},{"key":"e_1_2_8_51_1","unstructured":"\u00a0"},{"key":"e_1_2_8_52_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.0c01273"},{"key":"e_1_2_8_53_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202202814"},{"key":"e_1_2_8_54_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9CY01502G"},{"key":"e_1_2_8_55_1","unstructured":"\u00a0"},{"key":"e_1_2_8_56_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201607233"},{"key":"e_1_2_8_56_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201607233"},{"key":"e_1_2_8_57_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201604991"},{"key":"e_1_2_8_58_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201805630"},{"key":"e_1_2_8_58_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201805630"},{"key":"e_1_2_8_59_1","unstructured":"\u00a0"},{"key":"e_1_2_8_60_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.orglett.0c01783"},{"key":"e_1_2_8_61_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-020-20168-2"},{"key":"e_1_2_8_62_2","doi-asserted-by":"publisher","DOI":"10.1002\/zaac.202100078"},{"key":"e_1_2_8_63_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.2c00548"},{"key":"e_1_2_8_64_1","unstructured":"\u00a0"},{"key":"e_1_2_8_65_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b09038"},{"key":"e_1_2_8_66_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202013540"},{"key":"e_1_2_8_66_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.202013540"},{"key":"e_1_2_8_67_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41929-019-0404-6"},{"key":"e_1_2_8_68_1","unstructured":"\u00a0"},{"key":"e_1_2_8_69_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201200408"},{"key":"e_1_2_8_70_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201303989"},{"key":"e_1_2_8_71_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201504709"},{"key":"e_1_2_8_72_1","unstructured":"Mn-1\u2009bwas previously reported (Ref.\u2005[9] CCDC 1521775). Deposition Number(s)2189956 (forMn-1\u2009a) 2189957 (forMn-1\u2009c) 2189958 (forMn-2\u2009b) 2204982 (forMn-2\u2009a) 2204983 (forMn-2\u2009c) 2204984 (forMn-2\u2009a-decomp)contain(s) the supplementary crystallographic data for this paper. These data are provided free of charge by the joint Cambridge Crystallographic Data Centre and Fachinformationszentrum KarlsruheAccess Structures service."},{"key":"e_1_2_8_73_1","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201808676"},{"key":"e_1_2_8_73_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201808676"},{"key":"e_1_2_8_74_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b11070"},{"key":"e_1_2_8_75_1","unstructured":"\u00a0"},{"key":"e_1_2_8_76_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0960-894X(03)00102-1"},{"key":"e_1_2_8_77_2","doi-asserted-by":"publisher","DOI":"10.1039\/C6OB00496B"},{"key":"e_1_2_8_78_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jmedchem.8b00959"},{"key":"e_1_2_8_79_1","unstructured":"\u00a0"},{"key":"e_1_2_8_80_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200704654"},{"key":"e_1_2_8_80_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200704654"},{"key":"e_1_2_8_81_2","doi-asserted-by":"publisher","DOI":"10.1007\/978-3-642-20731-0"},{"key":"e_1_2_8_82_2","doi-asserted-by":"publisher","DOI":"10.1002\/ejic.201100752"},{"key":"e_1_2_8_83_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201503873"},{"key":"e_1_2_8_83_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201503873"},{"key":"e_1_2_8_84_2","doi-asserted-by":"publisher","DOI":"10.1098\/rsta.2014.0189"},{"key":"e_1_2_8_85_1","doi-asserted-by":"publisher","DOI":"10.1021\/ic50078a030"},{"key":"e_1_2_8_86_1","unstructured":"\u00a0"},{"key":"e_1_2_8_87_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201603148"},{"key":"e_1_2_8_88_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.6b03709"},{"key":"e_1_2_8_89_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201604991"},{"key":"e_1_2_8_90_1","unstructured":"\u00a0"},{"key":"e_1_2_8_91_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201705471"},{"key":"e_1_2_8_91_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201705471"},{"key":"e_1_2_8_92_2","doi-asserted-by":"publisher","DOI":"10.1002\/ejic.201800674"},{"key":"e_1_2_8_93_2","doi-asserted-by":"publisher","DOI":"10.1039\/C8CY00746B"},{"key":"e_1_2_8_94_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0CY00992J"},{"key":"e_1_2_8_95_1","doi-asserted-by":"publisher","DOI":"10.1063\/1.2370993"},{"key":"e_1_2_8_96_1","doi-asserted-by":"publisher","DOI":"10.1063\/1.447079"},{"key":"e_1_2_8_97_1","doi-asserted-by":"publisher","DOI":"10.1021\/jp810292n"}],"container-title":["Chemistry \u2013 A European Journal"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/chem.202202774","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/chem.202202774","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/chem.202202774","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,12]],"date-time":"2025-10-12T16:53:40Z","timestamp":1760288020000},"score":1,"resource":{"primary":{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/10.1002\/chem.202202774"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2022,11,7]]},"references-count":113,"journal-issue":{"issue":"2","published-print":{"date-parts":[[2023,1,9]]}},"alternative-id":["10.1002\/chem.202202774"],"URL":"https:\/\/doi.org\/10.1002\/chem.202202774","archive":["Portico"],"relation":{},"ISSN":["0947-6539","1521-3765"],"issn-type":[{"value":"0947-6539","type":"print"},{"value":"1521-3765","type":"electronic"}],"subject":[],"published":{"date-parts":[[2022,11,7]]},"assertion":[{"value":"2022-09-06","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2022-11-07","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e202202774"}}