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For their application, development of synthetic methods by connecting glycosides and aglycons with strict stereocontrol at the anomeric carbon, as well as with high functional\u2010group compatibility and environmental compatibility is a pivotal issue. Although Suzuki\u2013Miyaura\u2010type C(<jats:italic>sp<\/jats:italic><jats:sup>3<\/jats:sup>)\u2212C(<jats:italic>sp<\/jats:italic><jats:sup>2<\/jats:sup>) cross\u2010coupling using glycosyl boronates is a potential candidate for the construction of <jats:italic>C<\/jats:italic>\u2010glycosides, neither the cross\u2010coupling itself nor the facile synthesis of the coupling precursor, glycosyl boronates, have been achieved to date. 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