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The SOF undergoes a reversible single\u2010crystal\u2010to\u2010single\u2010crystal transformation when exposed to vapours of selected organic solvents, moving from a closed structure with isolated small voids to an expanded structure with solvated channels along the <jats:italic>b<\/jats:italic> axis. The observed selectivity is dictated by the fitting of the guest in the expanded SOF, following the degree of packing coefficient. The effect of solvent uptake on <jats:bold>TPPM<\/jats:bold> solid\u2010state fluorescence was investigated, evidencing a significant variation in the emission profile only in the presence of chloroform.<\/jats:p>","DOI":"10.1002\/chem.202202977","type":"journal-article","created":{"date-parts":[[2022,9,26]],"date-time":"2022-09-26T10:25:56Z","timestamp":1664187956000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":15,"title":["Selective and Reversible Solvent Uptake in Tetra\u20104\u2010(4\u2010pyridyl)phenylmethane\u2010based Supramolecular Organic Frameworks"],"prefix":"10.1002","volume":"28","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-4602-9373","authenticated-orcid":false,"given":"Danilo","family":"Marchetti","sequence":"first","affiliation":[{"name":"Department of Chemistry, Life Sciences and Environmental Sustainability INSTM UdR Parma University of Parma  Parco Area delle Scienze 17\/A 43124 Parma 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