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The results on Cu\n                    <jats:sup>2+<\/jats:sup>\n                    \u2010doped (C\n                    <jats:sub>2<\/jats:sub>\n                    H\n                    <jats:sub>5<\/jats:sub>\n                    NH\n                    <jats:sub>3<\/jats:sub>\n                    )\n                    <jats:sub>2<\/jats:sub>\n                    CdCl\n                    <jats:sub>4<\/jats:sub>\n                    , that is taken as a guide, show the existence of a highly anisotropic response to pressure related to a structural instability, driven by a negative force constant, that leads to an orthorhombic geometry of CuCl\n                    <jats:sub>6<\/jats:sub>\n                    <jats:sup>4\u2212<\/jats:sup>\n                    units but with a hole displaying a dominant 3z\n                    <jats:sup>2<\/jats:sup>\n                    \u2010r\n                    <jats:sup>2<\/jats:sup>\n                    character (z being the direction perpendicular to the layer plane). As a result of such an instability, a pressure of only 3\u2005GPa reduces by 0.21\u2005\u00c5 the longest Cu\n                    <jats:sup>2+<\/jats:sup>\n                    \u2010Cl\n                    <jats:sup>\u2212<\/jats:sup>\n                    distance, lying in the layer plane, while leaving unmodified the two other metal\u2010ligand distances. Owing to this fact, it is shown that the lowest\n                    <jats:italic>d\u2010d<\/jats:italic>\n                    transition would experience a red shift of 0.34\u2005eV while the first allowed charge transfer transition is also found to be red shifted but only by 0.11\u2005eV that reasonably concurs with the experimental value. The parallel study on Jahn\u2010Teller systems CdCl\n                    <jats:sub>2<\/jats:sub>\n                    :Cu\n                    <jats:sup>2+<\/jats:sup>\n                    and NaCl:Cu\n                    <jats:sup>2+<\/jats:sup>\n                    involving tetragonal elongated CuCl\n                    <jats:sub>6<\/jats:sub>\n                    <jats:sup>4\u2212<\/jats:sup>\n                    units shows that the reduction of the long axis by a pressure of 3\u2005GPa is three times smaller than that for the layered (C\n                    <jats:sub>2<\/jats:sub>\n                    H\n                    <jats:sub>5<\/jats:sub>\n                    NH\n                    <jats:sub>3<\/jats:sub>\n                    )\n                    <jats:sub>2<\/jats:sub>\n                    CdCl\n                    <jats:sub>4<\/jats:sub>\n                    :Cu\n                    <jats:sup>2+<\/jats:sup>\n                    compound. Accordingly, the optical transitions of such systems, which involve a positive force constant, are much less sensitive to pressure than in layered compounds. The origin of the red shift under pressure undergone by the lowest\n                    <jats:italic>d\u2010d<\/jats:italic>\n                    and charge transfer transitions of (C\n                    <jats:sub>2<\/jats:sub>\n                    H\n                    <jats:sub>5<\/jats:sub>\n                    NH\n                    <jats:sub>3<\/jats:sub>\n                    )\n                    <jats:sub>2<\/jats:sub>\n                    CdCl\n                    <jats:sub>4<\/jats:sub>\n                    :Cu\n                    <jats:sup>2+<\/jats:sup>\n                    is discussed in detail.\n                  <\/jats:p>","DOI":"10.1002\/chem.202202933","type":"journal-article","created":{"date-parts":[[2022,11,2]],"date-time":"2022-11-02T12:38:16Z","timestamp":1667392696000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":7,"title":["Red Shift in Optical Excitations on Layered Copper Perovskites under Pressure: Role of the Orthorhombic Instability"],"prefix":"10.1002","volume":"29","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-1588-338X","authenticated-orcid":false,"given":"David","family":"Carrasco\u2010Busturia","sequence":"first","affiliation":[{"name":"Department of Energy Conversion and Storage Technical University of Denmark  Anker Engelunds Vej. 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